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Ductile iron

 

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Ductile iron



 
 
Ductile iron, also called ductile cast iron, spheroidal graphite iron, or nodular cast iron, is a type of cast iron
Cast iron

Cast iron usually refers to Gray iron, but also identifies a large group of ferrous alloys, which solidify with a eutectic. The color of a fractured surface can be used to identify an alloy....
 invented in 1943 by Keith Millis
Keith Millis

Keith D. Millis was a metallurgical engineer and inventor of ductile iron.Early in the Second World War, chromium was considered critical to the war effort and experimentation was conducted by Millis to find a substitute....
. While most varieties of cast iron are brittle
Brittle

A material is brittle if it is liable to fracture when subjected to stress . That is, it has little tendency to deform before fracture. This fracture absorbs relatively little energy, even in materials of high Strength of materials, and usually makes a snapping sound....
, ductile iron is much more flexible
Flexible

Things known as Flexible include:*Flexible electronics*Flexible response*Flexible mold*Flexible employment*Flexible-fuel vehicle*Flexible rake receiver...
 and elastic
Elastic

Elastic may refer to:*Elastic collision, a term describing collisions in which kinetic energy is conserved*Elastic deformation, a reversible deformation of a material...
, due to its nodular graphite inclusions.

In 1949, Keith Millis, Lee Aunkst, Albert Gagnebin and Norman Pilling received a US patent on ductile iron production via magnesium treatment.

iron was the original "cast iron", and is an iron
Iron

Iron is a chemical element with the symbol Fe and atomic number 26. Iron is a Group 8 element and period 4 element. Iron is lustrous and silvery in color....
 alloy
Alloy

An alloy is a partial or complete solid solution of one or more chemical element in a metallic matrix. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may be homogeneous in distribution depending on thermal history....
 characterized by its relatively high carbon
Carbon

Carbon is a chemical element with chemical symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalence?making four electrons available to form covalent bond chemical bonds....
 content (usually 2% to 4%).






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Ductile iron, also called ductile cast iron, spheroidal graphite iron, or nodular cast iron, is a type of cast iron
Cast iron

Cast iron usually refers to Gray iron, but also identifies a large group of ferrous alloys, which solidify with a eutectic. The color of a fractured surface can be used to identify an alloy....
 invented in 1943 by Keith Millis
Keith Millis

Keith D. Millis was a metallurgical engineer and inventor of ductile iron.Early in the Second World War, chromium was considered critical to the war effort and experimentation was conducted by Millis to find a substitute....
. While most varieties of cast iron are brittle
Brittle

A material is brittle if it is liable to fracture when subjected to stress . That is, it has little tendency to deform before fracture. This fracture absorbs relatively little energy, even in materials of high Strength of materials, and usually makes a snapping sound....
, ductile iron is much more flexible
Flexible

Things known as Flexible include:*Flexible electronics*Flexible response*Flexible mold*Flexible employment*Flexible-fuel vehicle*Flexible rake receiver...
 and elastic
Elastic

Elastic may refer to:*Elastic collision, a term describing collisions in which kinetic energy is conserved*Elastic deformation, a reversible deformation of a material...
, due to its nodular graphite inclusions.

In 1949, Keith Millis, Lee Aunkst, Albert Gagnebin and Norman Pilling received a US patent on ductile iron production via magnesium treatment.

Metallurgy

Grey iron was the original "cast iron", and is an iron
Iron

Iron is a chemical element with the symbol Fe and atomic number 26. Iron is a Group 8 element and period 4 element. Iron is lustrous and silvery in color....
 alloy
Alloy

An alloy is a partial or complete solid solution of one or more chemical element in a metallic matrix. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may be homogeneous in distribution depending on thermal history....
 characterized by its relatively high carbon
Carbon

Carbon is a chemical element with chemical symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalence?making four electrons available to form covalent bond chemical bonds....
 content (usually 2% to 4%). When molten cast iron solidifies some of the carbon precipitates as graphite
Graphite

The mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Greek language ??afe?? : "to draw/write", for its use in pencils, where it is commonly called lead, as distinguished from the actual metallic element lead....
, forming tiny, irregular flakes within the crystal
Crystal

A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions....
 structure of the metal. While the graphite enhances the desirable properties of cast iron (improved casting & machining properties and better thermal conductivity
Thermal conductivity

In physics, thermal conductivity, , is the List of materials properties of a material that indicates its ability to conduct heat. It appears primarily in Heat conduction#Fourier's law for heat conduction....
), the flakes disrupt the crystal structure and provide a nucleation point for cracks, leading to cast iron's characteristic brittleness. In ductile iron the graphite is in the form of spherical
Sphere

A sphere is a symmetrical geometrical object. In non-mathematical usage, the term is used to refer either to a round ball or to its two-dimensional surface....
 nodules rather than flakes, thus inhibiting the creation of cracks and providing the enhanced ductility that gives the alloy its name. The formation of nodules is achieved by addition of "nodulizers" (for example, magnesium
Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, atomic weight 24.3050 and common oxidation number +2.Magnesium, an alkaline earth metal, is the ninth most abundance of the chemical elements in the universe by mass....
 or cerium
Cerium

Cerium is a chemical element with the symbol Ce and atomic number 58....
) into the melt. Yttrium
Yttrium

Yttrium is a chemical element with symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanoids and has historically been classified as a rare earth element....
 has also been studied as a possible nodulizer.

