Egyptian faience is a non-clay based
ceramicA ceramic is an inorganic, non-metallic solid prepared by the action of heat and subsequent cooling. Ceramic materials may have a crystalline or partly crystalline structure, or may be amorphous...
displaying surface
vitrificationVitrification is the transition of a substance into a glass. Vitrification may also refer to:*Vitrification, the transformation of radioactive waste into a stable state for storage*Vitrification, the use of an antifreeze-like liquid in cryopreservation...
which creates a bright lustre of various colours. Having not been made from clay it is often not classed as
potteryPottery is the ceramic ware made by potters. Major types of pottery include earthenware, stoneware, and porcelain. The places where such wares are made are called potteries. Pottery is one of the oldest human technologies and art-forms, and remains a major industry today...
. It is called "Egyptian faience" to distinguish it from
faienceFaience or faïence is the conventional name in English for fine tin-glazed pottery on a delicate pale buff body, associated with Faenza in northern Italy. The invention of a white pottery glaze suitable for painted decoration, by the addition of an oxide of tin to the slip of a lead glaze, was a...
, the
tin glazed potteryTin-glazed pottery is pottery covered in glaze containing tin oxide which is white, shiny and opaque. The pottery body is usually made of red or buff colored earthenware and the white glaze was often used to imitate Chinese porcelain...
associated with
FaenzaFaenza is an Italian city and comune, in the province of Ravenna, Emilia-Romagna, situated 50 km southeast of Bologna.Faenza is noted for its manufacture of majolica ware glazed earthenware pottery, known from the name of the town as "faience"....
in northern Italy. Egyptian faience, both locally produced and exported from Egypt, occurs widely in the ancient world, and is well known from Mesopotamia, the Mediterranean and in northern Europe as far away as Scotland.
Introduction
From the inception of faience in the archaeological record of
Ancient EgyptAncient Egypt was an ancient civilization of eastern North Africa, concentrated along the lower reaches of the Nile River in what is now the modern country of Egypt. The civilization coalesced around 3150 BC with the political unification of Upper and Lower Egypt under the first pharaoh, and...
, the elected colors of the
glazeGlaze or glazing is a thin shiny coating, or the act of applying the coating; it may refer to:In materials or engineering:* Architectural glass, a building material typically used as transparent glazing material in the building envelope...
s varied within an array of blue-green hues. Glazed in these colours, faience was perceived as substitute for blue-green materials such as
turquoiseTurquoise is an opaque, blue-to-green mineral that is a hydrous phosphate of copper and aluminium, with the chemical formula CuAl
648·4. It is rare and valuable in finer grades and has been prized as a gem and ornamental stone for thousands of years owing to its...
, found in the Sinai peninsula, and
lapis lazuliLapis lazuli is a relatively rare, semi-precious stone that has been prized since antiquity for its intense blue color....
, from
AfghanistanThe Islamic Republic of Afghanistan is a landlocked country in south central Asia. It is variously described as being located within Central Asia, South Asia, or the Middle East...
. As early as the Predynastic graves at
NaqadaNaqada is a town on the west bank of the Nile in the Egyptian governorate of Qena. It was known in Ancient Egypt as Nubt and in classical antiquity as Ombos. Its name derives from ancient Egyptian nub, meaning gold, on account of the proximity of gold mines in the Eastern Desert.Naqada comprises...
, Badar,el-Amrah, Matmar, Harageh, Avadiyedh and El-Gerzeh, glazed steatite and faience beads are found associated with these semi-precious stones. The association of faience with turquoise and lapis lazuli becomes even more conspicuous in Quennou's funerary papyrus, giving his title as the director of overseer of faience-making, using the word which strictly means lapis lazuli, which by the
New KingdomThe New Kingdom, sometimes referred to as the Egyptian Empire, is the period in ancient Egyptian history between the 16th century BC and the 11th century BC, covering the Eighteenth, Nineteenth, and Twentieth Dynasties of Egypt. The New Kingdom followed the Second Intermediate Period and was...
had also come to refer to the 'substitute', faience. The symbolism embedded in blue glazing could recall both the
NileThe Nile is a major north-flowing river in Africa, generally regarded as the longest river in the world....
