Shea butter
Encyclopedia
Shea butter is a slightly yellowish or ivory-colored fat
Fat
Fats consist of a wide group of compounds that are generally soluble in organic solvents and generally insoluble in water. Chemically, fats are triglycerides, triesters of glycerol and any of several fatty acids. Fats may be either solid or liquid at room temperature, depending on their structure...

 extracted from the nut
Nut (fruit)
A nut is a hard-shelled fruit of some plants having an indehiscent seed. While a wide variety of dried seeds and fruits are called nuts in English, only a certain number of them are considered by biologists to be true nuts...

 of the African shea tree (Vitellaria paradoxa). It is widely used in cosmetics
Cosmetics
Cosmetics are substances used to enhance the appearance or odor of the human body. Cosmetics include skin-care creams, lotions, powders, perfumes, lipsticks, fingernail and toe nail polish, eye and facial makeup, towelettes, permanent waves, colored contact lenses, hair colors, hair sprays and...

 as a moisturizer
Moisturizer
Moisturizers or emollients are complex mixtures of chemical agents specially designed to make the external layers of the skin softer and more pliable, by increasing its hydration by reducing evaporation. Naturally occurring skin lipids and sterols as well as artificial or natural oils,...

, salve
Salve
A salve is a medical ointment used to soothe the head or other body surface. A popular eye medicine known as "Phrygian powder" was one of Laodicea's sources of wealth...

 or lotion
Lotion
A lotion is a low- to medium-viscosity, topical preparation intended for application to unbroken skin. By contrast, creams and gels have higher viscosity.Lotions are usually applied to external skin with bare hands, a clean cloth, cotton wool or gauze...

. Shea butter is edible and may be used in food preparation. Occasionally the chocolate industry uses shea butter as a substitute for cocoa butter
Cocoa butter
Cocoa butter, also called theobroma oil, is a pale-yellow, pure edible vegetable fat extracted from the cocoa bean. It is used to make chocolate, biscuits, and baked goods, as well as some pharmaceuticals, ointments, and toiletries...

, although the taste is different.

The English
English language
English is a West Germanic language that arose in the Anglo-Saxon kingdoms of England and spread into what was to become south-east Scotland under the influence of the Anglian medieval kingdom of Northumbria...

 word "shea" comes from s'í, the tree's name in the Bamana
Bambara language
Bambara, more correctly known as Bamanankan , its designation in the language itself , is a language spoken in Mali by as many as six million people...

 language of Mali
Mali
Mali , officially the Republic of Mali , is a landlocked country in Western Africa. Mali borders Algeria on the north, Niger on the east, Burkina Faso and the Côte d'Ivoire on the south, Guinea on the south-west, and Senegal and Mauritania on the west. Its size is just over 1,240,000 km² with...

. The French
French language
French is a Romance language spoken as a first language in France, the Romandy region in Switzerland, Wallonia and Brussels in Belgium, Monaco, the regions of Quebec and Acadia in Canada, and by various communities elsewhere. Second-language speakers of French are distributed throughout many parts...

 name karité comes from ghariti, its equivalent in the Wolof language
Wolof language
Wolof is a language spoken in Senegal, The Gambia, and Mauritania, and is the native language of the Wolof people. Like the neighbouring languages Serer and Fula, it belongs to the Atlantic branch of the Niger–Congo language family...

 of Senegal
Senegal
Senegal , officially the Republic of Senegal , is a country in western Africa. It owes its name to the Sénégal River that borders it to the east and north...

.

Butter extraction and refining

The traditional method of preparing unrefined shea butter consists of the following steps:
  • Separating/cracking: The outer pulp of the fruit is removed. When dry, the nut, which is the source of shea butter, must be separated from the outer shell. This is a social activity, traditionally done by Women Elders and young girls who sit on the ground and break the shells with small rocks.
  • Crushing: To make the shea nuts into butter, they must be crushed. Traditionally, this is done with mortars and pestles. It is hard, grueling work - with the women spending hours lifting the heavy pestles and slamming them into the mortars to crush the nuts so they can be roasted.
  • Roasting: The crushed nuts are then roasted in huge pots over open, wood fires. The pots must be stirred constantly with wooden paddles so the butter does not burn. The butter is heavy and stirring it is hot, smoky work, done under the sun. This is where the slight, smoky smell of traditional shea butter originates.
  • Grinding: The roasted shea nuts are ground into a smoother paste, water is gradually added and the paste is mixed well by hand.
  • Separating the oils: The paste is kneaded by hand in large basins and water is gradually added to help separate out the butter oils. As they float to the top, the butter oils, which are in a curd state, are removed and excess water squeezed out. The butter oil curds are then melted in large open pots over slow fires. A period of slow boiling will remove any remaining water, by evaporation.
  • Collecting and shaping: The shea butter, which is creamy or golden yellow at this point, is ladled from the top of the pots and put in cool places to harden. Then it is formed into balls.


