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Silly Putty

 

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Silly Putty


 
 



Silly Putty (originally called Nutty Putty, and also marketing by other companies as Thinking Putty, Bouncing Putty) is the Crayola owned trademark name for a class of siliconeFacts About Silicone

Silicones, or polysiloxanes, are inorganic-organic polymers with the chemical formula [R2SiO]n, where R = organic grou...
 plastics known as Bouncing Putty. It is marketed today as a toy for children, but was originally created as an accident during the course of research into potential rubberRubber Overview

Rubber is an elastic hydrocarbon polymer which occurs as a milky emulsion in the sap of several varieties of plants....
 substitutes for use by the United StatesUnited States

The United States of America, also known as the United States, the U.S., the U.S.A., and America, is...
 during World War IIWorld War II Overview

World War II, or the Second World War, was a worldwide conflict fought between the Allied Powers and the Axis Powers ,...
.
During World War II, the USA was looking for a synthetic rubber compound because of the difficulties in obtaining natural rubber from the Far East. In researching this problem, James Wright of General Electric reacted boric acid with silicone oil and produced a gooey material – though it bounced it was certainly not a rubber substitute. Independently, Earl Warrick of the newly formed Dow CorningDow Corning

Dow Corning is a multinational corporation headquartered in Midland, Michigan, USA....
 Corporation also discovered that reacting boron compounds with silicone polymers resulted in a Bouncing Putty. For years the discovery languished as a laboratory curiosity.

It was after its success as a toy that other uses were found. The material's unique properties have found niche use in medical and scientific applications. In is used in large quantity by physical therapists for rehabilitative therapy of hand injuries. A number of other brands have emerged which alter the material's properties offering different levels of resistance for this market. Power Putty and TheraPutty are examples. The material is also used therapeutically for stress reduction. Patients with ADD, ADHD, Fragile-X and many other disorders find its continuous tactile sensation to be calming and focusing. In the home it can be used to pick up dirt, lint and pet hair, and it was even used by Apollo astronauts to secure tools in zero-gravity.

Description

As a bouncing putty, Silly Putty is an inorganicInorganic compound

An inorganic compound is a chemical compound that is not an organic compound....
 polymerPolymer

Polymer is a term used to describe molecules consisting of structural units and a large number of repeating units connected ...
, noted for its many unusual characteristics: It bounces, but breaks when given a sharp blow. It can also flow like a liquid and will form a puddle given enough time. Silly Putty and most other retail putty products have thixtropic agents added to reduce the flow and enable the putty to hold its shape.

The original coral-colored Silly Putty is composed of 65% dimethyl siloxaneSiloxane

Siloxanes are a class of organosilicon compounds with the empirical formula R2SiO, where R is an organic group....
, 17% silica (crystalline quartz), 9% Thixatrol ST, 4% polydimethylsiloxanePolydimethylsiloxane

Polydimethylsiloxane is the most widely used silicon-based organic polymer, and is particularly known for its unusual rheolo...
, 1% decamethyl cyclopentasiloxaneCyclopentasiloxane

Cyclopentasiloxane is a silicone fluid commonly used in cosmetics such as Deodorant and Hair spray....
, 1% glycerine, and 1% titanium dioxideTitanium dioxide

Titanium dioxide, also known as titanium oxide or titania, is the naturally occurring oxide of titanium, chemica...
.

Silly Putty's unusual flow characteristics are due to the ingredient polydimethylsiloxanePolydimethylsiloxane

Polydimethylsiloxane is the most widely used silicon-based organic polymer, and is particularly known for its unusual rheolo...
 (PDMS), a viscoelastic liquid. Viscoelasticity is a type of non-Newtonian flowNon-Newtonian fluid

A non-Newtonian fluid is a fluid in which the viscosity changes with the applied strain rate....
, characterizing material that acts as a viscous liquidLiquid

A liquid is one of the main phases of matter....
 over a long time period but as an elastic solidSolid

A solid object is in the phase of matter characterized by resistance to deformation and changes of volume....
 over a short time period. Silly Putty has sometimes been characterized as a dilatantDilatant

A dilatant material is one in which viscosity increases with the rate of shear....
 fluid. However, according to the science of rheologyRheology

Rheology is the study of the deformation and flow of matter under the influence of an applied stress....
, this is not strictly correct and it is more accurate to characterize it as a viscoelastic or rheopectic liquid.