, the waters of
heavenHeaven may refer to the physical heavens, the sky or the seemingly endless expanse of the universe beyond. This is the traditional literal meaning of the term in English...
and the home of the
godGod is a deity in theistic and deistic religions and other belief systems, representing either the sole deity in monotheism, or a principal deity in polytheism....
s, whereas green could possibly evoke images of regeneration, rebirth and vegetation.
Relationship with Egyptian copper industry
The discovery of faience glazing has tentatively been associated with the
copperCopper is a chemical element with the symbol Cu and atomic number 29.It is a ductile metal with very high thermal and electrical conductivity. Pure copper is rather soft and malleable and a freshly-exposed surface has a pinkish or peachy color...
industry:
bronzeBronze is a metal alloy consisting primarily of copper, usually with tin as the main additive, but sometimes with other elements such as phosphorus, manganese, aluminium, or silicon. It was particularly significant in antiquity, giving its name to the Bronze Age...
scale and corrosion products of leaded copper objects are found in the manufacture of faience
pigmentA pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, in which a material emits light.Many materials selectively absorb...
s. However, although the likelihood of glazed
quartzQuartz is the second most abundant mineral in the Earth's continental crust . It is made up of a continuous framework of SiO
4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO
2.There are many different varieties of...
pebbles developing accidentally in traces in copper
smeltingSmelting is a form of extractive metallurgy; its main use is to produce a metal from its ore. This includes iron extraction from iron ore, and copper extraction and other base metals from their ores...
furnaceA furnace is a device used for heating. The name derives from Latin fornax, oven. The earliest furnace was excavated at Balakot, a site of the Indus Valley Civilization, dating back to its mature phase...
s from the copper and wood ash is high, the regions in which these processes originate do not coincide.
Relationship with Egyptian glass industry
Although it appears no
glassIn general Glass refers to a solid, brittle, transparent material, commonly used for windows, bottles, or eyewear. Examples of glassy materials include, but are not limited to, soda-lime glass, borosilicate glass, acrylic glass, sugar glass, Muscovy-glass, or aluminium oxynitride. The term glass...
was intentionally produced in Egypt prior to the 18th dynasty, it is likely that faience,
fritFrit is a ceramic composition that has been fused, quenched to form a glass, and granulated. Frits form an important part of the batches used in compounding enamels and ceramic glazes; the purpose of this pre-fusion is to render any soluble and/or toxic components insoluble by causing them to...
and glass were all made in close proximity or in the same workshop complex, seeing as developments in one industry are reflected in others.. Such close relationship is reflected in the prominent similarity of the formulations of faience glaze and contemporary glass compositions. Despite the differences in the pyrotechnology of glass and faience, the latter being worked cold, archaeological evidence suggests that
New KingdomThe New Kingdom, sometimes referred to as the Egyptian Empire, is the period in ancient Egyptian history between the 16th century BC and the 11th century BC, covering the Eighteenth, Nineteenth, and Twentieth Dynasties of Egypt. The New Kingdom followed the Second Intermediate Period and was...
glass and faience production was undertaken in the same workshops.
Typical composition and access to raw materials
Faience has been defined as the first high technology ceramic, to emphasize its status as an artificial medium, rendering it effectively a precious stone. Egyptian faience is a non-clay based ceramic composed of crushed quartz or sand, with small amounts of
calciteCalcite is a carbonate mineral and the most stable polymorph of calcium carbonate . The other polymorphs are the minerals aragonite and vaterite. Aragonite will change to calcite at 470°C, and vaterite is even less stable....
lime and a mixture of
alkaliIn chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Alkalis are best known for being bases that dissolve in water. Bases are compounds with a pH greater than 7. The adjective alkaline is commonly used in English as a synonym for base, especially for...
s, displaying surface
vitrificationVitrification is the transition of a substance into a glass. Vitrification may also refer to:*Vitrification, the transformation of radioactive waste into a stable state for storage*Vitrification, the use of an antifreeze-like liquid in cryopreservation...
due to the
sodaSoda refers to:* a chemical compound containing sodium** Sodium carbonate, washing soda or soda ash** Sodium bicarbonate, baking soda** Sodium hydroxide, caustic soda** Sodium oxide* Soft drinks* Soda water, carbonated water...
lime silica
glazeGlaze or glazing is a thin shiny coating, or the act of applying the coating; it may refer to:In materials or engineering:* Architectural glass, a building material typically used as transparent glazing material in the building envelope...
often composed of copper pigments to create a bright blue-green luster. While in most instances domestic ores seem to have provided the bulk of the mineral pigments, evidence suggests that during periods of prosperity raw materials also available locally, such as lead and copper, were imported. Plant ash, from halophitic plants typical of dry and sea areas, was the major source of alkali until the Ptolemaic Period, when natron based alkalis almost completely replaced the previous source. Although the chemical composition of faience materials varies over time and according to the status of the workshop, also as a cause of change of accessibility of raw materials, the material constitution of the glaze is at all times consistent with the generally accepted version of faience glazing.