Industrially, a mechanical sheller such as the Universal Nut Sheller may be used, although controversy over its usability with shea nuts is reported in that article. The refined butter may be extracted with chemicals such as hexane
Hexane
Hexane is a hydrocarbon with the chemical formula C6H14; that is, an alkane with six carbon atoms.The term may refer to any of four other structural isomers with that formula, or to a mixture of them. In the IUPAC nomenclature, however, hexane is the unbranched isomer ; the other four structures...

, or by clay filter
Clay pot filter
The clay pot filter purifies water by passing it through the pores of a ceramic which has been fired in an open dung fire. These filters, intended to be affordable for developing countries, were developed by an Australian materials scientist and potter, Tony Flynn.-Production:These filters are made...

ing.

Composition and properties

Shea butter extract is a complex fat that contains, besides many nonsaponifiable
Saponification
Saponification is a process that produces soap, usually from fats and lye. In technical terms, saponification involves base hydrolysis of triglycerides, which are esters of fatty acids, to form the sodium salt of a carboxylate. In addition to soap, such traditional saponification processes...

 components (substances that cannot be fully converted into soap
Soap
In chemistry, soap is a salt of a fatty acid.IUPAC. "" Compendium of Chemical Terminology, 2nd ed. . Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford . XML on-line corrected version: created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. ISBN...

 by treatment with alkali
Alkali
In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Some authors also define an alkali as a base that dissolves in water. A solution of a soluble base has a pH greater than 7. The adjective alkaline is commonly used in English as a synonym for base,...

), the following fatty acids:oleic acid
Oleic acid
Oleic acid is a monounsaturated omega-9 fatty acid found in various animal and vegetable fats. It has the formula CH37CH=CH7COOH. It is an odorless, colourless oil, although commercial samples may be yellowish. The trans isomer of oleic acid is called elaidic acid...

 (40-60%), stearic acid
Stearic acid
Stearic acid is the saturated fatty acid with an 18 carbon chain and has the IUPAC name octadecanoic acid. It is a waxy solid, and its chemical formula is CH316CO2H. Its name comes from the Greek word στέαρ "stéatos", which means tallow. The salts and esters of stearic acid are called stearates...

 (20-50%), linoleic acid
Linoleic acid
Linoleic acid is an unsaturated n-6 fatty acid. It is a colorless liquid at room temperature. In physiological literature, it has a lipid number of 18:2...

 (3-11%), palmitic acid
Palmitic acid
Palmitic acid, or hexadecanoic acid in IUPAC nomenclature, is one of the most common saturated fatty acids found in animals and plants. Its molecular formula is CH314CO2H. As its name indicates, it is a major component of the oil from palm trees . Palmitate is a term for the salts and esters of...

 (2-9%), linolenic acid
Alpha-linolenic acid
α-Linolenic acid is an organic compound found in many common vegetable oils. In terms of its structure, it is named all-cis-9,12,15-octadecatrienoic acid. In physiological literature, it is given the name 18:3 ....

(<1%) and arachidic acid
Arachidic acid
Arachidic acid, also called eicosanoic acid, is the saturated fatty acid with a 20 carbon chain. It is as a minor constituent of peanut oil and corn oil . Its name derives from the Latin arachis — peanut...

(<1%).

Shea butter melts at body temperature and absorbs rapidly into the skin without leaving a greasy feeling.

Uses

Shea butter is mainly used as an ingredient in chocolate
Chocolate
Chocolate is a raw or processed food produced from the seed of the tropical Theobroma cacao tree. Cacao has been cultivated for at least three millennia in Mexico, Central and South America. Its earliest documented use is around 1100 BC...

.

Some companies have suggested a classification system for shea butter separating it into five grades: A (raw or unrefined, extracted using water), B (refined), C (highly refined and extracted with solvents such as hexane
Hexane
Hexane is a hydrocarbon with the chemical formula C6H14; that is, an alkane with six carbon atoms.The term may refer to any of four other structural isomers with that formula, or to a mixture of them. In the IUPAC nomenclature, however, hexane is the unbranched isomer ; the other four structures...

