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Chemosynthesis



 
 
Chemosynthesis is the biological conversion of one or more carbon molecules (usually carbon dioxide
Carbon dioxide

Carbon dioxide is a chemical compound composed of two oxygen atoms covalent bond to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state....
 or methane
Methane

Methane is a chemical compound with the molecular formula . It is the simplest alkane, and the principal component of natural gas. Methane's bond angles are 109.5 degrees....
) and nutrients into organic matter using the oxidation of inorganic molecules (e.g. hydrogen
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
 gas, hydrogen sulfide
Hydrogen sulfide

Hydrogen sulfide is the chemical compound with the chemical formula Hydrogen2Sulfur. This colorless, toxic and flammable gas is partially responsible for the foul odor of egg and flatulence....
) or methane as a source of energy, rather than sunlight, as in photosynthesis
Photosynthesis

File:Seawifs global biosphere.jpgPhotosynthesis is a metabolic pathway that converts carbon dioxide into organic compounds, especially sugars, using the energy from sunlight....
. Chemoautotrophs
Chemotroph

Chemotrophs are organisms that obtain energy by the oxidation of electron donating molecules in their environments. These molecules can be organic molecule or inorganic ....
 organism
Organism

In biology, an organism is any life thing . In at least some form, all organisms are capable of response to stimulus , reproduction, growth and developmental biology, and maintenance of homeostasis as a stable whole....
s that obtain carbon through chemosynthesis are phylogenetically diverse, but groups that include conspicuous or biogeochemically-important taxa include the sulfur-oxidizing gamma and epsilon proteobacteria, the Aquificae
Aquificae

The Aquificae phylum is a diverse collection of bacteria that live in harsh environmental settings. They have been found in hot springs, sulfur pools, and thermal ocean vents....
les, the Methanogen
Methanogen

Methanogens are archaea that produce methane as a metabolic byproduct in anoxic conditions. They are common in wetlands, where they are responsible for marsh gas, and in the guts of animals such as ruminants and humans, where they are responsible for the methane content of flatulence....
ic archaea and the neutrophilic iron-oxidizing bacteria.

Many microorganisms in dark regions of the oceans use chemosynthesis to produce biomass from 1-carbon molecules.






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Chemosynthesis is the biological conversion of one or more carbon molecules (usually carbon dioxide
Carbon dioxide

Carbon dioxide is a chemical compound composed of two oxygen atoms covalent bond to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state....
 or methane
Methane

Methane is a chemical compound with the molecular formula . It is the simplest alkane, and the principal component of natural gas. Methane's bond angles are 109.5 degrees....
) and nutrients into organic matter using the oxidation of inorganic molecules (e.g. hydrogen
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
 gas, hydrogen sulfide
Hydrogen sulfide

Hydrogen sulfide is the chemical compound with the chemical formula Hydrogen2Sulfur. This colorless, toxic and flammable gas is partially responsible for the foul odor of egg and flatulence....
) or methane as a source of energy, rather than sunlight, as in photosynthesis
Photosynthesis

File:Seawifs global biosphere.jpgPhotosynthesis is a metabolic pathway that converts carbon dioxide into organic compounds, especially sugars, using the energy from sunlight....
. Chemoautotrophs
Chemotroph

Chemotrophs are organisms that obtain energy by the oxidation of electron donating molecules in their environments. These molecules can be organic molecule or inorganic ....
 organism
Organism

In biology, an organism is any life thing . In at least some form, all organisms are capable of response to stimulus , reproduction, growth and developmental biology, and maintenance of homeostasis as a stable whole....
s that obtain carbon through chemosynthesis are phylogenetically diverse, but groups that include conspicuous or biogeochemically-important taxa include the sulfur-oxidizing gamma and epsilon proteobacteria, the Aquificae
Aquificae

The Aquificae phylum is a diverse collection of bacteria that live in harsh environmental settings. They have been found in hot springs, sulfur pools, and thermal ocean vents....
les, the Methanogen
Methanogen

Methanogens are archaea that produce methane as a metabolic byproduct in anoxic conditions. They are common in wetlands, where they are responsible for marsh gas, and in the guts of animals such as ruminants and humans, where they are responsible for the methane content of flatulence....
ic archaea and the neutrophilic iron-oxidizing bacteria.

