Giacinto Scoles
Encyclopedia
Giacinto Scoles is a European and North American chemist
Chemist
A chemist is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties such as density and acidity. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms...

 and physicist
Physicist
A physicist is a scientist who studies or practices physics. Physicists study a wide range of physical phenomena in many branches of physics spanning all length scales: from sub-atomic particles of which all ordinary matter is made to the behavior of the material Universe as a whole...

 who is best-known for his pioneering development of molecular beam methods for the study of weak van der Waals forces between atoms, molecules, and surfaces. He developed the cryogenic bolometer
Bolometer
A bolometer is a device for measuring the power of incident electromagnetic radiation via the heating of a material with a temperature-dependent electrical resistance. It was invented in 1878 by the American astronomer Samuel Pierpont Langley...

 as a universal detector of atomic and molecule beams that not only can detect a small flux of molecules, but also responds to the internal energy of the molecules. This is the bases for the optothermal spectroscopy technique which Scoles and others have used to obtain very high signal-to noise and high resolution ro-vibrational spectra.

Scoles was born in Italy and raised there through the Second World War. A few years after the war he moved, with his family, to Spain, where Scoles spent his adolescence. He returned to Italy and graduated the University of Genoa
University of Genoa
The University of Genoa is one of the largest universities in Italy.Located in Liguria on the Italian Riviera, the university was founded in 1471. It currently has about 40,000 students, 1,800 teaching and research staff and about 1,580 administrative staff.- Campus :The University of Genoa is...

 in 1959 with a degree in Chemistry. His publication record started with “Vapour Pressure of Isotopic Liquids I” published 1959 in Il Nuovo Cimento. Starting his interdisciplinary research between chemistry and physics, in 1960 he was appointed Assistant Professorship in the Physics Department of the University of Genoa where he taught a lab course and conducted experiments on isotope separation
Isotope separation
Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes, for example separating natural uranium into enriched uranium and depleted uranium. This is a crucial process in the manufacture of uranium fuel for nuclear power stations, and is...

 during physical adsorption (physisorption
Physisorption
Physisorption, also called physical adsorption, is a process in which the electronic structure of the atom or molecule is barely perturbed upon adsorption...

).

In 1961, he changed research area and joined Jan Beenakker’s group at the Kamerlingh-Onnes Laboratorium of Leiden University
Leiden University
Leiden University , located in the city of Leiden, is the oldest university in the Netherlands. The university was founded in 1575 by William, Prince of Orange, leader of the Dutch Revolt in the Eighty Years' War. The royal Dutch House of Orange-Nassau and Leiden University still have a close...

 in the Netherlands. There he coauthored one of the very first papers [1] on what became soon known as the Senftleben-Beenakker effect
Senftleben-Beenakker effect
The Senftleben-Beenakker effect is the dependence on a magnetic or electric field of transport properties of polyatomic gases. The effect is caused by the precession of the dipole of the gas molecules between collisions...

: The influence of an external magnetic or electric field on the transport properties of dilute polyatomic gases. The idea behind this effect is that every polyatomic molecule – even a simple paramagnetic one like N2 – has a magnetic moment
Magnetic moment
The magnetic moment of a magnet is a quantity that determines the force that the magnet can exert on electric currents and the torque that a magnetic field will exert on it...

, due to its end-over-end rotation, which can be used as a handle to make it precess in an external magnetic field
Magnetic field
A magnetic field is a mathematical description of the magnetic influence of electric currents and magnetic materials. The magnetic field at any given point is specified by both a direction and a magnitude ; as such it is a vector field.Technically, a magnetic field is a pseudo vector;...

. If the precession frequency is sufficiently large compared to the collision frequency
Collision frequency
Collision frequency is defined in chemical kinetics, in the background of theoretical kinetics, as the average number of collisions between reacting molecules per unit of time...

, the average kinetic cross section
Cross section (physics)
A cross section is the effective area which governs the probability of some scattering or absorption event. Together with particle density and path length, it can be used to predict the total scattering probability via the Beer-Lambert law....

 will change, and so will the transport properties. Likewise, for polar molecules one may employ electric fields to achieve the desired precession. This field has yielded a wealth of information on the non-spherical part (i.e. the angle dependence) of the intermolecular potential. In addition, several new phenomena were later discovered that had been believed to be non-existing in neutral gases, like transverse transport effects in a magnetic field, comparable to the Hall effect
Hall effect
The Hall effect is the production of a voltage difference across an electrical conductor, transverse to an electric current in the conductor and a magnetic field perpendicular to the current...

 in electrical conduction.

