Spallation
Encyclopedia
In general, spallation is a process in which fragments of material (spall
Spall
Spall are flakes of a material that are broken off a larger solid body and can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure...

) are ejected from a body due to impact or stress. In the context of impact mechanics it describes ejection or vaporization of material from a target during impact by a projectile
Projectile
A projectile is any object projected into space by the exertion of a force. Although a thrown baseball is technically a projectile too, the term more commonly refers to a weapon....

. In planetary physics
Planetary science
Planetary science is the scientific study of planets , moons, and planetary systems, in particular those of the Solar System and the processes that form them. It studies objects ranging in size from micrometeoroids to gas giants, aiming to determine their composition, dynamics, formation,...

, spallation describes meteor
METEOR
METEOR is a metric for the evaluation of machine translation output. The metric is based on the harmonic mean of unigram precision and recall, with recall weighted higher than precision...

itic impacts on a planetary surface and the effects of a stellar wind
Stellar wind
A stellar wind is a flow of neutral or charged gas ejected from the upper atmosphere of a star. It is distinguished from the bipolar outflows characteristic of young stars by being less collimated, although stellar winds are not generally spherically symmetric.Different types of stars have...

 on a planetary atmosphere. In the context of mining
Mining
Mining is the extraction of valuable minerals or other geological materials from the earth, from an ore body, vein or seam. The term also includes the removal of soil. Materials recovered by mining include base metals, precious metals, iron, uranium, coal, diamonds, limestone, oil shale, rock...

 or geology
Geology
Geology is the science comprising the study of solid Earth, the rocks of which it is composed, and the processes by which it evolves. Geology gives insight into the history of the Earth, as it provides the primary evidence for plate tectonics, the evolutionary history of life, and past climates...

, spallation can refer to pieces of rock breaking off a rock face due to the internal stresses in the rock; it commonly occurs on mine shaft walls. In the context of anthropology
Anthropology
Anthropology is the study of humanity. It has origins in the humanities, the natural sciences, and the social sciences. The term "anthropology" is from the Greek anthrōpos , "man", understood to mean mankind or humanity, and -logia , "discourse" or "study", and was first used in 1501 by German...

, spallation is a process used to make stone tools such as arrowhead
Arrowhead
An arrowhead is a tip, usually sharpened, added to an arrow to make it more deadly or to fulfill some special purpose. Historically arrowheads were made of stone and of organic materials; as human civilization progressed other materials were used...

s by knapping. In nuclear physics
Nuclear physics
Nuclear physics is the field of physics that studies the building blocks and interactions of atomic nuclei. The most commonly known applications of nuclear physics are nuclear power generation and nuclear weapons technology, but the research has provided application in many fields, including those...

, spallation is the process in which a heavy nucleus emits a large number of nucleon
Nucleon
In physics, a nucleon is a collective name for two particles: the neutron and the proton. These are the two constituents of the atomic nucleus. Until the 1960s, the nucleons were thought to be elementary particles...

s as a result of being hit by a high-energy particle
Subatomic particle
In physics or chemistry, subatomic particles are the smaller particles composing nucleons and atoms. There are two types of subatomic particles: elementary particles, which are not made of other particles, and composite particles...

, thus greatly reducing its atomic weight
Atomic weight
Atomic weight is a dimensionless physical quantity, the ratio of the average mass of atoms of an element to 1/12 of the mass of an atom of carbon-12...

.

Spallation in solid mechanics

Spallation can occur when a tensile stress wave propagates through a material and can be observed in flat plate impact tests. It is caused by an internal cavitation due to stresses, which are generated by the interaction of stress waves, exceeding the local tensile strength
Tensile strength
Ultimate tensile strength , often shortened to tensile strength or ultimate strength, is the maximum stress that a material can withstand while being stretched or pulled before necking, which is when the specimen's cross-section starts to significantly contract...

 of materials. A fragment or multiple fragments will be created on the free end of the plate. This fragment known as "spall
Spall
Spall are flakes of a material that are broken off a larger solid body and can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure...

" acts as a secondary projectile with velocities that can be as high as one third of the stress wave speed on the material. This type of failure is typically an effect of high explosive squash head (HESH) charges.

