Barium star
Encyclopedia
Barium stars are G to K class giants
Giant star
A giant star is a star with substantially larger radius and luminosity than a main sequence star of the same surface temperature. Typically, giant stars have radii between 10 and 100 solar radii and luminosities between 10 and 1,000 times that of the Sun. Stars still more luminous than giants are...

, whose spectra indicate an overabundance of s-process
S-process
The S-process or slow-neutron-capture-process is a nucleosynthesis process that occurs at relatively low neutron density and intermediate temperature conditions in stars. Under these conditions the rate of neutron capture by atomic nuclei is slow relative to the rate of radioactive beta-minus decay...

 elements by the presence of singly ionized barium
Barium
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. Barium is never found in nature in its pure form due to its reactivity with air. Its oxide is historically known as baryta but it reacts with...

, Ba II, at λ
Wavelength
In physics, the wavelength of a sinusoidal wave is the spatial period of the wave—the distance over which the wave's shape repeats.It is usually determined by considering the distance between consecutive corresponding points of the same phase, such as crests, troughs, or zero crossings, and is a...

 455.4nm. Barium stars also show enhanced spectral features of carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...

, the bands of the molecules CH, CN and C2
Diatomic carbon
Diatomic carbon is a diatomic molecule of carbon , which occurs in electric arcs; in comets, stellar atmospheres and the interstellar medium; and in blue hydrocarbon flames.-Chemistry:...

. The class was originally recognized and defined by William Bidelman and Philip Keenan
Philip Childs Keenan
Philip Childs Keenan was an American astronomer.Keenan was an American spectroscopist who collaborated with William Wilson Morgan and Edith Kellman to develop the MKK stellar spectral classification system between 1939 and 1943...

.

Observational studies of their radial velocity
Radial velocity
Radial velocity is the velocity of an object in the direction of the line of sight . In astronomy, radial velocity most commonly refers to the spectroscopic radial velocity...

 suggested that all barium stars are binary stars  Observations in the ultraviolet
Ultraviolet
Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than X-rays, in the range 10 nm to 400 nm, and energies from 3 eV to 124 eV...

 using International Ultraviolet Explorer
International Ultraviolet Explorer
The International Ultraviolet Explorer was an astronomical observatory satellite primarily designed to take ultraviolet spectra. The satellite was a collaborative project between NASA, the UK Science Research Council and the European Space Agency...

 detected white dwarfs in some barium star systems.

Barium stars are believed to be the result of mass transfer
Mass transfer
Mass transfer is the net movement of mass from one location, usually meaning a stream, phase, fraction or component, to another. Mass transfer occurs in many processes, such as absorption, evaporation, adsorption, drying, precipitation, membrane filtration, and distillation. Mass transfer is used...

 in a binary star
Binary star
A binary star is a star system consisting of two stars orbiting around their common center of mass. The brighter star is called the primary and the other is its companion star, comes, or secondary...

 system. The mass transfer occurred when the presently-observed giant star was on the main sequence
Main sequence
The main sequence is a continuous and distinctive band of stars that appears on plots of stellar color versus brightness. These color-magnitude plots are known as Hertzsprung–Russell diagrams after their co-developers, Ejnar Hertzsprung and Henry Norris Russell...

. Its companion, the donor star, was a carbon star
Carbon star
A carbon star is a late-type star similar to a red giant whose atmosphere contains more carbon than oxygen; the two elements combine in the upper layers of the star, forming carbon monoxide, which consumes all the oxygen in the atmosphere, leaving carbon atoms free to form other carbon compounds,...

 on the asymptotic giant branch
Asymptotic Giant Branch
The asymptotic giant branch is the region of the Hertzsprung-Russell diagram populated by evolving low to medium-mass stars. This is a period of stellar evolution undertaken by all low to intermediate mass stars late in their lives....

 (AGB), and had produced carbon and s-process elements in its interior. These nuclear fusion products were mixed by convection
Convection
Convection is the movement of molecules within fluids and rheids. It cannot take place in solids, since neither bulk current flows nor significant diffusion can take place in solids....

 to its surface. Some of that matter "polluted" the surface layers of the main sequence star as the donor star lost mass at the end of its AGB evolution, and it subsequently evolved to become a white dwarf. We are observing these systems an indeterminate amount of time after the mass transfer event, when the donor star has long been a white dwarf, and the "polluted" recipient star has evolved to become a red giant
Red giant
A red giant is a luminous giant star of low or intermediate mass in a late phase of stellar evolution. The outer atmosphere is inflated and tenuous, making the radius immense and the surface temperature low, somewhere from 5,000 K and lower...

. .

During its evolution, the barium star will at times be larger and cooler than the limits of the spectral types G or K. When this happens, ordinarily such a star is spectral type M, but the s-process excesses may cause it to show its altered composition as another spectral peculiarity. While the star's surface temperature is in the M-type regime, the star may show molecular features of the s-process element zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...

, zirconium oxide (ZrO) bands. When this happens, the star will appear as an "extrinsic" S star.

Historically, barium stars posed a puzzle, because in standard stellar evolution
Stellar evolution
Stellar evolution is the process by which a star undergoes a sequence of radical changes during its lifetime. Depending on the mass of the star, this lifetime ranges from only a few million years to trillions of years .Stellar evolution is not studied by observing the life of a single...

 theory G and K giants are not far enough along in their evolution to have synthesized carbon and s-process elements and mix them to their surfaces. The discovery of the stars' binary nature resolved the puzzle, putting the source of their spectral peculiarities into a companion star which should have produced such material. The mass transfer episode is believed to be quite brief on an astronomical timescale. The mass transfer hypothesis predicts that there should be main sequence stars with barium star spectral peculiarities. At least one such star, HR 107, is known.

Prototypical barium stars include zeta Capricorni
Zeta Capricorni
Zeta Capricorni, , is a fourth-magnitude star in the constellation Capricornus. ζ Capricorni is a binary star, with the primary component ζ Capricorni A being a yellow G-type supergiant with an apparent magnitude of +3.77...

, HR 774, and HR 4474.

The CH stars
CH stars
CH stars are particular type of carbon stars which are characterized by the presence of exceedingly strong CH absorption bands in their spectra. They belong to the star population II, meaning they're metal poor and generally pretty middle-aged stars, and are underluminous compared to the classical...

 are Population II stars with similar evolutionary state, spectral peculiarities, and orbital statistics, and are believed to be the older, metal-poor analogs of the barium stars..
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