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Potash



 
 
Potash is the common name given to potassium carbonate
Potassium carbonate

Potassium carbonate is a white salt, soluble in water , which forms a strongly alkaline solution. It can be made as the product of potassium hydroxide's absorbent reaction with carbon dioxide....
 and various mined and manufactured salts that contain the element potassium
Potassium

Potassium is a chemical element. It has the symbol K , atomic number 19, and atomic mass 39.0983. Potassium was first isolated from potash, hence the name....
 in water-soluble form.

Potash has been used since antiquity
Ancient history

Ancient history is the history from the History of writing until the Early Middle Ages in Europe, the Qin Dynasty in China, the Chola Empire in India, and some less defined point in the rest of the world ....
 in the manufacture of glass
Glass

Glass generally refers to a Hardness, brittle, transparency amorphous solid, such as that used for windows, many Glass Bottles, or eyewear, including, but not limited to, soda-lime glass, borosilicate glass, acrylic glass, sugar glass, Muscovite , or aluminium oxynitride....
, soap
SOAP

SOAP, originally defined as Simple Object Access Protocol, is a protocol specification for exchanging structured information in the implementation of Web Services in computer networks....
, and soil
Soil

Soil is the naturally occurring, unconsolidated or loose covering on the Earth's surface. Soil is composed of particles of broken rock that have been altered by chemical and environmental processes including weathering and erosion....
 fertilizer
Fertilizer

Fertilizers are chemical compounds given to plants to promote growth; they are usually applied either through the soil, for uptake by plant roots, or by foliar feeding, for uptake through leaves....
. Potash is vital for agriculture because it improves water retention, yield, nutrient value, taste, colour, texture and disease resistance of food crops.






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Potashusgov
Potash is the common name given to potassium carbonate
Potassium carbonate

Potassium carbonate is a white salt, soluble in water , which forms a strongly alkaline solution. It can be made as the product of potassium hydroxide's absorbent reaction with carbon dioxide....
 and various mined and manufactured salts that contain the element potassium
Potassium

Potassium is a chemical element. It has the symbol K , atomic number 19, and atomic mass 39.0983. Potassium was first isolated from potash, hence the name....
 in water-soluble form.

Potash has been used since antiquity
Ancient history

Ancient history is the history from the History of writing until the Early Middle Ages in Europe, the Qin Dynasty in China, the Chola Empire in India, and some less defined point in the rest of the world ....
 in the manufacture of glass
Glass

Glass generally refers to a Hardness, brittle, transparency amorphous solid, such as that used for windows, many Glass Bottles, or eyewear, including, but not limited to, soda-lime glass, borosilicate glass, acrylic glass, sugar glass, Muscovite , or aluminium oxynitride....
, soap
SOAP

SOAP, originally defined as Simple Object Access Protocol, is a protocol specification for exchanging structured information in the implementation of Web Services in computer networks....
, and soil
Soil

Soil is the naturally occurring, unconsolidated or loose covering on the Earth's surface. Soil is composed of particles of broken rock that have been altered by chemical and environmental processes including weathering and erosion....
 fertilizer
Fertilizer

Fertilizers are chemical compounds given to plants to promote growth; they are usually applied either through the soil, for uptake by plant roots, or by foliar feeding, for uptake through leaves....
. Potash is vital for agriculture because it improves water retention, yield, nutrient value, taste, colour, texture and disease resistance of food crops. It has wide application to fruit and vegetables, rice, wheat and other grains, sugar, corn, soybeans, palm oil and cotton, all of which benefit from the nutrient’s quality enhancing properties.

The name came from the old method of making potassium carbonate by leaching wood ashes and evaporating the solutions collected in large iron pots, leaving a white residue called "pot ash". Later, "potash" became the term widely applied to naturally occurring potassium salts and the commercial product derived from them.

To further confuse the terminology, potash imports/exports etc. are reported in 'K2O' equivalent, although fertilizer never contains potassium oxide, per se, because potassium oxide is caustic and so highly reactive that potassium oxide must be stored under kerosene
Kerosene

Kerosene, sometimes spelled kerosine in scientific and industrial usage, also known as paraffin, is a combustible hydrocarbon liquid....
, as with metallic potassium.

