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Mass transfer



 
 
Mass transfer is the transfer of mass from high concentration to low concentration. The phrase is commonly used in engineering for physical processes that involve molecular
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
 and convective
Convection

Convection in the most general terms refers to the movement of molecules within fluids . Convection is one of the major modes of heat transfer and mass transfer....
 transport of atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
s and molecule
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
s within physical system
System

System is a set of interacting or interdependent entities, real or abstract, forming an integrated whole.The concept of an "integrated whole" can also be stated in terms of a system embodying a set of relationships which are differentiated from relationships of the set to other elements, and from relationships between an element of the se...
s. Mass transfer includes both fluid flow and separation unit operation
Unit operation

In chemical engineering and related fields, a unit operation is a basic step in a process. For example in milk processing, homogenization, pasteurization, chilling, and packaging are each unit operations which are connected to create the overall process....
s.

common examples of mass transfer processes are the evaporation
Evaporation

Evaporation is the slow vaporization of a liquid and the reverse of condensation. A type of phase transition, it is the process by which molecules in a liquid State of matter spontaneously become gaseous ....
 of water
Water

Water is a common chemical substance that is essential for the survival of all known forms of life. In typical usage, water refers only to its liquid form or States of matter, but the substance also has a solid state, ice, and a gaseous state, water vapor or steam....
 from a pond to the atmosphere
Earth's atmosphere

The Earth's atmosphere is a layer of gases surrounding the planet Earth that is retained by the Earth's gravity. Dry air contains roughly 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.038% Carbon dioxide in the Earth's atmosphere, and trace amounts of other gases....
; the diffusion
Diffusion

Molecular diffusion, often called simply diffusion, is a net transport of molecules from a region of higher concentration to one of lower concentration by random molecular motion....
 of chemical impurities in lakes, river
River

A river is a natural stream of water, usually freshwater, flowing toward an ocean, a lake, or another stream. In some cases a river flows into the ground or dries up completely before reaching another body of water....
s, and ocean
Ocean

An ocean is a major body of Seawater, and a principal component of the hydrosphere. Approximately 71% of the Earth's surface is covered by ocean, a World Ocean that is customarily divided into several principal oceans and smaller seas....
s from natural or artificial point source
Point source

A point source is a localised relatively-small source of something.Point source may also refer to:*Point source , a localised source of pollution...
s; mass transfer is also responsible for the separation of components in an apparatus such as a distillation
Distillation

Distillation is a method of separation process mixtures based on differences in their Volatility in a boiling liquid mixture. Distillation is a unit operation, or a physical separation process, and not a chemical reaction....
 column.






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Encyclopedia


Mass transfer is the transfer of mass from high concentration to low concentration. The phrase is commonly used in engineering for physical processes that involve molecular
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
 and convective
Convection

Convection in the most general terms refers to the movement of molecules within fluids . Convection is one of the major modes of heat transfer and mass transfer....
 transport of atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
s and molecule
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
s within physical system
System

System is a set of interacting or interdependent entities, real or abstract, forming an integrated whole.The concept of an "integrated whole" can also be stated in terms of a system embodying a set of relationships which are differentiated from relationships of the set to other elements, and from relationships between an element of the se...
s. Mass transfer includes both fluid flow and separation unit operation
Unit operation

In chemical engineering and related fields, a unit operation is a basic step in a process. For example in milk processing, homogenization, pasteurization, chilling, and packaging are each unit operations which are connected to create the overall process....
s.

Examples

Some common examples of mass transfer processes are the evaporation
Evaporation

Evaporation is the slow vaporization of a liquid and the reverse of condensation. A type of phase transition, it is the process by which molecules in a liquid State of matter spontaneously become gaseous ....
 of water
Water

Water is a common chemical substance that is essential for the survival of all known forms of life. In typical usage, water refers only to its liquid form or States of matter, but the substance also has a solid state, ice, and a gaseous state, water vapor or steam....
 from a pond to the atmosphere
Earth's atmosphere

The Earth's atmosphere is a layer of gases surrounding the planet Earth that is retained by the Earth's gravity. Dry air contains roughly 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.038% Carbon dioxide in the Earth's atmosphere, and trace amounts of other gases....
; the diffusion
Diffusion

Molecular diffusion, often called simply diffusion, is a net transport of molecules from a region of higher concentration to one of lower concentration by random molecular motion....
 of chemical impurities in lakes, river
River

A river is a natural stream of water, usually freshwater, flowing toward an ocean, a lake, or another stream. In some cases a river flows into the ground or dries up completely before reaching another body of water....
s, and ocean
Ocean

