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Dye laser
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A dye laser is a laser which uses an organic dye as the lasing medium, usually as a liquid solution. Compared to gases and most solid state lasing media, a dye can usually be used for a much wider range of wavelengths. The wide bandwidth makes them particularly suitable for tunable lasers and pulsed lasers.
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Encyclopedia
A dye laser is a laser which uses an organic dye as the lasing medium, usually as a liquid solution. Compared to gases and most solid state lasing media, a dye can usually be used for a much wider range of wavelengths. The wide bandwidth makes them particularly suitable for tunable lasers and pulsed lasers. Moreover, the dye can be replaced by another type in order to generate different wavelengths with the same laser, although this usually requires replacing other optical components in the laser as well.
Dye lasers are also used dermatologically, to make skin tone more even.
Construction
A dye laser is comprised of an organic dye mixed with a solvent, which may be circulated through a dye cell, or streamed through open air using a dye jet. A high energy source of light is needed to ‘pump’ the liquid beyond its lasing threshold. A high speed flash lamp or an external laser is usually used for this purpose. Mirrors are also needed to oscillate the light produced by the dye’s fluorescence, which is amplified with each pass through the liquid. The output mirror is normally around 80% reflective, while all other mirrors are usually more than 99% reflective. The dye solution is usually circulated at high speeds, to help avoid triplet absorption and to decrease degradation of the dye. A prism or diffraction grating is usually mounted in the beam path, to allow tuning of the beam.
Because the liquid medium of a dye laser can fit any shape, there are a multitude of different configurations that can be used. A Fabry-Perot laser cavity is usually used for flash lamp pumped lasers, which consists of two mirrors, which may be flat or curved, mounted parallel to each other, with the laser medium in between. The dye cell is usually side-pumped, with one or more flash lamps running parallel to the dye cell in a reflector cavity. The reflector cavity is often water cooled, to prevent thermal shock in the dye caused by the large amounts of near-infrared radiation which the flash lamp produces. Axial pumped lasers have a flash lamp that surrounds the dye cell, which has lower inductance for a shorter flash, and improved transfer efficiency. Coaxial pumped lasers have a dye cell that surrounds the flash lamp, for even better transfer efficiency, but have a lower gain due to diffraction losses. Flash pumped lasers can only be used for pulsed output.
A ring laser design is often chosen for continuous operation, although a Fabry-Perot design is sometimes used. In a ring laser, the mirrors of the laser are positioned to allow the beam to travel in a circular path. The dye cell, or cuvette, is usually very small. Sometimes a dye jet is used to help avoid reflection losses. The dye is usually pumped with an external laser, such as a nitrogen, excimer, or frequency doubled Nd:YAG laser. The liquid is circulated at very high speeds, to prevent triplet absorption from cutting off the beam.
Operation
The dyes used in these lasers contain rather large organic molecules which fluoresce when exposed to the proper frequency of light. Dyes will emit stimulated radiation when the molecules are in their singlet state. In this state, the molecules emit light via fluorescence, and the dye is quite clear to the lasing wavelength. Within a microsecond, or less, the molecules will change to their triplet state. In the triplet state, light is emitted via phosphorescence, and the molecules begin to absorb the lasing wavelength, making the dye opaque. Liquid dyes also have an extremely high lasing threshold. Flash lamp pumped lasers need a flash with an extremely short duration, to deliver the large amounts of energy necessary to bring the dye past threshold before triplet absorption overcomes singlet emission. Dye lasers with an external pump laser can direct enough energy of the proper wavelength into the dye with a relatively small amount of input energy, but the dye must be circulated at high speeds to keep the triplet molecules out of the beam path.
Since organic dyes tend to degrade under the influence of light, the dye solution is normally circulated from a large reservoir. The dye solution can be flowing through a cuvette, i.e., a glass container, or be as a dye jet, i.e., as a sheet-like stream in open air from a specially-shaped nozzle. With a dye jet, one avoids reflection losses from the glass surfaces and contamination of the walls of the cuvette. These advantages come at the cost of a more-complicated alignment. Dye lasers emission is inherently broad. In order to produce narrow bandwidth tuning these lasers use many types of cavities and resonators which include gratings, prisms, and etalons.
Liquid dyes are very high gain laser mediums. The beam only needs to make a few passes through the liquid for high gains in power, and hence, the high transmittance of the output coupler. This high gain nature also leads to very high losses, as any reflections generated by the dye cell walls, or flashlamp reflector, will dramatically reduce the amount of energy available to the beam. Pumping cavities are often coated, anodized, or otherwise made of a material that will absorb the lasing wavelength while effectively reflecting the pumping energy.
Chemicals used
Some of the dyes are rhodamine, fluorescein, coumarin, stilbene, umbelliferone, tetracene, malachite green, and others. While some dyes are actually used in food coloring, most dyes are very toxic, and often carcinogenic. Many dyes, such as rhodamine 6G, (in its chloride form), can be very corrosive to all metals except stainless steel.
A wide variety of solvents can be used, although some dyes will dissolve better in some solvents than in others. Some of the solvents used are water, glycol, ethanol, methanol, hexane, cyclohexane, cyclodextrin, and many others. Solvents are often highly toxic, and can sometimes be absorbed directly through the skin, or through inhaled vapors. Many solvents are also extremely flammable.
Adamantane is added to some dyes to prolong their life.
Cycloheptatriene and cyclooctatetraene (COT) can be added as triplet quenchers for rhodamine G, increasing the laser output power. Output power of 1.4 kilowatt at 585 nm was achieved using Rhodamine 6G with COT in methanol-water solution.
Ultra-short optical pulses
R. L. Fork, B. I. Greene, and C. V. Shank have demonstrated, in 1981, the generation of ultra-short laser pulse using a ring-dye laser (or dye laser exploiting colliding pulse mode-locking). Such kind of laser is capable of generating laser pulses of ~ 0.1 ps duration.
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