The following table lists a number of potassium compounds which use the word potash in their traditional names:
Common name Chemical name Formula
Potash fertilizer potassium oxide
Potassium oxide

Potassium oxide is a Chemical compound of potassium and oxygen. This pale yellow solid, the simplest oxide of potassium, is a rarely encountered, highly reactive species....
 
K2O
Caustic potash or potash lye potassium hydroxide
Potassium hydroxide

Potassium hydroxide is the inorganic compound with the formula potassiumhydroxide. Along with sodium hydroxide, this colourless solid is a prototypical "strong base"....
KOH
Carbonate of potash, salts of tartar, or pearlash   potassium carbonate
Potassium carbonate

Potassium carbonate is a white salt, soluble in water , which forms a strongly alkaline solution. It can be made as the product of potassium hydroxide's absorbent reaction with carbon dioxide....
K2CO3
Chlorate of potashpotassium chlorate
Potassium chlorate

Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the chemical formula KClO3. In pure form, it is a white crystalline substance....
 
KClO3
Muriate of potash potassium chloride
Potassium chloride

The chemical compound potassium chloride is a metal halide Salt composed of potassium and chlorine. In its pure state it is odorless. It has a white or colorless vitreous crystal, with a crystal structure that cleaves easily in three directions....
 
KCl
Nitrate of potash or saltpeterpotassium nitrate
Potassium nitrate

Potassium nitrate is a chemical compound with the chemical formula PotassiumNitrogenOxygen3. A naturally occurring mineral source of nitrogen, KNO3 constitutes a critical oxidation component of black powder/gunpowder....
 
KNO3
Sulfate of potash potassium sulfate
Potassium sulfate

Potassium sulfate is a flammable white crystalline salt which is Solubility in water.The chemical is commonly used in fertilizers, providing both potassium and sulfur....
 
K2SO4
Permanganate of potash potassium permanganate
Potassium permanganate

Potassium permanganate is the inorganic chemical compound potassiummanganeseoxygen4, a water soluble salt consisting of equal Mole amounts of potassium and permanganate ions....
 
KMnO4


Potash production and trade


History

Since the 14th century, potash was widely produced by Ethiopia
Ethiopia

Ethiopia , officially the Federal Democratic Republic of Ethiopia, is a landlocked country situated in the Horn of Africa. Ethiopia is bordered by Eritrea to the north, Sudan to the west, Kenya to the south, Somalia to the east and Djibouti to the northeast....
. It was their number one export up until the 20th century; however after the Ethiopian War against Kenya it became irrelevant. Potash was one of the most important industrial chemicals in Canada
Canada

Canada is a country occupying most of northern North America, extending from the Atlantic Ocean in the east to the Pacific Ocean in the west and northward into the Arctic Ocean....
. It was refined from the ashes of broadleaved trees and produced primarily in the forested areas of Europe, Russia
Russia

Russia , or the Russian Federation , is a list of countries spanning more than one continent country extending over much of northern Eurasia....
, and North America
North America

North America is the northern continent of the Americas, situated in the Earth's northern hemisphere and almost totally in the western hemisphere....
. The first U.S. patent
United States patent law

United States patent law was established "to promote the Progress of Science and useful Arts, by securing for limited Times to Authors and Inventors the exclusive Right to their respective Writings and Discoveries;" as provided in the United States Constitution....
 was issued in 1790 to Samuel Hopkins
Samuel Hopkins (inventor)

Samuel Hopkins was an United States inventor from Philadelphia, Pennsylvania, and Pittsford, Vermont. On July 31, 1790 he was granted the first U.S....
 for an improvement "in the making Pot ash and Pearl ash by a new Apparatus and Process."

Potash production provided late-18th and early-19th century settlers in North America a way to obtain badly needed cash and credit as they cleared their wooded land for crops. To make full use of their land, excess wood, including stumps, needed to be disposed. The easiest way to accomplish this was to burn any wood not needed for fuel or construction. Ashes from hardwood
Hardwood

The term hardwood is used to describe wood from non-monocot flowering plant trees and for those trees themselves. These are usually broad-leaved; in temperate and boreal latitudes they are mostly deciduous, but in tropics and subtropics mostly evergreen....
 trees could then be used to make lye
Potassium hydroxide

Potassium hydroxide is the inorganic compound with the formula potassiumhydroxide. Along with sodium hydroxide, this colourless solid is a prototypical "strong base"....
, which could either be used to make soap or boiled down to produce valuable potash. Hardwood could generate ashes at the rate of 60 to 100 bushel
Bushel

A bushel is a unit of dry measure, usually subdivided into eight local gallons in the systems of Imperial units and U.S. customary units. It is used for volumes of dry measure commodity, not liquids, most often in agriculture....
s per acre (500 to 900 m³/km²). In 1790, ashes could be sold for $3.25 to $6.25 per acre ($800 to $1500/km²) in rural New York State
New York

The State of New York is a U.S. state in the Mid-Atlantic States and Northeastern United States regions of the United States and is the nation's List of U.S....
 – nearly the same rate as hiring a laborer to clear the same area.