Silly Putty is also a fairly good adhesiveAdhesive

An adhesive is a compound that adheres or bonds two items together....
. When newspaperNewspaper

A newspaper is a publication containing news and information and advertising, usually printed on low-cost paper called newsp...
 ink was petroleum based, Silly Putty could be used to transfer newspaper images to other surfaces, possibly after introducing distortion. Newer papers with soy-based inks are more resistant to this activity.

Silly Putty will dissolve when in contact with an alcohol. After the alcohol evaporates, the material will not exhibit the original properties.

Silly Putty is sold as a 13 gram (0.47 ounce) piece of plastic clay inside an egg-shaped plastic container. It is available in various colors, including glow-in-the-darkGlow-in-the-dark

Glow-in-the-dark may refer to:*Bioluminescence - the production and emission of light by a living organism as the result of...
 and metallic. The brand is owned by Crayola LLC (formerly the Binney & Smith company), which also owns CrayolaCrayola

Crayola is a brand of crayons and other writing and drawing utensils, such as markers, chalk, and colored pencils manufactur...
 crayons. Today, twenty thousand eggs of Silly Putty are produced daily. Since 1950, more than 300 million eggs of Silly Putty have been sold, or approximately 4500 tons. Other Bouncing Putty brands offer the material in larger size containers and in a wide variety of colors.

History of Silly Putty

Silly Putty's origin was due to a wartime accident. During World War II, Japan invaded rubber producing countries in order to cut off the United States supply of rubber. It was needed in order to produce tires for vehicles, boots for soldiers, gas masks, rafts, and even bombers. To help combat the lack of rubber US citizens were asked to donate any rubber around their house such as spare tires, rubber boots, and rubber rain coats. All rubber made products were rationed and citizens had to make their products last till the end of the war. Also in response the government asked producers to try and come up with a synthetic rubber compound.

In 1943, James Wright, a Scottish engineer, worked for General Electric in a New Haven, Conn., laboratory. Combining a boric acid and silicone oil, Wright had ended up with a putty that had some unique properties. The putty would bounce when dropped, and could stretch farther than regular rubber, would not collect mold, and had a very high melting temperature. Unfortunately the substance did not contain the properties needed to replace rubber. In 1945, hoping there was a use for his new developed putty, Wright sent a sample to scientists all around the world, but no practical use was ever found.

Finally, in 1949, the putty reached the owner of a toy store, Ruth Fallgatter, who contacted Peter Hodgson, a marketing consultant, to produce her catalog and discuss bouncing putty. The two decided to market their bouncing putty selling it in a clear case for $2. The putty outsold every item in the catalogue except for 50-cent Crayola crayons. Despite the fortune it made, Fallgatter did not pursue it any more, but Hodgson saw its potential.

Already $12,000 in debt, Hodgson borrowed $147 to buy a batch of the putty to pack one ounce portions into plastic eggs for $1, calling it silly putty. After making progress in the industry, even selling over 250,000 eggs of silly putty in three days, Hodgson was almost put out of business in 1951 by the Korean War. Silicone, a main ingredient in silly putty, was put on ration, hurting his business. In 1952, a year later, the restriction on silicone was lifted and silly putty production resumed. In the beginning, its target market was mainly adults. However, by 1955 the majority of the consumers were aged 6 through 12. In 1957 Hodgson produced the first televised commercial for silly putty, which aired during the Howdy Doody ShowHowdy Doody Overview

Howdy Doody was a children's television program that aired on NBC from 1947 through 1960....
.

In 1961, Silly Putty went worldwide, becoming a hit in the Soviet Union, Germany, Italy, Netherlands, and Switzerland. Silly Putty went to the moon in 1968 with the Apollo 8 astronauts.

Peter Hodgson died in 1976. A year later, Binney and Smith, the makers of Crayola products, acquired the rights to Silly Putty. By 1987, Silly Putty had pushed sales to over two million eggs annually.

See also

  • DilatantDilatant

    A dilatant material is one in which viscosity increases with the rate of shear....
  • Non-Newtonian fluidNon-Newtonian fluid

    A non-Newtonian fluid is a fluid in which the viscosity changes with the applied strain rate....
  • ViscoelasticityViscoelasticity

    A viscoelastic material is one in which:...


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