Laser spallation

Laser induced spallation is a recent experimental technique developed to understand the adhesion
Adhesion
Adhesion is any attraction process between dissimilar molecular species that can potentially bring them in close contact. By contrast, cohesion takes place between similar molecules....

 of thin films with substrate
Wafer (electronics)
A wafer is a thin slice of semiconductor material, such as a silicon crystal, used in the fabrication of integrated circuits and other microdevices...

s. A high energy pulsed laser
Laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of photons. The term "laser" originated as an acronym for Light Amplification by Stimulated Emission of Radiation...

 (typically Nd:YAG
Nd:YAG laser
Nd:YAG is a crystal that is used as a lasing medium for solid-state lasers. The dopant, triply ionized neodymium, typically replaces yttrium in the crystal structure of the yttrium aluminium garnet , since they are of similar size...

) is used to create a compressive stress pulse in the substrate
Wafer (electronics)
A wafer is a thin slice of semiconductor material, such as a silicon crystal, used in the fabrication of integrated circuits and other microdevices...

 wherein it propagates and reflects as a tensile wave at the free boundary. This tensile pulse spalls/peels the thin film while propagating towards the substrate. Using theory of wave propagation
Wave propagation
Wave propagation is any of the ways in which waves travel.With respect to the direction of the oscillation relative to the propagation direction, we can distinguish between longitudinal wave and transverse waves....

 in solids it is possible to extract the interface strength. The stress pulse created in this fashion is usually around 3-8 nanoseconds in duration while its magnitude varies as a function of laser
Laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of photons. The term "laser" originated as an acronym for Light Amplification by Stimulated Emission of Radiation...

 fluence. Due to the non-contact application of load, this technique is very well suited to spall ultra-thin films (1 micrometre in thickness or less). It is also possible to mode convert a longitudinal stress wave into a shear stress
Shear stress
A shear stress, denoted \tau\, , is defined as the component of stress coplanar with a material cross section. Shear stress arises from the force vector component parallel to the cross section...

 using a pulse shaping prism and achieve shear spallation.

Nuclear spallation

See also Cosmic ray spallation
Cosmic ray spallation
Cosmic ray spallation is a form of naturally occurring nuclear fission and nucleosynthesis. It refers to the formation of elements from the impact of cosmic rays on an object. Cosmic rays are highly energetic charged particles from outside of Earth ranging from protons, alpha particles, and nuclei...



Nuclear spallation occurs naturally in earth's atmosphere
Earth's atmosphere
The atmosphere of Earth is a layer of gases surrounding the planet Earth that is retained by Earth's gravity. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention , and reducing temperature extremes between day and night...

 owing to the impacts of cosmic ray
Cosmic ray
Cosmic rays are energetic charged subatomic particles, originating from outer space. They may produce secondary particles that penetrate the Earth's atmosphere and surface. The term ray is historical as cosmic rays were thought to be electromagnetic radiation...

s, and also on the surfaces of bodies in space such as meteorite
Meteorite
A meteorite is a natural object originating in outer space that survives impact with the Earth's surface. Meteorites can be big or small. Most meteorites derive from small astronomical objects called meteoroids, but they are also sometimes produced by impacts of asteroids...

s and the moon
Moon
The Moon is Earth's only known natural satellite,There are a number of near-Earth asteroids including 3753 Cruithne that are co-orbital with Earth: their orbits bring them close to Earth for periods of time but then alter in the long term . These are quasi-satellites and not true moons. For more...

. Evidence of cosmic ray spallation is evidence that the material in question has been exposed on the surface of the body of which it is part, and gives a means of measuring the length of time of exposure. The composition of the cosmic rays themselves also indicates that they have suffered spallation before reaching Earth, because the proportion of light elements such as Li, B,and Be in them exceeds average cosmic abundances; these elements in the cosmic rays were evidently formed from spallation of oxygen, nitrogen, carbon and perhaps silicon in the cosmic ray sources or during their lengthy travel here. Cosmogenic isotopes of aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

, beryllium
Beryllium
Beryllium is the chemical element with the symbol Be and atomic number 4. It is a divalent element which occurs naturally only in combination with other elements in minerals. Notable gemstones which contain beryllium include beryl and chrysoberyl...

, chlorine
Chlorine
Chlorine is the chemical element with atomic number 17 and symbol Cl. It is the second lightest halogen, found in the periodic table in group 17. The element forms diatomic molecules under standard conditions, called dichlorine...

