Pharmacosiderite
Encyclopedia
Pharmacosiderite is a hydrate
d basic ferric
arsenate, with chemical formula
K
Fe
4(As
O
4)3(OH
)4·(6-7)H2O
and a molecular weight
of 873.38 g/mol. It consists of the elements
arsenic
, iron
, hydrogen
, potassium
, sodium
and oxygen
. It has a Mohs hardness
of 2 to 3, about that of a finger nail. Its specific gravity
is about 2.7 to 2.9, has indistinct cleavage
, and is usually transparent or translucent. It has a yellow
or white
streak and a yellow, green
, brown
or red
color
. Its lustre
is adamantine, vitreous and resinous, and it has conchoidal, brittle and sectile fracture
.
Pharmacosiderite has an isometric crystal system, with yellowish-green, sharply defined cube
crystals. Its crystals are doubly refracting, and exhibit a banded structure in polarized light. When placed in ammonium
solution
, a crystal changes color to a distinguishing red. Upon placing it into dilute hydrochloric acid
the original color is restored.
This secondary origin mineral
is normally formed in the oxidation zones of ore
deposits. The alteration of arsenopyrite
, tennantite
and other primary arsenates can form pharmacosiderite. It can also form from precipitation
of hydrothermal solutions, but only rarely. It can be found in abundance in Cornwall
, Hungary
and the U.S.
state of Utah
.
When it was first discovered, pharmacosiderite was known as cube ore. The present name, given by J. F. L. Hausmann in 1813, is made up of the Greek
words for arsenic and iron, the two most significant consisting elements. Farmakon means poison, which is related to arsenic, and sideros means iron.
Pharmacolite and picropharmacolite
, which are different arsenates, are not associated besides via nomenclature
. Siderite
, a carbonate mineral, only shares the common element iron with pharmacosiderite.
Hydrate
Hydrate is a term used in inorganic chemistry and organic chemistry to indicate that a substance contains water. The chemical state of the water varies widely between hydrates, some of which were so labeled before their chemical structure was understood....
d basic ferric
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
arsenate, with chemical formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....
K
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...
Fe
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
4(As
Arsenic
Arsenic is a chemical element with the symbol As, atomic number 33 and relative atomic mass 74.92. Arsenic occurs in many minerals, usually in conjunction with sulfur and metals, and also as a pure elemental crystal. It was first documented by Albertus Magnus in 1250.Arsenic is a metalloid...
O
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
4)3(OH
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...
)4·(6-7)H2O
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...
and a molecular weight
Molecular mass
The molecular mass of a substance is the mass of one molecule of that substance, in unified atomic mass unit u...
of 873.38 g/mol. It consists of the elements
Chemical element
A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. Familiar examples of elements include carbon, oxygen, aluminum, iron, copper, gold, mercury, and lead.As of November 2011, 118 elements...
arsenic
Arsenic
Arsenic is a chemical element with the symbol As, atomic number 33 and relative atomic mass 74.92. Arsenic occurs in many minerals, usually in conjunction with sulfur and metals, and also as a pure elemental crystal. It was first documented by Albertus Magnus in 1250.Arsenic is a metalloid...
, iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...
, hydrogen
Hydrogen
Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of , hydrogen is the lightest and most abundant chemical element, constituting roughly 75% of the Universe's chemical elemental mass. Stars in the main sequence are mainly...
, potassium
Potassium
Potassium is the chemical element with the symbol K and atomic number 19. Elemental potassium is a soft silvery-white alkali metal that oxidizes rapidly in air and is very reactive with water, generating sufficient heat to ignite the hydrogen emitted in the reaction.Potassium and sodium are...
, sodium
Sodium
Sodium is a chemical element with the symbol Na and atomic number 11. It is a soft, silvery-white, highly reactive metal and is a member of the alkali metals; its only stable isotope is 23Na. It is an abundant element that exists in numerous minerals, most commonly as sodium chloride...
and oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...
. It has a Mohs hardness
Mohs scale of mineral hardness
The Mohs scale of mineral hardness characterizes the scratch resistance of various minerals through the ability of a harder material to scratch a softer material. It was created in 1812 by the German geologist and mineralogist Friedrich Mohs and is one of several definitions of hardness in...
of 2 to 3, about that of a finger nail. Its specific gravity
Relative density
Relative density, or specific gravity, is the ratio of the density of a substance to the density of a given reference material. Specific gravity usually means relative density with respect to water...
is about 2.7 to 2.9, has indistinct cleavage
Cleavage (crystal)
Cleavage, in mineralogy, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness are a result of the regular locations of atoms and ions in the crystal, which create smooth repeating surfaces that are visible both in the...
, and is usually transparent or translucent. It has a yellow
Yellow
Yellow is the color evoked by light that stimulates both the L and M cone cells of the retina about equally, with no significant stimulation of the S cone cells. Light with a wavelength of 570–590 nm is yellow, as is light with a suitable mixture of red and green...
or white
White
White is a color, the perception of which is evoked by light that stimulates all three types of color sensitive cone cells in the human eye in nearly equal amounts and with high brightness compared to the surroundings. A white visual stimulation will be void of hue and grayness.White light can be...
streak and a yellow, green
Green
Green is a color, the perception of which is evoked by light having a spectrum dominated by energy with a wavelength of roughly 520–570 nanometres. In the subtractive color system, it is not a primary color, but is created out of a mixture of yellow and blue, or yellow and cyan; it is considered...