Faience working technology
Typical faience mixture is thixotropic, that is thick at first and then soft and flowing as it begins to be formed.
This property, together with the angularity of silica particles accounts for the gritty slumps formed when the material is wetted, rendering faience a difficult material to hold a shape. If pressed too vigorously this material will resist flow until it yields and cracks, due to its limited plastic deformation and low yield strength.
Body binding technology
A number of possible binding agents, amongst Arabic gum, clay, lime, egg white and resin, have been suggested to help in the binding process. Although traces of clay have been found in most Pharaonic faience, reconstruction experiments showed that clay, organic gums or lime while successfully improving the wet working performance, failed to improve the fired strength of the faience, or proved the gum was too sticky for the removal of objects from their molds. The use of alkalis as binders, in the form of natron or plant ash, produced suitable results in experiments. Pulverized glass or sintered material of similar composition could also enhance the fired strength of faience bodies: the compositions of such glasses is in fact comparable to the published compositions of New Kingdom glass.
Body working technology
Three methods have been hypothesized to shape the body of faience objects: modeling, moulding and abrasion, the last being used in the conjunction with the first two. Modeling, scraping and grinding are the techniques most widely used in earlier times, as represented in the material qualities of Predynastic and Protodynastic faience objects. Predynastic bead manufacture is essentially a cold technology, more akin to stone working than glass: a general form of faience is modeled, possibly free formed by hand, then holes are drilled to create beads.
In the Middle Kingdom, the techniques employed are molding and forming on a core, sometimes in conjunction with intermediate layers between the glaze and the body. Marbleized faience, resulting from the working of different colored faience bodies together, as to produce a uniform adherent body, also appears in this period. Towards the end of the Middle Kingdom, incising, inlaying and resisting techniques appear: bound to become progressively popular towards the New Kingdom. In the New Kingdom, beads, amulets and finger rings are produced by a combination of modeling and molding techniques. In this period, sculptural detail was created using inlays of different colored faience or by scraping the body to reveal the white intermediate layer in relief. Moulding was first applied to faience manufacture in the Middle Kingdom by forming a model of an object, or employing a finished faience piece, impressing it in wet clay, and later by firing the clay to create a durable mold. The faience paste could then be pressed into the mold, and following drying, be re-worked through surface abrasion before firing. Moulds could facilitate mass production of faience objects such as amulets rings and inlays, as evidenced by the several thousand of small open face, earth-ware clay molds excavated at Tell el Amarna.
Wheel throwing, possibly occurring from the New Kingdom onwards, is certainly established by the Greco-Romano period, when large amounts of clay seems to have been added to the faience body.. Because of the limited plasticity of faience, rendering throwing extremely difficult, a progressive increase of clay in the faience bodies culminating in the quartz, clay and glass frit bodies of Islamic times, is observed in the archaeological record.
Ptolemaic and Roman faience tends to be typologically and technologically distinct from the earlier material: it is characterized by the widespread use of moulding and high relief on vessels.
Glazing technology
The technology of glazing a siliceous body with a soda lime silica glaze, employs various methods discovered over time: namely application, efflorescence and cementation glazing.
Application glazing
In the application method, formerly assumed to be the only one used for faience glazing; silica, lime and alkalis are ground in the raw state to a small particle size, thus mixed in water to form a slurry which is then applied to the quartz core. Partial fritting of the slurry favors the first stages of vitrification, which in turn lowers the final firing temperature. The slurry can be then applied to the body, through brushing or dipping, to create a fine, powdery coating. Upon firing, the water from the melting glaze partially diffuses in the sand body, sintering the quartz particles and thus creating some solid bridges in the body.
Efflorescence of glazing
In the self-glazing process of efflorescence, the glazing materials, in the form of water-soluble alkali salts, are mixed with the raw crushed quartz of the core of the object. As the water in the body evaporates, the salts migrate to the surface of the object to recrystallize, creating a thin surface, which glazes upon firing.
