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Separation process

 

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Separation process



 
 
In chemistry
Chemistry

Chemistry is the science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions....
 and chemical engineering
Chemical engineering

Chemical engineering is the branch of engineering that deals with the application of physical science , with mathematics, to the process of converting raw materials or chemicals into more useful or valuable forms....
, a separation process is used to transform a mixture
Mixture

In chemistry, a mixture is a substance made by combining two or more different materials without a chemical reaction occurring .While there are no physical changes in a mixture, the chemical properties of a mixture, such as its melting point, may differ from those of its components....
 of substances into two or more distinct products. The separated products could differ in chemical properties or some physical property, such as size, or crystal modification or other separation into different components.

Barring a few exceptions, almost every element
Chemical element

A chemical element is a type of atom that is distinguished by its atomic number; that is, by the number of protons in its atomic nucleus. The term is also used to refer to a pure chemical Chemical substance composed of atoms with the same number of protons....
 or compound
Chemical compound

A chemical compound is a Chemical substance consisting of two or more different chemical element Chemical bond together in a fixed mass ratio that can be split into simpler substances....
 is found naturally in an impure state such as a mixture of two or more substances.






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In chemistry
Chemistry

Chemistry is the science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions....
 and chemical engineering
Chemical engineering

Chemical engineering is the branch of engineering that deals with the application of physical science , with mathematics, to the process of converting raw materials or chemicals into more useful or valuable forms....
, a separation process is used to transform a mixture
Mixture

In chemistry, a mixture is a substance made by combining two or more different materials without a chemical reaction occurring .While there are no physical changes in a mixture, the chemical properties of a mixture, such as its melting point, may differ from those of its components....
 of substances into two or more distinct products. The separated products could differ in chemical properties or some physical property, such as size, or crystal modification or other separation into different components.

Barring a few exceptions, almost every element
Chemical element

A chemical element is a type of atom that is distinguished by its atomic number; that is, by the number of protons in its atomic nucleus. The term is also used to refer to a pure chemical Chemical substance composed of atoms with the same number of protons....
 or compound
Chemical compound

A chemical compound is a Chemical substance consisting of two or more different chemical element Chemical bond together in a fixed mass ratio that can be split into simpler substances....
 is found naturally in an impure state such as a mixture of two or more substances. Many times the need to separate it into its individual components arises. Separation applications in the field of chemical engineering
Chemical engineering

Chemical engineering is the branch of engineering that deals with the application of physical science , with mathematics, to the process of converting raw materials or chemicals into more useful or valuable forms....
 are very important. A good example is that of crude oil
Petroleum

Petroleum or crude oil is a naturally occurring, flammable liquid found in rock formations in the Earth consisting of a complex mixture of hydrocarbons of various molecular weights, plus other organic compounds....
. Crude oil is a mixture of various hydrocarbons and is valuable in this natural form. Demand is greater, however, for the purified various hydrocarbons such as natural gases, gasoline, diesel, jet fuel, lubricating oils, asphalt,etc.

Separation processes can essentially be termed as mass transfer
Mass transfer

Mass transfer is the transfer of mass from high concentration to low concentration. The phrase is commonly used in engineering for physical processes that involve molecule and convection transport of atoms and molecules within systems....
 processes. The classification can be based on the means of separation, mechanical or chemical. The choice of separation depends on the pros and cons of each. Mechanical separations are usually favored if possible due to the lower cost of the operations as compared to chemical separations. Systems that can not be separated by purely mechanical means (e.g. crude oil), chemical separation is the remaining solution. The mixture at hand could exist as a combination of any two or more states: solid-solid, solid-liquid, solid-gas, liquid-liquid, liquid-gas, gas-gas, solid-liquid-gas mixture, etc.

Depending on the raw mixture, various processes can be employed to separate the mixtures. Many times two or more of these processes have to be used in combination to obtain the desired separation. In addition to chemical processes, mechanical processes can also be applied where possible. In the example of crude oil, one upstream distillation operation will feed its two or more product streams into multiple downstream
Downstream processing

Downstream processing refers to the recovery and purification of biosynthetic products, particularly pharmaceuticals, from natural sources such as animal or plant tissue or Fermentation broth, including the recycling of salvageable components and the proper treatment and disposal of waste....
 distillation operations to further separate the crude, and so on until final products are purified.