, brown
Brown
Brown is a color term, denoting a range of composite colors produced by a mixture of orange, red, rose, or yellow with black or gray. The term is from Old English brún, in origin for any dusky or dark shade of color....
or red
Red
Red is any of a number of similar colors evoked by light consisting predominantly of the longest wavelengths of light discernible by the human eye, in the wavelength range of roughly 630–740 nm. Longer wavelengths than this are called infrared , and cannot be seen by the naked eye...
color
Color
Color or colour is the visual perceptual property corresponding in humans to the categories called red, green, blue and others. Color derives from the spectrum of light interacting in the eye with the spectral sensitivities of the light receptors...
. Its lustre
Lustre (mineralogy)
Lustre is a description of the way light interacts with the surface of a crystal, rock, or mineral. The word lustre traces its origins back to the Latin word lux, meaning "light", and generally implies radiance, gloss, or brilliance....
is adamantine, vitreous and resinous, and it has conchoidal, brittle and sectile fracture
Fracture
A fracture is the separation of an object or material into two, or more, pieces under the action of stress.The word fracture is often applied to bones of living creatures , or to crystals or crystalline materials, such as gemstones or metal...
.
Pharmacosiderite has an isometric crystal system, with yellowish-green, sharply defined cube
Cube
In geometry, a cube is a three-dimensional solid object bounded by six square faces, facets or sides, with three meeting at each vertex. The cube can also be called a regular hexahedron and is one of the five Platonic solids. It is a special kind of square prism, of rectangular parallelepiped and...
crystals. Its crystals are doubly refracting, and exhibit a banded structure in polarized light. When placed in ammonium
Ammonium
The ammonium cation is a positively charged polyatomic cation with the chemical formula NH. It is formed by the protonation of ammonia...
solution
Solution
In chemistry, a solution is a homogeneous mixture composed of only one phase. In such a mixture, a solute is dissolved in another substance, known as a solvent. The solvent does the dissolving.- Types of solutions :...
, a crystal changes color to a distinguishing red. Upon placing it into dilute hydrochloric acid
Hydrochloric acid
Hydrochloric acid is a solution of hydrogen chloride in water, that is a highly corrosive, strong mineral acid with many industrial uses. It is found naturally in gastric acid....
the original color is restored.
This secondary origin mineral
Mineral
A mineral is a naturally occurring solid chemical substance formed through biogeochemical processes, having characteristic chemical composition, highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not...
is normally formed in the oxidation zones of ore
Ore
An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element....
deposits. The alteration of arsenopyrite
Arsenopyrite
Arsenopyrite is an iron arsenic sulfide . It is a hard metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it becomes magnetic and gives off toxic fumes...
, tennantite
Tennantite
Tennantite is a copper arsenic sulfosalt mineral. Its chemical formula is Cu12As4S13. It is grey-black, steel-gray, iron-gray or black in color. A closely related mineral, tetrahedrite has antimony substituting for arsenic and the two form a solid solution series. The two have very similar...
and other primary arsenates can form pharmacosiderite. It can also form from precipitation
Precipitation (chemistry)
Precipitation is the formation of a solid in a solution or inside anothersolid during a chemical reaction or by diffusion in a solid. When the reaction occurs in a liquid, the solid formed is called the precipitate, or when compacted by a centrifuge, a pellet. The liquid remaining above the solid...
of hydrothermal solutions, but only rarely. It can be found in abundance in Cornwall
Cornwall
Cornwall is a unitary authority and ceremonial county of England, within the United Kingdom. It is bordered to the north and west by the Celtic Sea, to the south by the English Channel, and to the east by the county of Devon, over the River Tamar. Cornwall has a population of , and covers an area of...
, Hungary
Hungary
Hungary , officially the Republic of Hungary , is a landlocked country in Central Europe. It is situated in the Carpathian Basin and is bordered by Slovakia to the north, Ukraine and Romania to the east, Serbia and Croatia to the south, Slovenia to the southwest and Austria to the west. The...
and the U.S.
United States
The United States of America is a federal constitutional republic comprising fifty states and a federal district...
state of Utah
Utah
Utah is a state in the Western United States. It was the 45th state to join the Union, on January 4, 1896. Approximately 80% of Utah's 2,763,885 people live along the Wasatch Front, centering on Salt Lake City. This leaves vast expanses of the state nearly uninhabited, making the population the...
.
When it was first discovered, pharmacosiderite was known as cube ore. The present name, given by J. F. L. Hausmann in 1813, is made up of the Greek
Greek language
Greek is an independent branch of the Indo-European family of languages. Native to the southern Balkans, it has the longest documented history of any Indo-European language, spanning 34 centuries of written records. Its writing system has been the Greek alphabet for the majority of its history;...
words for arsenic and iron, the two most significant consisting elements. Farmakon means poison, which is related to arsenic, and sideros means iron.
Pharmacolite and picropharmacolite
Picropharmacolite
Picropharmacolite, Ca4Mg22·11H2O, is a rare arsenate mineral. It was named in 1819 from the Greek for bitter, in allusion to its magnesium content, and its chemical similarity to pharmacolite. The mineral irhtemite, Ca4Mg22·4H2O, has the same composition as picropharmacolite, except that it has...
, which are different arsenates, are not associated besides via nomenclature
IUPAC nomenclature
A chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used most frequently worldwide is the one created and developed by the International Union of Pure and Applied Chemistry ....
. Siderite
Siderite
Siderite is a mineral composed of iron carbonate FeCO3. It takes its name from the Greek word σίδηρος sideros, “iron”. It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus...
, a carbonate mineral, only shares the common element iron with pharmacosiderite.