Graphite iron having spherical graphite are produced from grey cast iron by a malleabilizing heat treatment. The heat treatment consists of heating grey cast iron at around 900 °C for almost 24 hours and cooling slowly or moderately in air. This treatment converts the graphite from flakes to a spherical shape. Cooling slowly gives a ferrite matrix while cooling moderately gives a pearlitic matrix.

A recent development in ductile iron metallurgy
Metallurgy

Metallurgy is a domain of materials science that studies the physical and chemical behavior of metallic Chemical element, their intermetallics, and their mixtures, which are called alloys....
 is austempered ductile iron where the metallurgical structure is manipulated through a sophisticated heat treating process.

Composition

A typical chemical analysis of this material:
  • Iron
    Iron

    Iron is a chemical element with the symbol Fe and atomic number 26. Iron is a Group 8 element and period 4 element. Iron is lustrous and silvery in color....
  • Carbon
    Carbon

    Carbon is a chemical element with chemical symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalence?making four electrons available to form covalent bond chemical bonds....
     3.3 to 3.4%
  • Silicon
    Silicon

    Silicon is the most common metalloid. It is a chemical element, which has the symbol Si and atomic number 14. The atomic mass is 28.0855....
     2.2 to 2.8%
  • Manganese
    Manganese

    Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a Oxidation state in nature , and in many minerals....
     0.1 to 0.5%
  • Magnesium
    Magnesium

    Magnesium is a chemical element with the symbol Mg, atomic number 12, atomic weight 24.3050 and common oxidation number +2.Magnesium, an alkaline earth metal, is the ninth most abundance of the chemical elements in the universe by mass....
     0.03 to 0.05%
  • Phosphorus
    Phosphorus

    Phosphorus is the chemical element that has the symbol P and atomic number 15. The name comes from the and . A Valency nonmetal of the nitrogen group, phosphorus is commonly found in inorganic phosphate minerals....
     0.005 to 0.04%
  • Sulfur
    Sulfur

    Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
     0.005 to 0.02%


Other elements such as copper
Copper

Copper is a chemical element with the symbol Cu and atomic number 29.It is a ductile metal with very high thermal and electrical conductivity....
 or tin
Tin

Tin is a chemical element with the symbol Sn and atomic number 50. Tin is obtained chiefly from the mineral cassiterite, where it occurs as an oxide, SnO2....
 may be added to increase tensile and yield strength while simultaneously reducing elongation. Improved corrosion resistance can be achieved by replacing 15% to 30% of the iron
Iron

Iron is a chemical element with the symbol Fe and atomic number 26. Iron is a Group 8 element and period 4 element. Iron is lustrous and silvery in color....
 in the alloy with varying amounts of nickel
Nickel

Nickel is a chemical element, with the chemical symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge....
, copper
Copper

Copper is a chemical element with the symbol Cu and atomic number 29.It is a ductile metal with very high thermal and electrical conductivity....
, or chromium
Chromium

Chromium is a chemical element which has the symbol Cr and atomic number 24. It is a steely-gray, Lustre , hard metal that takes a high polish and has a high melting point....
.

Applications

Much of the annual production of ductile iron is in the form of ductile cast iron pipe, used for water and sewer lines. Ductile iron pipe is stronger and easier to tap
Taps and dies

Taps and dies are cutting tools used to create screw threads in solid substances including, but not limited to, metal, wood, and plastic. A tap is used to cut the female portion of the mating pair ....
, requires less support and provides greater flow area compared with pipe made from other materials. In difficult terrain it can be a better choice than PVC
Polyvinyl chloride

Polyvinyl chloride, commonly abbreviated PVC, is the third most widely used thermoplastic polymer after polyethylene and polypropylene....
, concrete
Concrete

Concrete is a construction material composed of cement as well as other cementitious materials such as fly ash and slag cement, construction aggregate , water , and Chemistry admixtures....
, polyethylene
Polyethylene

Polyethylene or polythene is a thermoplastic commodity heavily used in consumer products . Over 60 million tons of the material are produced worldwide every year....
, or steel
Steel

Steel is an alloy consisting mostly of iron, with a carbon content between 0.2% and 2.14% by weight , depending on grade. Carbon is the most cost-effective alloying material for iron, but various other alloying elements are used such as manganese, chromium, vanadium, and tungsten....
 pipe.

Ductile iron is specifically useful in many automotive components, where strength needs surpass that of aluminum but do not necessarily require steel. Other major industrial applications include off-highway diesel trucks, class 8 trucks, agricultural tractors, and oil well pumps.

See also

  • Malleable iron
    Malleable iron

    Malleable iron is the oldest member of the family of nodular irons. Like all nodular irons, malleable iron exhibits good ductility. Incorrectly considered by some to be an "old" or "dead" material, malleable iron still has a legitimate place in the design engineer's toolbox....


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