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Soda-lime glass

 

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Soda-lime glass


 
 



Soda-lime glass, also called soda-lime-silica glass, is the most prevalent type of glassGlass Summary

Glass is a uniform amorphous solid material, usually produced when the viscous molten material cools very rapidly to below i...
, used for windowpanes, and glass containers (bottles and jars) for beverages, food, and some commodity items. Also PyrexPyrex

Pyrex® is a brand name of borosilicate glass introduced by Corning Glass Works in 1924....
 brand kitchen glassware manufactured since 1998 (when the brand was spun off under World KitchenWorld Kitchen Summary

World Kitchen, LLC is a kitchenware products maker and distributor based in Reston, Virginia....
) is made of soda-lime glass (previously, it was made of better quality, thermal shockThermal shock Overview

Thermal shock is the name given to cracking as a result of rapid temperature change....
 resistant borosilicate glassBorosilicate glass

Borosilicate glass is a particular type of glass, better known under the brand names Pyrex, Kimax, and Endural....
).

Soda-lime glass is prepared by melting the raw materialsGlass

Glass is a uniform amorphous solid material, usually produced when the viscous molten material cools very rapidly to below i...
, such as sodaSodium carbonate

Sodium carbonate, , is a sodium salt of carbonic acid....
, limeLime (mineral)

Lime is a general term for various naturally occurring minerals and materials derived from them, in which carbonates, oxides...
, silica, alumina, and small quantities of fining agents (e.g., sodium sulfateSodium sulfate

Sodium sulfate is an important compound of sodium....
, sodium chlorideSodium chloride Summary

Sodium chloride, also known as common salt, table salt, or halite, is a chemical compound with the formula NaCl....
) in a glass furnaceGlass container industry

Glass containers are a common part of everyday life - we enjoy beverages such as water, soft drink, juice, beer, wine, spiri...
 at temperatures locally up to 1675°C. The temperature is only limited by the quality of the furnace superstructure material and by the glass composition. Green and brown bottles are obtained from raw materials containing iron oxideIron oxide

Altogether there are 16 known iron oxides....
. For lowering the price of the raw materials, pure chemicals are not used, but relatively inexpensive minerals such as tronaTrona

Trona, hydrated sodium bicarbonate carbonate, is an evaporite mineral....
, sandSand Overview

Sand is an example of a class of materials called granular matter....
, and feldsparFeldspar

Feldspar is the name of an important group of rock-forming minerals which make up perhaps as much as 60% of the Earth's crus...
. The mix of raw materials is termed batchGlass container industry

Glass containers are a common part of everyday life - we enjoy beverages such as water, soft drink, juice, beer, wine, spiri...
.

Soda-lime glass is divided technically into glass used for windows, called float glassFloat glass

Float glass is sheet glass made by floating the molten glass on a bed of molten tin....
or flat glassFlat glass Summary

Flat glass, sheet glass, or plate glass is a type of glass, initially produced in plane form, commonly used for ...
, and glass for containers, called container glassContainer glass

Container glass is a type of glass for the production of glass containers, such as bottles, jars, drinkware, and bowls...
. Both types differ in the application, production method, and chemical composition (see table below). Float glass has a higher magnesium oxideMagnesium oxide Overview

Magnesium oxide is a white solid mineral that occurs naturally as periclase and is a source of magnesium....
 and sodium oxideSodium oxide

Sodium oxide has formula Na2O. It is also called sodium oxide, disodium oxide, sodium monoxide, and soda....
 content as compared to container glass, and a lower silica, calcium oxideCalcium oxide Summary

Calcium oxide, commonly known as lime, quicklime or burnt lime, is a widely used chemical compound....
, and aluminium oxideAluminium oxide

Aluminium oxide is a chemical compound of aluminium and oxygen with the chemical formula 23....
 content. From this follows a slightly higher quality of container glass concerning the chemical durability against water (see table), which is required especially for storage of beverages and food.

Typical compositions and properties

The following table lists some physical properties soda-lime glasses. Unless otherwise stated, the glass compositions and many experimentally determined properties are taken from one large study. Those values marked in italic font have been interpolated from sililar glass compositions (see calculation of glass propertiesCalculation of glass properties

The calculation of glass properties is used to predict glass properties of interest or glass behavior under certain conditi...
) due to the lack of experimental data.