, iodine
Iodine
Iodine is a chemical element with the symbol I and atomic number 53. The name is pronounced , , or . The name is from the , meaning violet or purple, due to the color of elemental iodine vapor....

 and neon
Neon
Neon is the chemical element that has the symbol Ne and an atomic number of 10. Although a very common element in the universe, it is rare on Earth. A colorless, inert noble gas under standard conditions, neon gives a distinct reddish-orange glow when used in either low-voltage neon glow lamps or...

, formed by spallation of terrestrial elements under cosmic ray bombardment, have been detected on earth.

Nuclear spallation is one of the processes by which a particle accelerator
Particle accelerator
A particle accelerator is a device that uses electromagnetic fields to propel charged particles to high speeds and to contain them in well-defined beams. An ordinary CRT television set is a simple form of accelerator. There are two basic types: electrostatic and oscillating field accelerators.In...

 may be used to produce a beam of neutron
Neutron
The neutron is a subatomic hadron particle which has the symbol or , no net electric charge and a mass slightly larger than that of a proton. With the exception of hydrogen, nuclei of atoms consist of protons and neutrons, which are therefore collectively referred to as nucleons. The number of...

s. A mercury
Mercury (element)
Mercury is a chemical element with the symbol Hg and atomic number 80. It is also known as quicksilver or hydrargyrum...

, tantalum
Tantalum
Tantalum is a chemical element with the symbol Ta and atomic number 73. Previously known as tantalium, the name comes from Tantalus, a character in Greek mythology. Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion resistant. It is part of the refractory...

 or other heavy metal target is used, and 20 to 30 neutrons are expelled after each impact. Although this is a far more expensive way of producing neutron beams than by a chain reaction
Chain reaction
A chain reaction is a sequence of reactions where a reactive product or by-product causes additional reactions to take place. In a chain reaction, positive feedback leads to a self-amplifying chain of events....

 of nuclear fission
Nuclear fission
In nuclear physics and nuclear chemistry, nuclear fission is a nuclear reaction in which the nucleus of an atom splits into smaller parts , often producing free neutrons and photons , and releasing a tremendous amount of energy...

 in a nuclear reactor
Nuclear reactor
A nuclear reactor is a device to initiate and control a sustained nuclear chain reaction. Most commonly they are used for generating electricity and for the propulsion of ships. Usually heat from nuclear fission is passed to a working fluid , which runs through turbines that power either ship's...

, it has the advantage that the beam can be pulsed with relative ease. The concept of nuclear spallation was first coined by Nobelist Glenn T. Seaborg
Glenn T. Seaborg
Glenn Theodore Seaborg was an American scientist who won the 1951 Nobel Prize in Chemistry for "discoveries in the chemistry of the transuranium elements", contributed to the discovery and isolation of ten elements, and developed the actinide concept, which led to the current arrangement of the...

 in his doctoral thesis on the inelastic scattering of neutrons
Inelastic neutron scattering
Inelastic neutron scattering is an experimental technique commonly used in condensed matter research to study atomic and molecular motion as well as magnetic and crystal field excitations....

 in 1937.

Production of neutrons at a spallation neutron source

Generally the production of neutrons at a spallation source begins with a high-powered accelerator
Particle accelerator
A particle accelerator is a device that uses electromagnetic fields to propel charged particles to high speeds and to contain them in well-defined beams. An ordinary CRT television set is a simple form of accelerator. There are two basic types: electrostatic and oscillating field accelerators.In...

. This is more often than not a synchrotron
Synchrotron
A synchrotron is a particular type of cyclic particle accelerator in which the magnetic field and the electric field are carefully synchronised with the travelling particle beam. The proton synchrotron was originally conceived by Sir Marcus Oliphant...

. As an example, the ISIS neutron source
ISIS neutron source
ISIS is a pulsed neutron and muon source. It is situated at the Rutherford Appleton Laboratory on the Harwell Science and Innovation Campus in Oxfordshire, United Kingdom and is part of the Science and Technology Facilities Council...

 is based on some components of the former Nimrod synchrotron
Nimrod (synchrotron)
Nimrod was a 7 GeV proton synchrotron operating in the Rutherford Appleton Laboratory in the United Kingdom between 1964 and 1978. It was used forstudies of nuclear and sub-nuclearphenomena...