In 1964, Giacinto Scoles returned to the University of Genoa as Assistant Professor of Physics. In Genoa he stayed until 1971 and in those years established a renowned molecular beams laboratory devoted to the investigation of intermolecular forces in gases. Most significant was the development of the cryogenic bolometer to detect molecular beams. Bolometers detect tiny heat input (with noise on the order of 10-14 watt
Watt
The watt is a derived unit of power in the International System of Units , named after the Scottish engineer James Watt . The unit, defined as one joule per second, measures the rate of energy conversion.-Definition:...

s per square root
Square root
In mathematics, a square root of a number x is a number r such that r2 = x, or, in other words, a number r whose square is x...

 hertz
Hertz
The hertz is the SI unit of frequency defined as the number of cycles per second of a periodic phenomenon. One of its most common uses is the description of the sine wave, particularly those used in radio and audio applications....

) and had previously been developed as detectors of Infrared Radiation but here they are used to measure the internal and translational energy of a beam of atoms or molecules. The test apparatus set up together with M. Cavallini and G. Gallinaro [2] offered great advantages with respect to conventional techniques used at that time and reduced the cost of building beam machines. Scoles and his colleagues published a series of key papers which include the determination of the energy dependence of the integral collision cross section of He scattered by He [3], the observation of “Rainbow Scattering“ between two crossed beams of Argon [4], the first measurement of orbiting resonances in the scattering between two atoms (Hg and H) [5].

In 1971, Scoles moved to the University of Waterloo
University of Waterloo
The University of Waterloo is a comprehensive public university in the city of Waterloo, Ontario, Canada. The school was founded in 1957 by Drs. Gerry Hagey and Ira G. Needles, and has since grown to an institution of more than 30,000 students, faculty, and staff...

, Canada as Professor of Chemistry and Physics. There, he set up the first successful crossed molecular beam
Crossed molecular beam
Crossed molecular beam experiments are chemical experiments where two beams of atoms or molecules are collided together to elucidate the dynamics of the chemical reaction, and can detect individual reactive collisions.- Technique :...

 laboratory in Canada. He help establish the Waterloo Centre for Molecular Beams and Laser Chemistry, the Centre for Surface Science in Technology, as well as the weekly chemical physics seminars and annual Symposium on Chemical Physics, both of which continue to this day. He was the initial (Acting) Director of the Guelph-Waterloo Centre for Graduate Work in Chemistry, the first true inter-university graduate program in Canada. Scoles performed crossed beam differential scattering cross-section studies of atom-atom, atom-molecule and molecule-molecule interactions, using his bolometer detector. He also began using helium atom diffraction to study the structure of surfaces, both of pure crystals which often undergo change from the bulk structure (reconstruction) and also the structure of overlayers of atoms and molecules absorbed on surfaces. With Terry Gough and then graduate student Roger Miller, Scoles introduced the technique of bolometer-detected optothermal spectroscopy of molecular beams where vibrational excitation of a beam of molecules is detected by the bolometer. They used this technique to studies vibrational dissociation of a complex of two or more molecules held together by Van der Waals forces. By the early 1980s, Scoles began the first studies of the spectroscopy of molecules adsorbed in or on clusters of rare gas atoms.

In the mid to late 1970s Scoles spent part of his time at the University of Trento
University of Trento
The University of Trento is an Italian university located in the cities of Trento and Rovereto. It has been able to achieve considerable results in didactics, research and international relations, as shown by Censis University Guide and by the Italian Ministry of...

, Italy where he established a new molecular beam laboratory. The activity of the Trento lab was mainly focused on opto-thermal spectroscopy and atomic hydrogen scattering experiments.

Giacinto Scoles moved to Princeton University
Princeton University
Princeton University is a private research university located in Princeton, New Jersey, United States. The school is one of the eight universities of the Ivy League, and is one of the nine Colonial Colleges founded before the American Revolution....

 in 1986. One of the experiments that Scoles brought to Princeton was the study of IR spectroscopy of molecules attached to inert gas clusters, particularly Ar and Xe clusters. In this work, he developed the now widely used “pickup technique” [6] and set the stage for his later pioneering work on superfluid
Superfluid
Superfluidity is a state of matter in which the matter behaves like a fluid without viscosity and with extremely high thermal conductivity. The substance, which appears to be a normal liquid, will flow without friction past any surface, which allows it to continue to circulate over obstructions and...

