|
|
|
|
Quinone
|
| |
|
| |
- "DDQ" redirects here. DDQ is also the former callsign of a TV station in Toowoomba, Queensland, Australia.
Quinones are "compounds having a fully conjugated cyclic dione structure, such as that of benzoquinones, derived from aromatic compounds by conversion of an even number of –CH= groups into –C(=O)– groups with any necessary rearrangement of double bonds (polycyclic and heterocyclic analogues are included)."
Benzoquinone, sometimes referred to simply as "quinone", is one of the two isomers of cyclohexadienedione.

Discussion
Ask a question about 'Quinone'
Start a new discussion about 'Quinone'
Answer questions from other users
|
Encyclopedia
- "DDQ" redirects here. DDQ is also the former callsign of a TV station in Toowoomba, Queensland, Australia.
Quinones are "compounds having a fully conjugated cyclic dione structure, such as that of benzoquinones, derived from aromatic compounds by conversion of an even number of –CH= groups into –C(=O)– groups with any necessary rearrangement of double bonds (polycyclic and heterocyclic analogues are included)."
Benzoquinone, sometimes referred to simply as "quinone", is one of the two isomers of cyclohexadienedione. These compounds have the molecular formula C6H4O2. Orthobenzoquinone is the 1,2-dione, whereas parabenzoquinone is the 1,4-dione. Orthobenzoquinone is the oxidized form of catechol (1,2-dihydroxybenzene), while parabenzoquinone is the oxidized form of hydroquinone (quinol). An acidic potassium iodide solution reduces a solution of benzoquinone to hydroquinone, which is oxidized back with a solution of silver nitrate.
Some examples of quinones
Biochemistry
Quinones are common constituents of biologically relevant molecules (e.g. Vitamin K1 is phylloquinone). Others serve as electron acceptors in electron transport chains such as those in Photosystems I & II of photosynthesis, and aerobic respiration. A natural example of the oxidation of hydroquinone to quinone is in the spray of bombardier beetles; hydroquinone is reacted with hydrogen peroxide to produce a fiery blast of steam, a strong deterrent in the animal world. Quinones can be partially reduced to quinols.
Oxidizing agents
Benzoquinone is used in organic chemistry as an oxidizing agent. Stronger quinone oxidising agents exist; for instance: 2,3,5,6-tetrachloro-parabenzoquinone (also known as p-chloranil) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (also known as DDQ).
External links
|
| |
|
|