Cementation glazing
Cementation glazing, a technique discovered in the Middle Kingdom, is also a self-glazing technique. The possibility of the existence of cementation glazing, also known as 'Qom technique', followed the observation of this method in use at the village of '
QomQom is a city in Iran. It lies by road southwest of Tehran and is the capital of Qom Province. It has an estimated population of 1,042,309 in 2005...
' in Iran in 1960s. In this method the artifact, while buried in a glazing powder with a high flux content, is heated inside a vessel, causing the fusion of the object with the cement. During firing, the flux migrates to the quartz and precipitates as glass.
Alternative techniques
A vapour glaze reaction similar to salt glazing is an alternative glazing process, has been suggested. In this process, the vaporization or dissociation of salts leads to vapour transport through the enveloping powder to the quartz body where a glaze is formed.
Recognition of glazing techniques
Although glaze compositions vary regionally and chronologically, depending on the formation of the body and the glazing process employed, objects produced with different glazing techniques do not exhibit immediate diagnostic chemical variations in their compositions.The recognition of the various glazing techniques, through microscopic observations of the degree of sintering and the vitreous phase of quartz body, is also ambiguous. For instance, objects with applied glazes and those which may have been glazed by efflorescence have overlapping characteristic features. The following proposed criteria are subject to variation caused by increases in flux concentration, firing temperatures and time at peak temperatures.
Recognition of application glazing- Macroscopically, applied glazes vary in thickness through the body, displaying thicker glazes on bases. The traces of kiln supports, as well as the characteristic tendency to run and drip leading to pooling, may indicate the orientation of the object during firing. In high magnification observations, the interface boundary of body and glaze appears well defined. The absence of interstitial glass in the core is characteristic of application glazing: however, the possibility of adding glazing mixture to the quartz sand body, as well as the use of pre-melted glazes in the later periods, can predictably increase the degree of sintering of the core
Recognition of cementation- Objects glazed through cementation display a thin even glaze all over the body, with no drying or firing marks, and portray a fairly friable and soft body Microscopically, the concentration of copper characteristically decreases from the surface: the interaction layer is thin and well defined and the interstitial glass is absent with exception to the vicinity of the boundary layer.
Recognition of efflorescence glazing- Pieces glazed by efflorescence may show traces of stand marks: the glaze appears thick and prone to cracking, thinning toward the edge of the piece and in concave areas. In high magnification the interstitial glass is extensive; the unreacted salts which have not reached the surface fuse of the body accumulate in the core, creating bridges between the quartz particles.
Typologies
An extensive literature has accumulated in attempt to explain the processing of Egyptian faience and develop an adequate typology that encompasses both technological choices and chemical variations of faience bodies . Body color, density and luster provided the basis of the first typology developed for faience: seven variants were proposed and still permit to distinguish faience objects during field sorting
Classification of body variants
Most of the categories introduced by Lucas fail to recognize the glazing technology utilized or suggest the stylistic and technological choices embedded in the manufacture of a faience object. However, variant A describes a technologically unique product and as such is still applicable: it has a finely ground underglaze consisting of quartz particles in a glass matrix, often revealed by incisions or depressions cut into the overlying glaze. Glassy faience, variant E, displays no distinct outer layer from the interior, thus it has been suggested that the term 'faience' is a misnomer and the alternative name 'imperfect glass' has been advised. Regarding variant F specimens, Lucas suggests the use of lead glazes, however it appears that lead was never practiced in Ancient Egypt.
Workshop evidence
The excavations led by Petrie at Tell-Amarna and Naucratis have reported finding workshop evidence. Lucas documented a large number of molds at the palace area of Amenhotep III, at Qantir from Dynasties 19-20 and at the palace area of Naucratis also described in different sources as a scarab maker's and faience factory. However, seeing as there is a lack of carefully documented archaeological evidence as to the nature of faience factory sites, direct information about the glazing process does not exist.
Although recent excavations at the archaeological sites of Abydos and Amarna have supplemented our knowledge of the ancient production of faience gained from the earlier excavated sites of Lisht, Memphis and Naukratis, the differentiation of glass furnaces from faience kilns still remains problematic. Replication experiments, using modern kilns and replica faience pastes, indicate that faience is fired in the range of 800-1000°