 helium nanodroplets, for which he recently shared the Benjamin Franklin Award in Physics. The helium experiments, started with students S. Goyal and D. Schutt, provided the first molecular spectra of solutes in liquid helium, a unique superfluid solvent [7]. Frank Stienkemeier joined the group as a postdoc and together with graduate students John Higgins and Carlo Callegari (and sabbatical visitor Wolfgang Ernst) established the “Alkali age” of the group which provided a rich vein to explore chemical dynamics in this fascinating state of mater [8]. Graduate student James Reho brought time resolved spectroscopy techniques into the mix [9]. Erik Kerstel did a thesis on subdoppler spectroscopy of hydrogen bonded complexes, including the first such spectra in the vibrational overtone region [10]. Brooks Pate
Brooks Pate
Brooks H. Pate is the William R. Kenan Jr. Professor of chemistry, at the University of Virginia.He graduated from University of Virginia with a B.S. in 1987, and from Princeton University with a Ph.D. in 1992. He was a NRC Postdoctoral Fellow at NIST, from 1992 to 1993. He heads the Pate...

 brought Scoles and Kevin K. Lehmann
Kevin K. Lehmann
Kevin K. Lehmann is an American chemist and spectroscopist, and a famous professor, in both physics and chemistry at the University of Virginia, best-known for his work in the area of intramolecular and collisional dynamics, and for his advances in the method of cavity ring down spectroscopy...

 together for what proved to be a long series of experiments (and many Ph.D. theses) that characterized Intramolecular Vibrational energy Redistribution. They first studied the hydrogen stretching fundamental and first overtone spectral regions and observed Lorentzian lineshapes due to irreversible relaxation for large molecules with a very high density of states
Density of states
In solid-state and condensed matter physics, the density of states of a system describes the number of states per interval of energy at each energy level that are available to be occupied by electrons. Unlike isolated systems, like atoms or molecules in gas phase, the density distributions are not...

 [11]. They developed IR-microwave and later IR-IR double resonance methods to provide unambiguous quantum assignments of even highly congested spectra and to reach higher in energy [12]. The work by Andrea Callegari on benzene, long a model system for such studies is noted among many such studies. After this work, Carlo Callegari converted the apparatus into a helium droplet machine, which was used for the first study of overtone vibrational transitions in helium nanodroplets. Also, the pure rotational spectra of HCCCN and HCN in helium were observed [13]. This established that a single droplet could absorb several thousand photons without “optically pumping” out of resonance.
Scoles was instrumental in the establishment of the Princeton Materials Institute and became a close collaborator of Peter Eisenberger, its first director. Scoles also brought to Princeton his Helium Diffraction Spectrometer for the study of surface structure [14]. His focus turned from inorganic overlayers to the study of self-assembled monolayers, particularly alkane thiols on Au(111) [15]. Scoles collaborated with Eisenberger in using X-Rays as a complementary surface structure tool and showed the power of the combination of the two methods. Giacinto developed expertise in atomic force microscopy (AFM) to study surface structure and more recently, tip induced surface modification using the nanografting technique [16,17] which had been previously developed by his former student Gang Yu Liu. In collaboration with Steve Bernasek, Giacinto has also studied the influence of vibrational excitation (again for the first time in the first C-H overtone region) on the sticking probability of a molecule (methane) on a metal surface [18].

Starting in 2003, Scoles returned part time to Italy, taking appointments at the Trieste Synchrotron Elettra
Elettra
ELETTRA Synchrotron Light Laboratory is a national synchrotron laboratory located in Basovizza on the outskirts of Trieste, Italy.The facility, available for use by the Italian and international scientific communities, houses several ultra bright light sources, which use the synchrotron and free...

 and the International School for Advanced Studies (SISSA
Sissa
Sissa is a comune in the Province of Parma in the Italian region Emilia-Romagna, located about 100 km northwest of Bologna and about 20 km northwest of Parma....

), In SISSA he joined the Condensed Mater group where he began collaborating on theoretical problems dealing with helium nanodroplets and with physisorption. At the same time, he started an experimental group in Elettra, focusing on nanoscience, with particular attention to self-assembled monolayers and their properties [19,20]. Later, Scoles expanded his research into nanoscale biological processes, biophysics, and nanomedicine, in connection with the local Consortium of Molecular Biomedicine.

Awards and honors

  • 2006 - Research Prize of the Chemistry Faculty of the University of Bochum
  • 2006 - Benjamin Franklin Medal in Physics (with Jan Peter Toennies
    Jan Peter Toennies
    Professor Jan Peter Toennies is an American scientist and former director of the Max Planck Institute for Dynamics and Self-Organization...

    ) from the Franklin Institute
    Franklin Institute
    The Franklin Institute is a museum in Philadelphia, Pennsylvania, and one of the oldest centers of science education and development in the United States, dating to 1824. The Institute also houses the Benjamin Franklin National Memorial.-History:On February 5, 1824, Samuel Vaughn Merrick and...