Potash as baking aid


Potash along with hartshorn
Ammonium bicarbonate

Ammonium bicarbonate, also called bicarbonate of ammonia, ammonium hydrogen carbonate, hartshorn, or powdered baking ammonia, is the bicarbonate salt of ammonia....
 was also used as a baking aid similar to baking soda
Sodium bicarbonate

Sodium bicarbonate or sodium hydrogen carbonate is the chemical compound with the formula NaHCO3. Sodium bicarbonate is a white solid that is crystalline but often appears as a fine powder....
 in old German baked goods such as Lebkuchen (ginger bread).

Potash in the modern era

In 2005, Canada
Canada

Canada is a country occupying most of northern North America, extending from the Atlantic Ocean in the east to the Pacific Ocean in the west and northward into the Arctic Ocean....
 was the largest producer of potash with almost one-fourth of the world share followed by Russia
Russia

Russia , or the Russian Federation , is a list of countries spanning more than one continent country extending over much of northern Eurasia....
 and Belarus
Belarus

Belarus is a landlocked country in Eastern Europe, bordered by Russia to the north and east, Ukraine to the south, Poland to the west, and Lithuania and Latvia to the north....
 in Soligorsk, reports the British Geological Survey
British Geological Survey

The British Geological Survey is a partly publicly-funded body which aims to advance geoscience knowledge of the United Kingdom landmass and its continental shelf by means of systematic surveying, monitoring and research....
. The most significant reserve of Canada's potash is located in the province of Saskatchewan
Saskatchewan

Saskatchewan is a prairie provinces in Canada, which has an area of 588,276.09 square kilometres and a population of 1,015,895 , mostly living in the southern half of the province....
 and controlled by the Potash Corporation of Saskatchewan
Potash Corporation of Saskatchewan

The Potash Corporation of Saskatchewan Inc. , today generally referred to as PotashCorp, is a Canadian corporation based in Saskatoon, Saskatchewan....
.

Unlike other producers, Israel
Israel

Israel officially the State of Israel , is a country in the Middle East located on the eastern shore of the Mediterranean Sea. It borders Lebanon in the north, Syria in the northeast, Jordan in the east, and Egypt on the southwest, and contains geographically diverse features within its relatively small area....
's Dead Sea Works
Dead Sea Works

The Dead Sea Works is the current name of the successor company to the Palestine Potash Company which was founded by Moshe Novomeysky in the 1920s -- for more detail on its foundation, see Moshe_Novomeysky#Palestine_Potash_Company...
 and Jordan
Jordan

Jordan , officially the Hashemite Kingdom of Jordan, is an Arab country in Southwest Asia spanning the southern part of the Syrian Desert down to the Gulf of Aqaba....
's Arab Potash Company
Arab Potash

Arab Potash is a company that is primarily involved in harvesting minerals from the Dead Sea. The company was formed in 1956 as a pan-Arab business venture and has a 100-year concession from the government of Jordan to manufacture and market mineral products derived from the Dead Sea....
 use solar evaporation pans in the Dead Sea
Dead Sea

For the Brian Keene book of the same name, see Dead Sea The Dead Sea is a salt lake between Israel and the West Bank to the west, and Jordan to the east....
 to produce carnallite
Carnallite

Carnallite is an evaporite mineral, a hydrated potassium magnesium chloride with formula: potassiummagnesiumchlorine3?6. It is variably colored yellow to white, reddish, and sometimes colorless or blue....
 from which potassium chloride
Potassium chloride

The chemical compound potassium chloride is a metal halide Salt composed of potassium and chlorine. In its pure state it is odorless. It has a white or colorless vitreous crystal, with a crystal structure that cleaves easily in three directions....
 is produced.

External links

  • , issued for a method of potash production
  • magazine article