Various types of separation processes

  • Adsorption
    Adsorption

    Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid , forming a film of molecules or atoms ....
  • Centrifugation
    Centrifugation

    Centrifugation is a process that involves the use of the centrifugal force for the separation processs, used in industry and in laboratory settings....
     and Cyclone
    Cyclonic separation

    Cyclonic separation is a method of removing particulates from an air, gas or water stream, without the use of filter s, through vortex separation....
    s - density differences
  • Chromatography
    Chromatography

    Chromatography is the collective term for a family of laboratory techniques for the separation of mixtures. It involves passing a mixture dissolved in a "mobile phase" through a stationary phase, which separates the analyte to be measured from other molecules in the mixture and allows it to be isolated....
     involves the separation of different dissolved substances as they travel through a material. The dissolved substances are separated based on their interaction with the stationary phase.
  • Crystallization
    Crystallization

    Crystallization is the process of formation of solid crystals Precipitation from a solution, melting or more rarely Deposition directly from a gas....
  • Decantation
    Decantation

    Decantation is a process for the separation of mixtures, carefully pouring a solution from a container in order to leave the precipitate in the bottom of the original container....
  • Demister (Vapor)
    Demister (Vapor)

    A demister, is a device often fitted to vapor liquid separator vessels to enhance the removal of liquid droplets Entrainment in a vapor stream....
     - removing liquid droplets from gas streams
  • Dissolved air flotation - suspended solids are encouraged to float to the top of a fluid by rising air bubbles.
  • Distillation
    Distillation

    Distillation is a method of separation process mixtures based on differences in their Volatility in a boiling liquid mixture. Distillation is a unit operation, or a physical separation process, and not a chemical reaction....
     - used for mixtures of liquids with different boiling points, or for a solid dissolved in a liquid.
  • Drying
    Drying

    Drying is a mass transfer process resulting in the removal of water moisture or moisture from another solvent, by evaporation from a solid, semi-solid or liquid to end in a solid state....
     - removing liquid from a solid by vaporising it
  • Electrophoresis
    Electrophoresis

    Electrophoresis is the best-known electrokinetic phenomena. It was discovered by Reuss in 1807. He observed that clay particles dispersed in water migrate under influence of an applied electric field....
     Organic molecules, such as protein
    Protein

    Proteins are organic compounds made of amino acids arranged in a linear chain and joined together by peptide bonds between the carboxyl and amino groups of adjacent amino acid Residue ....
     are placed in a gel
    Gel

    A gel is a solid, gelatin material that can have properties ranging from soft and weak to hard and tough. Gels are defined as a substantially dilute crosslinked system, which exhibits no flow when in the steady-state....
    . A voltage
    Voltage

    Electrical tension is the potential difference between two points of an electrical or electronic circuit, expressed in volts. It is the measurement of the potential for an electric field to cause an electric current in an electrical conductor....
     is applied and the molecules move through the gel because they are charged
    Electric charge

    Electric charge is a fundamental conserved property of some subatomic particles, which determines their electromagnetic interaction. Electrically charged matter is influenced by, and produces, electromagnetic fields....
    . The gel restricts the motion so that different proteins will make different amounts of progress in any given time.
  • Elutriation
    Elutriation

    Elutriation, also known as air classification, is a process for separating lighter particles from heavier ones using a vertically-directed stream of gas or liquid ....
  • Evaporation
    Evaporation

    Evaporation is the slow vaporization of a liquid and the reverse of condensation. A type of phase transition, it is the process by which molecules in a liquid State of matter spontaneously become gaseous ....
  • Extraction
    • Leaching
      Leaching

      In general, leaching is the extraction of certain materials from a carrier into a liquid . Specifically, it may refer to:*Leaching *Leaching ...
    • Liquid-liquid extraction
      Liquid-liquid extraction

      Liquid-liquid extraction, also known as solvent extraction and partitioning, is a method to separate compounds based on their relative solubility in two different miscible liquids, usually Water and an solvent....
    • Solid phase extraction
      Solid phase extraction

      Solid-phase extraction is a separation process that is used to remove certain compounds from a mixture of impurities based on their physical and chemical properties....
  • Flocculation
    Flocculation

    Flocculation is a process where a solute comes out of solution in the form of floc or flakes. The action differs from Precipitation in that the solute coming out of solution does so at a concentration generally below its solubility limit in the liquid....
     - density differences utilization a flocculant such as soap or detergent
  • Fractional freezing
    Fractional freezing

    Fractional freezing is a process used in process engineering and chemistry to separate two liquids with different melting points. It can be done by partial melting of a solid, for example in zone melting of silicon or metals, or by partial crystallization of a liquid, for example "freeze distillation", also called "normal freezing'...
  • Filtration
    Filtration

    Filtration is a mechanical or physical operation which is used for the separation of solids from fluids by interposing a medium to fluid flow through which the fluid can pass, but the solids in the fluid are retained....
    . Mesh
    Mesh

    Mesh consists of semi-permeable barrier made of connected strands of metal, fiber, or other flexible/ductile material. Mesh is similar to spider web or Net in that it has many attached or woven strands....
    , bag and paper filters are used to remove large particulates suspended in fluids, eg. fly ash
    Fly ash

    Fly ash is one of the residues generated in the combustion of coal. Fly ash is generally captured from the chimneys of Fossil fuel power plant, and is one of two types of ash that jointly are known as coal ash; the other, bottom ash, is removed from the bottom of coal furnaces....
    , while membrane processes including microfiltration
    Microfiltration