An ocean is a major body of Seawater, and a principal component of the hydrosphere. Approximately 71% of the Earth's surface is covered by ocean, a World Ocean that is customarily divided into several principal oceans and smaller seas....
s from natural or artificial point source
Point source

A point source is a localised relatively-small source of something.Point source may also refer to:*Point source , a localised source of pollution...
s; mass transfer is also responsible for the separation of components in an apparatus such as a distillation
Distillation

Distillation is a method of separation process mixtures based on differences in their Volatility in a boiling liquid mixture. Distillation is a unit operation, or a physical separation process, and not a chemical reaction....
 column. In HVAC
HVAC

HVAC is an initialism or acronym that stands for "heating, Ventilation , and air conditioning". HVAC is sometimes referred to as climate control and is particularly important in the design of medium to large industrial and office buildings such as skyscrapers and in marine environments such as aquariums, where humidity and tem...
 examples of a heat and mass exchangers are cooling tower
Cooling tower

Cooling towers are heat removal devices used to transfer process waste heat to the atmosphere. Cooling towers may either use the evaporation of water to remove process heat and cool the working fluid to near the Wet-bulb temperature or rely solely on air to cool the working fluid to near the Dry-bulb temperature....
s and evaporative coolers where evaporation of water cools that portion which remains as a liquid, as well as cooling and humidifying the air
AIR

Air is the part of Earth's atmosphere that humans breath and as such Air .Air may also refer to:...
 passing through.

The driving force for mass transfer is a difference in concentration; the random motion of molecules causes a net transfer of mass from an area of high concentration to an area of low concentration. The amount of mass transfer can be quantified through the calculation and application of mass transfer coefficient
Mass transfer coefficient

In engineering, the mass transfer coefficient is a diffusion rate constant that relates the mass transfer rate, mass transfer area, and concentration gradient as driving force:...
s. Mass transfer finds extensive application in chemical engineering
Chemical engineering

Chemical engineering is the branch of engineering that deals with the application of physical science , with mathematics, to the process of converting raw materials or chemicals into more useful or valuable forms....
 problems, where material balance on components is performed.

In astronomy
Astronomy

Astronomy is the science of Astronomical object and Phenomenon that originate outside the Earth's atmosphere . It is concerned with the evolution, physics, chemistry, meteorology, and motion of celestial objects, as well as the physical cosmology....
, mass transfer is the process by which matter
Matter

In common usage, matter is anything that has both mass and volume . A more rigorous definition is used in science: matter is what atoms and molecules are made of....
 gravitation
Gravitation

Gravitation is a natural phenomenon that gives weight to objects. In everyday life, attraction due to gravity is the result of the presence of relatively large bodies, such as the Earth and the Moon....
ally bound to a body, usually a star
Star

A star is a massive, luminous ball of Plasma that is held together by its own gravity. The nearest star to Earth is the Sun, which is the source of most of the energy on Earth....
, fills its Roche lobe
Roche lobe

The Roche lobe is the region of space around a star in a binary star within which orbiting material is gravitationally bound to that star. If the star expands past its Roche lobe, then the material outside of the lobe will fall into the other star....
 and becomes gravitationally bound to a second body, usually a compact object (white dwarf
White dwarf

A white dwarf, also called a degenerate dwarf, is a small star composed mostly of electron-degenerate matter. Because a white dwarf's mass is comparable to that of the Sun and its volume is comparable to that of the Earth, it is very density....
, neutron star
Neutron star

A neutron star is a type of compact star that can result from the gravitational collapse of a massive star during a Type II supernova, Type Ib and Ic supernovae supernova event....
 or black hole
Black hole

In general relativity, a black hole is a region of space in which the gravitational field is so powerful that nothing, including electromagnetic radiation , can escape its pull after having fallen past its event horizon....
), and is eventually accreted onto it. It is a common phenomenon in binary systems
Binary star

A binary star is a star system consisting of two stars orbiting around their common center of mass. The brighter star is called the primary and the other is its companion star or secondary....
, and may play an important role in some types of supernova
Supernova

A supernova is a Astronomy#Stellar astronomy explosion. Supernovae are extremely luminous and cause a burst of radiation that often briefly outshines an entire galaxy, before fading from view over several weeks or months....
e, and pulsar
Pulsar

Pulsars are highly magnetized, rotating neutron stars that emit a beam of electromagnetic radiation. The observed periods of their pulses range from 1.4 milliseconds to 8.5 seconds....
s.