), D (lowest uncontaminated grade), E (with contaminants). Commercial grades are A, B, C. The color of raw (grade A) butter ranges from cream (like whipped butter
Butter
Butter is a dairy product made by churning fresh or fermented cream or milk. It is generally used as a spread and a condiment, as well as in cooking applications, such as baking, sauce making, and pan frying...

) to grayish yellow, and it has a nutty aroma which is removed in the other grades. Grade C is pure white While the level of vitamin content can be affected by refining, up to 95% of vitamin content can remain in refined grades (i.e. grade C) of shea butter while reducing contamination levels to non-detectable levels.

The main industrial use of shea butter outside Africa is in cosmetics, such as moisturizer
Moisturizer
Moisturizers or emollients are complex mixtures of chemical agents specially designed to make the external layers of the skin softer and more pliable, by increasing its hydration by reducing evaporation. Naturally occurring skin lipids and sterols as well as artificial or natural oils,...

 cream
Cream
Cream is a dairy product that is composed of the higher-butterfat layer skimmed from the top of milk before homogenization. In un-homogenized milk, over time, the lighter fat rises to the top. In the industrial production of cream this process is accelerated by using centrifuges called "separators"...

s and emulsion
Emulsion
An emulsion is a mixture of two or more liquids that are normally immiscible . Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion is used when both the dispersed and the...

, and hair conditioner
Hair conditioner
Hair conditioner is a hair care product that alters the texture and appearance of hair.-History:For centuries, natural oils have been used to condition human hair. These natural products are still used today, including essential oils such as tea tree oil and carrier oils such as jojoba oil...

s for dry and brittle hair.

It is also used by soap makers, typically in small amounts (5-7% of the oils in the recipe), because of its property of leaving a small amount of oil in the soap.

Medicinal

Shea butter is used as a base for medicinal ointments. Some of the isolated chemical constituents are reported to have anti-inflammatory
Anti-inflammatory
Anti-inflammatory refers to the property of a substance or treatment that reduces inflammation. Anti-inflammatory drugs make up about half of analgesics, remedying pain by reducing inflammation as opposed to opioids, which affect the central nervous system....

, emollient and humectant
Humectant
A humectant is a hygroscopic substance. It is often a molecule with several hydrophilic groups, most often hydroxyl groups, but amines and carboxyl groups, sometimes esterified, can be encountered as well; the affinity to form hydrogen bonds with molecules of water is crucial here.Since...

 properties.

Shea butter has been used as a sunblocking lotion
Sunscreen
Sunblock is a lotion, spray, gel or other topical product that absorbs or reflects some of the sun's ultraviolet radiation on the skin exposed to sunlight and thus helps protect against sunburn...

 and has a limited capacity to absorb ultraviolet radiation.

In Ghana, shea butter, locally known as nkuto (Akan
Akan language
Akan, also known as Twi and Fante, is an Akan language that is the principal native language of Ghana, spoken over much of the southern half of that country, by about 52% of the population, and to a lesser extent across the border in eastern Côte d'Ivoire...

) or nku (Ga
Ga District
Ga was a former district of Greater Accra Region, Ghana. It has since been divided into the Ga East District and the Ga West District.The Ga District is divided in different sub-areas...

) is used as lotion to protect the skin during the dry Harmattan
Harmattan
The Harmattan is a dry and dusty West African trade wind. It blows south from the Sahara into the Gulf of Guinea between the end of November and the middle of March...

 season.

In Nigeria shea butter is used for the management of sinusitis
Sinusitis
Sinusitis is inflammation of the paranasal sinuses, which may be due to infection, allergy, or autoimmune issues. Most cases are due to a viral infection and resolve over the course of 10 days...

 and relief of nasal congestion
Nasal congestion
Nasal congestion is the blockage of the nasal passages usually due to membranes lining the nose becoming swollen from inflamed blood vessels. It is also known as nasal blockage, nasal obstruction, blocked nose, stuffy nose, or stuffed up nose.Nasal congestion has many causes and can range from a...

. It is also massaged into joints and other parts of the body where pain is experienced.

Traditional

In Africa, shea butter is used for cooking oil, as a waterproofing wax, for hairdressing, for candle-making, and also as an ingredient in medicinal ointments. It is also used by makers of traditional African percussion instrument
Percussion instrument
A percussion instrument is any object which produces a sound when hit with an implement or when it is shaken, rubbed, scraped, or otherwise acted upon in a way that sets the object into vibration...

s to increase the durability of wood (such as carved djembe
Djembe
A djembe also known as jembe, jenbe, djbobimbe, jymbe, yembe, or jimbay, or sanbanyi in Susu; is a skin-covered drum meant played with bare hands....

shells), dried calabash gourds, and leather tuning straps.
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