Many microorganisms in dark regions of the oceans use chemosynthesis to produce biomass from 1-carbon molecules. Two categories can be distinguished. In the rare sites at which hydrogen molecules (H2) are available, the energy available from the reaction between CO2 and H2 (leading to production of methane, CH4) can be large enough to drive the production of biomass. Alternatively, in most oceanic environments, energy for chemosynthesis derives from reactions between O2 and substances such as hydrogen sulfide or ammonia. In this second case, the chemosynthetic microorganisms are dependent on photosynthesis which occurs elsewhere and which produces the O2 that they require.

Many chemosynthetic microorganisms are consumed by other organisms in the ocean, and symbiotic
Symbiosis

The term symbiosis commonly describes close and often long-term interactions between different biological species. The term was first used in 1879 by the Germany mycology Heinrich Anton de Bary, who defined it as "the living together of unlike organisms"....
 associations between chemosynthesizers and respiring heterotrophs are quite common. Large populations of animals can be supported by chemosynthetic primary production
Primary production

Primary production is the production of organic compounds from atmospheric or aquatic carbon dioxide, principally through the process of photosynthesis, with chemosynthesis being much less important....
 at hydrothermal vent
Hydrothermal vent

A hydrothermal vent is a fissure vent in a planet's surface from which Geothermal heated water issues. Hydrothermal vents are commonly found near volcano active places, areas where tectonic plates are moving apart, ocean basins, and hotspot ....
s, methane clathrate
Methane clathrate

Methane clathrate, also called methane hydrate or methane ice, is a solid form of water that contains a large amount of methane within its crystal structure ....
s, cold seep
Cold seep

A cold seep is an area of the ocean floor where hydrogen sulfide, methane and other hydrocarbon-rich fluid seepage occurs, often in the form of a brine pool....
s, and whale fall
Whale fall

Whale fall is the term used for a whale carcass that has fallen to the ocean floor. Whale falls were first observed in the 1980s, with the advent of deep-sea robotic exploration....
s.

It has been hypothesized that chemosynthesis may support life below the surface of Mars
MARS

In cryptography, MARS is a block cipher that was IBM's submission to the Advanced Encryption Standard process. MARS was selected as an AES finalist in August 1999, after the AES2 conference in March 1999, where it was voted as the fifth and last finalist algorithm....
, Jupiter's
Jupiter

Jupiter is the fifth planet from the Sun and the Solar system by size planet within the Solar System. It is two and a half times as massive as all of the other planets in our Solar System combined....
 moon Europa
Europa (moon)

'Europa' is the Moons_of_Jupiter#Table Natural satellite of the planet Jupiter. Europa was discovered in 1610 by Galileo Galilei , and named after a mythical Phoenician noblewoman, Europa , who was courted by Zeus and became the queen of Crete....
, and other planets.

Hydrogen sulfide chemosynthesis: CO2 + O2 + 4 ? CH2O + 4 + 3

Use of term in molecular nanotechnology


The term chemosynthesis is also used in molecular nanotechnology
Molecular nanotechnology

Molecular nanotechnology is the concept of engineering functional mechanical systems at the molecular scale. An equivalent definition would be "machines at the molecular scale designed and built atom-by-atom"....
 broadly to refer to any chemical synthesis
Chemical synthesis

In chemistry, chemical synthesis is purposeful execution of chemical reactions in order to get a product , or several products. This happens by physics and chemical manipulations usually involving one or more reactions....
 where reactions
Chemical reaction

A chemical reaction is a process that always results in the interconversion of chemical substances. The substance or substances initially involved in a chemical reaction are called reactants....
 occur due to random thermal motion, a class which encompasses almost all of modern synthetic chemistry. The human-authored processes of chemical engineering
Chemical engineering

Chemical engineering is the branch of engineering that deals with the application of physical science , with mathematics, to the process of converting raw materials or chemicals into more useful or valuable forms....
 are accordingly represented as biomimicry
Biomimicry

Biomimicry is a relatively new science that studies nature, its models, systems, processes and elements and then imitates or takes creative inspiration from them to solve human problems sustainability ....
 of the natural phenomena above, and the entire class of non-photosynthetic chains by which complex molecules are constructed is described as chemo-.