Properties Soda-lime glass
for containersContainer glass

Container glass is a type of glass for the production of glass containers, such as bottles, jars, drinkware, and bowls...
Soda-lime glass
for windowWindow

----A window is an opening in an otherwise solid and opaque surface through which light and, sometimes, air can pass....
s
Chemical
composition,
wt%
74 SiO2Silicon dioxide

The chemical compound silicon dioxide, also known as silica, is the oxide of silicon, chemical formula SiO2....
, 13 Na2OFacts About Sodium oxide

Sodium oxide has formula Na2O. It is also called sodium oxide, disodium oxide, sodium monoxide, and soda....
,
10.5 CaOCalcium oxide

Calcium oxide, commonly known as lime, quicklime or burnt lime, is a widely used chemical compound....
, 1.3 Al2O3Aluminium oxide

Aluminium oxide is a chemical compound of aluminium and oxygen with the chemical formula 23....
,
0.3 K2OPotassium oxide Summary

Potassium oxide is a compound of potassium and oxygen used mainly as an intermediate in inorganic synthesis....
, 0.2 SO3Sulfur trioxide

Sulfur trioxide has the chemical formula SO3....
,
0.2 MgOMagnesium oxide

Magnesium oxide is a white solid mineral that occurs naturally as periclase and is a source of magnesium....
, 0.01 TiO2Titanium dioxide

Titanium dioxide, also known as titanium oxide or titania, is the naturally occurring oxide of titanium, chemica...
,
0.04 Fe2O3Iron(III) oxide

Iron oxide also known as ferric oxide, 'Hematite, 'red iron oxide, 'synthetic maghemite, 'colcothar'...
73 SiO2, 14 Na2O,
9 CaO, 0.15 Al2O3,
0.03 K2O, 4 MgO,
0.02 TiO2, 0.1 Fe2O3
ViscosityViscosity

Viscosity is a measure of the resistance of a fluid to deform under shear stress....

log(?, Pa·s) = A +
B / (T in °C - To)
550-1450°C:
A = -2.309
B = 3922
To = 291
550-1450°C:
A = -2.585
B = 4215
To = 263
Glass transitionFacts About Glass transition temperature

A materials glass transition temperature, Tg, is the temperature below which molecules have little relative mobility....

temperatureGlass transition temperature

A materials glass transition temperature, Tg, is the temperature below which molecules have little relative mobility....
, Tg, °C
573 564
Coefficient ofCoefficient of thermal expansion

During heat transfer, the energy that is stored in the intermolecular bonds between atoms changes....

thermal expansionCoefficient of thermal expansion Overview

During heat transfer, the energy that is stored in the intermolecular bonds between atoms changes....
,
ppm/K, ~100-300°C
9 9.5
DensityDensity

Density is a measure of mass per unit of volume....

at 20°C, g/cm3
2.52 2.53
Refractive indexRefractive index

The refractive index of a material is the factor by which the phase velocity of electromagnetic radiation is slowed in that...

nD at 20°C
1.518 1.520
DispersionDispersion (optics) Overview

In optics, dispersion is a phenomenon that causes the separation of a wave into spectral components with different wavelengt...
 at 20°C,
104×(nF-nC)
86.7 87.7
Young's modulusFacts About Young's modulus

In solid mechanics, Young's Modulus is a measure of the stiffness of a given material....

at 20°C, GPa
72 74
Shear modulusShear modulus

In materials science, shear modulus, G, or sometimes S, sometimes referred to as the modulus of rigidity, is d...

at 20°C, GPa
29.8 29.8
LiquidusLiquidus temperature

The liquidus temperature, TL or Tliq, is mostly used for glasses and alloys....

temperatureLiquidus temperature

The liquidus temperature, TL or Tliq, is mostly used for glasses and alloys....
, °C
1040 1000
HeatHeat capacity

Heat capacity is a measurable physical quantity that characterizes the ability of a body to store heat as it changes in temp...

capacityHeat capacity

Heat capacity is a measurable physical quantity that characterizes the ability of a body to store heat as it changes in temp...
 at 20°C,
J/(mol·K)
49 48
Surface tensionSurface tension Summary

In physics, surface tension is an effect within the surface layer of a liquid that causes that layer to behave as an elastic...
,
at ~1300°C, mJ/m2
315 
Chemical durability,
Hydrolytic classCorrosion

Corrosion is deterioration of intrinsic properties in a material due to reactions with its environment....
,
after ISO 719
3 3...4


Coefficient of Restitution (glass sphere vs. glass wall): 0.97 ± 0.01

Thermal Conductivity: 0.9-1.3 W/m.K

Hardness (Mohs Scale): 6–7

Knoop Hardness: 585 kg/mm2 + 20

See also

  • Glass batch calculationGlass batch calculation

    Glass batch calculation or glass batching is used to determine the correct mix of raw materials for a glass melt....