    Microfiltration is a filtration process which removes contaminants from a fluid by passage through a microporous semipermeable membrane. A typical microfiltration membrane pore size range is 0.1 to 10 micrometres ....
    , ultrafiltration
    Ultrafiltration

    Ultrafiltration is a variety of membrane filtration in which hydrostatic pressure forces a liquid against a semipermeable membrane. Suspended solids and solutes of high molecular weight are retained, while water and low molecular weight solutes pass through the membrane....
    , nanofiltration
    Nanofiltration

    Nanofiltration is a relatively recent membrane process used most often with low total dissolved solids water such as surface water and fresh groundwater, with the purpose of softening and removal of disinfection by-product precursors such as natural organic matter and synthetic organic matter...
    , reverse osmosis
    Reverse osmosis

    Reverse osmosis is a filtration process typically used for water. It works by using pressure to force a solution through a semi-permeable membrane, retaining the solute on one side and allowing the pure solvent to pass to the other side....
    , dialysis (biochemistry)
    Dialysis (biochemistry)

    In biochemistry, dialysis is the process of separating molecules in solution by the difference in their rates of diffusion through a semipermeable membrane, such as dialysis tubing....
     utilising synthetic membranes can separate micrometre
    Micrometre

    A micrometre or micron is one Micro- of a metre, or equivalently one thousandth of a millimetre. It is also commonly known as a micron....
    -sized or smaller species.
  • Oil-water separation
    API oil-water separator

    An API oil-water separator is a device designed to separate gross amounts of oil and suspended solids from the wastewater effluents of Oil refinery, Petrochemical, chemical plants, Natural gas processings and other industrial sources....
     - gravimetric separator used to remove suspended oil droplets from wastewaters in oil refineries
    Oil refinery

    An oil refinery is an industrial process plant where crude oil is processed and refined into more useful petroleum products, such as gasoline, diesel fuel, asphalt, heating oil, kerosene, and liquefied petroleum gas....
    , petrochemical
    Petrochemical

    Petrochemicals are chemical products made from raw materials of petroleum or other hydrocarbon origin. Although some of the chemical compounds that originate from petroleum may also be derived from coal and natural gas, petroleum is the major source....
     and chemical plant
    Chemical plant

    A chemical plant is an industry Industrial process factory that manufactures chemicals, usually on a large scale. The general objective of a chemical plant is to create new material wealth via the chemical or biological transformation and or separation of materials....
    s, natural gas processing plants
    Natural gas processing

    Natural gas processing plants, or fractionators, are used to purify the raw natural gas extracted from underground Natural gas field and brought up to the surface by Oil well....
     and similar industries.
  • Precipitation
    Precipitation (chemistry)

    Precipitation is the formation of a solid in a solution during a chemical reaction. When the reaction occurs, the solid formed is called the precipitate, and the liquid remaining above the solid is called the supernate....
  • Recrystallization
    Recrystallization

    Recrystallization is a physical process that has meanings in chemistry, metallurgy and geology....
  • Sedimentation
    Sedimentation

    Sedimentation describes the motion of molecules in solutions or particle s in suspension in response to an external force such as gravitation, centrifugal force or electromagnetism....
     - density differences
    • Gravity separation
      Gravity separation

      Gravity separation is an industrial method of separating two components from a suspension or any other homogeneous mixture where separating the components with gravity is sufficiently practical....
  • Sieving
  • Stripping
    Stripping (chemistry)

    Stripping is a physical separation process where one or more components are removed from a liquid stream by a vapor stream. In industrial applications the liquid and vapor streams can have concurrent or countercurrent flows....
  • Sublimation
    Sublimation (physics)

    Sublimation of an element or compound is a transition from the solid to gas phase with no intermediate liquid stage. Sublimation is an endothermic phase transition that occurs at temperatures and pressures below the triple point ....
  • Vapor-liquid separation
    Souders-Brown equation

    The Souders-Brown equation has been the tool for obtaining the maximum allowable vapor velocity in Vapor-liquid separator . It has also been used for the same purpose in designing trayed fractionating columns, trayed absorption columns and other vapor-liquid contacting columns....
     - designed by using the Souders-Brown equation.
  • Winnowing
  • Zone refining


See also

  • Analytical chemistry
    Analytical chemistry

    Analytical chemistry is the study of the chemical composition of natural and artificial materials. Unlike other major sub disciplines of chemistry such as inorganic chemistry and organic chemistry, analytical chemistry is not restricted to any particular type of chemical compound or chemical reaction....
  • Chemical engineering
    Chemical engineering

    Chemical engineering is the branch of engineering that deals with the application of physical science , with mathematics, to the process of converting raw materials or chemicals into more useful or valuable forms....
  • Unit operations