This form of engineering is then contrasted with mechanosynthesis
Mechanosynthesis

Mechanosynthesis is any chemical synthesis in which reaction outcomes are determined by the use of mechanical constraints to direct reactive molecules to specific molecular sites....
, a hypothetical process where individual molecule
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
s are mechanically manipulated to control reactions to human specification. Since photosynthesis
Photosynthesis

File:Seawifs global biosphere.jpgPhotosynthesis is a metabolic pathway that converts carbon dioxide into organic compounds, especially sugars, using the energy from sunlight....
 and other natural processes create extremely complex molecules to the specifications contained in RNA
RNA

Ribonucleic acid is a type of molecule that consists of a long chain of nucleotide units. Each nucleotide consists of a nucleobase, a ribose sugar, and a phosphate....
 and stored long-term in DNA
DNA

Deoxyribonucleic acid is a nucleic acid that contains the genetics instructions used in the development and functioning of all known living organisms and some viruses....
 form, advocates of molecular engineering
Molecular engineering

Molecular engineering is any means of manufacturing molecules. It may be used to create, on an extremely small scale, most typically one at a time, new molecules which may not exist in nature, or be stable beyond a very narrow range of conditions....
 claim that an artificial process can likewise exploit a chain of long-term storage, short-term storage, enzyme
Enzyme

Enzymes are biomolecules that catalysis chemical reactions. Almost all enzymes are proteins. In enzymatic reactions, the molecules at the beginning of the process are called Substrate , and the enzyme converts them into different molecules, the products....
-like copying mechanisms similar to those in the cell
Cell (biology)

The cell is the structural and functional unit of all known Life organisms. It is the smallest unit of an organism that is classified as living, and is often called the building bricks of life....
, and ultimately produce complex molecules which need not be protein
Protein

Proteins are organic compounds made of amino acids arranged in a linear chain and joined together by peptide bonds between the carboxyl and amino groups of adjacent amino acid Residue ....
s. For instance, sheet diamond or carbon nanotube
Carbon nanotube

Carbon nanotubes are allotropes of carbon with a nanostructure that can have a length-to-diameter ratio of up to 28,000,000:1, which is significantly larger than any other material....
s could be produced by a chain of non-biological reactions that have been designed using the basic model of biology.

Use of the term chemosynthesis reinforces the view that this is feasible by pointing out that several alternate means of creating complex proteins, mineral shells of mollusks and crustaceans, etc., evolved naturally, not all of them dependent on photosynthesis and a food chain
Food chain

Food chains, also called, food networks and/or trophic social networks, describe the eating relationships between species within an ecosystem....
 from the sun via chlorophyll
Chlorophyll

Chlorophyll is a green pigment found in most plants, algae, and cyanobacteria. Its name is derived from Greek language: ?????? and f????? ....
. Since more than one such pathway exists to creating complex molecules, even extremely specific ones such as protein
Protein

Proteins are organic compounds made of amino acids arranged in a linear chain and joined together by peptide bonds between the carboxyl and amino groups of adjacent amino acid Residue ....
s edible to fish
Fish

A fish is any marine biology vertebrate animal that is typically ectothermic , covered with scale , and equipped with two sets of paired fins and several unpaired fins....
, the likelihood of humans being able to design an entirely new one is considered (by these advocates) to be near certainty in the long run, and possible within a generation.

Discovery

In 1890, Sergei Nikolaevich Vinogradskii (Winogradsky) proposed a novel life process called chemosynthesis. His discovery suggested that some microbes could live solely on inorganic matter emerged during his physiological research in 1880s in Strassburg and Zurich on sulfur, iron, and nitrogen bacteria.

This was confirmed nearly 100 years later, when hydrothermal vents were predicted to exist in 1970s. The hot springs and strange creatures were discovered by Alvin
DSV Alvin

Alvin is a 16-ton, manned deep-ocean research submersible owned by the United States Navy and operated by the Woods Hole Oceanographic Institution in Woods Hole, Massachusetts....
, the world's first deep-sea submersible, in 1977 at the Galapagos Rift.

A mid-nineties (1993-1997) television
Television

Television is a widely used telecommunication mass-media for transmitting and receiving moving , either monochrome or color, usually accompanied by sound....
 series hosted by Bill Nye
Bill Nye

William Sanford Nye also known as "Bill Nye the Science Guy," is an United States comedian, Television program, Science education and mechanical engineer....
 named chemosynthesis as one of the 100 greatest scientific discoveries of all time.

Annoted Reference

  • "The Origin of Life and Evolution." 100 Greatest Discoveries. . CICA, Ottawa. 16 Jan. 2007, 19h00.
Note: This film discusses life, evolution and extinction. For more information see .


See also

  • Autotroph
    Autotroph

    An autotroph is an organism that produces complex organic compounds from simple inorganic molecules using energy from light or inorganic chemical reactions....
  • Heterotroph
    Heterotroph

    A heterotroph is an organism that organic compound substrates to get its Energy#Chemical energy for its life cycle. This contrasts with autotrophs such as plants which are able to directly use sources of energy such as light to produce organic substrates from inorganic carbon dioxide....


External links