For separation processes, thermodynamics
Thermodynamics

In physics, thermodynamics is the study of the conversion of heat energy into different forms of energy ; different energy conversions into heat energy; and its relation to macroscopic variables such as temperature, pressure, and volume....
 determines the extent of separation, while mass transfer determines the rate at which the separation will occur.

Analogies between heat, mass, and momentum transfer


It is important to note that in molecular transport, heat, or mass there are many similarities. The molecular diffusion equations of Newton
Newtonian fluid

A Newtonian fluid is a fluid whose shear stress versus rate of strain curve is linear and passes through the Origin . The constant of proportionality is known as the viscosity....
 for momentum, Fourier law
Heat conduction

Heat conduction or thermal conduction is the spontaneous heat transfer through matter, from a region of higher temperature to a region of lower temperature, and acts to equalize temperature differences....
 for heat, and Fick
Fick's law of diffusion

Fick's laws of diffusion describe diffusion and can be used to solve for the diffusion coefficient D. They were derived by Adolf Fick in the year 1855....
 for mass are very similar. Therefore there are many analogies among these three molecular transport processes. A great deal of effort has been devoted in the literature to developing analogies among these three transport processes for turbulent transfer so as to allow prediction of one from any of the others. Reynolds analogy
Reynolds analogy

Reynolds analogy relates turbulent momentum and heat transfer. The main assumption is that heat flux q/A in a turbulent system is analogous to momentum flux t, which suggests that the ratio t/ must be constant for all radial positions....
 assumes that the turbulent diffusivities are all equal and that the molecular diffusivities of momentum (µ/?) and mass (DAB) are negligible compared to the turbulent diffusivities. When liquids are present and/or drag is present the analogy is not valid. Other analogies, such as von Karman
Theodore von Karman

Theodore von K?rm?n was a Hungarian people-United States engineer and physicist who was active primarily in the fields of aeronautics and astronautics....
's and Prandtl
Ludwig Prandtl

Ludwig Prandtl was a Germany scientist. He was a pioneer of aerodynamics, and developed the mathematical basis for the fundamental principles of subsonic aerodynamics in the 1920s....
's, usually results in poor relations. The most successful and most widely used analogy is the Chilton and Colburn J-factor analogy
Chilton and Colburn J-factor analogy

Chilton and Colburn J-factor analogy is probably the most successful and widely used analogy from heat, momentum, and mass transfer analogies. The basic mechanisms and mathematics of heat, mass, and momentum transport are essentially the same....
. This analogy is based on experimental data for gases and liquids in both the laminar and turbulent regions. Although it is based on experimental data, it can be shown to satisfy the exact solution derived from laminar flow over a flat plate.

See also

  • Crystal growth
    Crystal growth

    Crystal growth is a major stage of a crystallization, after the nucleation stage. It occurs from the addition of new atoms, ions, or polymer strings into the characteristic arrangement, or lattice, of a crystal....
  • Heat transfer
    Heat transfer

    Heat transfer is the transition of thermal energy or simply heat from a hotter object to a cooler object . When an object or fluid is at a different temperature than its thermodynamic system or another object, transfer of thermal energy, also known as heat transfer, or heat exchange, occurs in such a way that the body and the surround...
  • Heat exchanger
    Heat exchanger

    A heat exchanger is a device built for efficient heat transfer from one medium to another, whether the media are separated by a solid wall so that they never mix, or the media are in direct contact....
    s
  • Fick%27s%20law
  • Distillation column
  • McCabe-Thiele method
    McCabe-Thiele method

    The graphical approach presented by McCabe and Thiele in 1925, the McCabe-Thiele method is considered the simplest and perhaps most instructive method for analysis of binary distillation....
  • Vapor-Liquid Equilibrium
    Vapor-liquid equilibrium

    Vapor-liquid equilibrium, abbreviated as VLE by some, is a condition where a liquid and its vapor are in Chemical equilibrium with each other, a condition or state where the rate of evaporation equals the rate of condensation on a molecular level such that there is no net vapor-liquid interconversion....
  • Liquid-liquid extraction
    Liquid-liquid extraction

    Liquid-liquid extraction, also known as solvent extraction and partitioning, is a method to separate compounds based on their relative solubility in two different miscible liquids, usually Water and an solvent....
  • Separation process
    Separation process

    In chemistry and chemical engineering, a separation process is used to transform a mixture of substances into two or more distinct products. The separated products could differ in chemical properties or some physical property, such as size, or crystal modification or other separation into different components....