. Nimrod was uncompetitive for particle physics
Particle physics
Particle physics is a branch of physics that studies the existence and interactions of particles that are the constituents of what is usually referred to as matter or radiation. In current understanding, particles are excitations of quantum fields and interact following their dynamics...

 so it was replaced with a new synchrotron, initially using the original injector
Injector
ʎ̩An injector, ejector, steam ejector, steam injector, eductor-jet pump or thermocompressor is a pump-like device that uses the Venturi effect of a converging-diverging nozzle to convert the pressure energy of a motive fluid to velocity energy which creates a low pressure zone that dɯaws in and...

s, but which produces a highly intense pulsed beam of protons. Whereas Nimrod would produce around 2 µA at 7 GeV, ISIS produces 200 µA at 0.8 GeV. This is pulsed at the rate of 50 Hz, and this intense beam of protons is focused onto a target. Experiments have been done with depleted uranium
Depleted uranium
Depleted uranium is uranium with a lower content of the fissile isotope U-235 than natural uranium . Uses of DU take advantage of its very high density of 19.1 g/cm3...

 targets but although these produce the most intense neutron beams, they also have the shortest lives. Generally, therefore, tantalum
Tantalum
Tantalum is a chemical element with the symbol Ta and atomic number 73. Previously known as tantalium, the name comes from Tantalus, a character in Greek mythology. Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion resistant. It is part of the refractory...

 targets have been used. Spallation processes in the target produce the neutrons, initially at very high energies—a good fraction of the proton energy. These neutrons are then slowed in moderators filled with liquid hydrogen
Liquid hydrogen
Liquid hydrogen is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form.To exist as a liquid, H2 must be pressurized above and cooled below hydrogen's Critical point. However, for hydrogen to be in a full liquid state without boiling off, it needs to be...

 or liquid methane
Methane
Methane is a chemical compound with the chemical formula . It is the simplest alkane, the principal component of natural gas, and probably the most abundant organic compound on earth. The relative abundance of methane makes it an attractive fuel...

 to the energies that are needed for the scattering instruments. Whilst protons can be focused since they have charge, chargeless neutrons cannot be, so in this arrangement the instruments are arranged around the moderators.
Inertial confinement fusion
Inertial confinement fusion
Inertial confinement fusion is a process where nuclear fusion reactions are initiated by heating and compressing a fuel target, typically in the form of a pellet that most often contains a mixture of deuterium and tritium....

 has the potential to produce orders of magnitude more neutrons than spallation. Neutron radiography
Neutron Radiography
Neutron Radiography is the process by which film is exposed by first passing neutrons through an object to produce a visible image of the materials that make up the object. Primarily used in scientific investigations.- Brief History of Neutron Imaging :...

 can be used to locate hydrogen atoms in structures, resolve atomic thermal motion and study collective excitations of photons more effectively than X-rays.

See also

  • Spall
    Spall
    Spall are flakes of a material that are broken off a larger solid body and can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure...

    , or spalling
  • Cosmic ray spallation
    Cosmic ray spallation
    Cosmic ray spallation is a form of naturally occurring nuclear fission and nucleosynthesis. It refers to the formation of elements from the impact of cosmic rays on an object. Cosmic rays are highly energetic charged particles from outside of Earth ranging from protons, alpha particles, and nuclei...

  • Energy amplifier
    Energy amplifier
    In nuclear physics, an energy amplifier is a novel type of nuclear power reactor, a subcritical reactor, in which an energetic particle beam is used to stimulate a reaction, which in turn releases enough energy to power the particle accelerator and leave an energy profit for power generation...

  • Subcritical reactor
    Subcritical reactor
    A subcritical reactor is a nuclear fission reactor that produces fission without achieving criticality. Instead of a sustaining chain reaction, a subcritical reactor uses additional neutrons from an outside source...

     (accelerator-driven system)

Spallation Facilities

  • Spallation Neutron Source
    Spallation Neutron Source
    The Spallation Neutron Source is an accelerator-based neutron source facility that provides the most intense pulsed neutron beams in the world for scientific research and industrial development...

     Oak Ridge
  • ISIS neutron source
    ISIS neutron source
    ISIS is a pulsed neutron and muon source. It is situated at the Rutherford Appleton Laboratory on the Harwell Science and Innovation Campus in Oxfordshire, United Kingdom and is part of the Science and Technology Facilities Council...

  • European Spallation Source
    European Spallation Source
    European Spallation Source is the name of a materials research facility for scientific research using the neutron scattering technique. The facility will be built in Lund, Sweden starting in 2013. The facility is expected to open in 2019 and will be fully operational in 2025...

  • PSI Spallation Neutron Source (SINQ)
  • LANSCE Los Alamos

External links

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