    .
  • 2003 - Creativity Award from the NSF 2003-5
  • 2004 - Texas A&M University
    Texas A&M University
    Texas A&M University is a coeducational public research university located in College Station, Texas . It is the flagship institution of the Texas A&M University System. The sixth-largest university in the United States, A&M's enrollment for Fall 2011 was over 50,000 for the first time in school...

    , Frontiers in Chemical Research Lecturer
  • 2004 - Moscowitz Lecturer at the University of Minnesota
    University of Minnesota
    The University of Minnesota, Twin Cities is a public research university located in Minneapolis and St. Paul, Minnesota, United States. It is the oldest and largest part of the University of Minnesota system and has the fourth-largest main campus student body in the United States, with 52,557...

    , October 2004
  • 2003 - Distinguished Visiting Professor, University of Florida
    University of Florida
    The University of Florida is an American public land-grant, sea-grant, and space-grant research university located on a campus in Gainesville, Florida. The university traces its historical origins to 1853, and has operated continuously on its present Gainesville campus since September 1906...

    , Gainesville.
  • 2003 - Earle K. Plyler Prize for Molecular Spectroscopy
    Earle K. Plyler Prize for Molecular Spectroscopy
    The Earle K. Plyler Prize for Molecular Spectroscopy and Dynamics is a prize that has been awarded annually by the American Physical Society since 1977. The recipient is chosen for "notable contributions to the field of molecular spectroscopy and dynamics". The prize is named after Earle K...

     from the American Physical Society
    American Physical Society
    The American Physical Society is the world's second largest organization of physicists, behind the Deutsche Physikalische Gesellschaft. The Society publishes more than a dozen scientific journals, including the world renowned Physical Review and Physical Review Letters, and organizes more than 20...

     (with Kevin K. Lehmann
    Kevin K. Lehmann
    Kevin K. Lehmann is an American chemist and spectroscopist, and a famous professor, in both physics and chemistry at the University of Virginia, best-known for his work in the area of intramolecular and collisional dynamics, and for his advances in the method of cavity ring down spectroscopy...

    ).
  • 2002 - Peter Debye Award
    Peter Debye Award
    The Peter Debye Award in Physical Chemistry is awarded annually by the American Chemical Society to encourage and reward outstanding research in Physical Chemistry. The award is granted without regard to age or nationality.-Past recipients:*2011 Louis E. Brus...

     in Physical Chemistry from the American Chemical Society
    American Chemical Society
    The American Chemical Society is a scientific society based in the United States that supports scientific inquiry in the field of chemistry. Founded in 1876 at New York University, the ACS currently has more than 161,000 members at all degree-levels and in all fields of chemistry, chemical...

  • 2001 - H. E. Gunning Lecturer, Dept. of Chem., University of Alberta
    University of Alberta
    The University of Alberta is a public research university located in Edmonton, Alberta, Canada. Founded in 1908 by Alexander Cameron Rutherford, the first premier of Alberta and Henry Marshall Tory, its first president, it is widely recognized as one of the best universities in Canada...

  • 2000 - Elected Foreign Member of The Royal Netherlands Academy of Arts and Sciences
    Royal Netherlands Academy of Arts and Sciences
    The Royal Netherlands Academy of Arts and Sciences is an organisation dedicated to the advancement of science and literature in the Netherlands...

  • 2000 - Honorary Science Doctorate from the University of Waterloo
    University of Waterloo
    The University of Waterloo is a comprehensive public university in the city of Waterloo, Ontario, Canada. The school was founded in 1957 by Drs. Gerry Hagey and Ira G. Needles, and has since grown to an institution of more than 30,000 students, faculty, and staff...

  • 1999 - Samuel M. McElvain
    Samuel M. McElvain
    Samuel Marion McElvain was an American chemist. McElvain studied first at Washington University in St. Louis and received his MS and Ph.D from the University of Illinois in 1923. In 1923 he became professor at the University of Wisconsin–Madison, from which he retired in 1961.-References:...

     Lecturer, University of Wisconsin–Madison
    University of Wisconsin–Madison
    The University of Wisconsin–Madison is a public research university located in Madison, Wisconsin, United States. Founded in 1848, UW–Madison is the flagship campus of the University of Wisconsin System. It became a land-grant institution in 1866...

  • 1997 - Elected Fellow of The Royal Society (United Kingdom)
  • 1996 - Recipient of an Honorary Doctorate in Physics from the University of Genoa
    University of Genoa
    The University of Genoa is one of the largest universities in Italy.Located in Liguria on the Italian Riviera, the university was founded in 1471. It currently has about 40,000 students, 1,800 teaching and research staff and about 1,580 administrative staff.- Campus :The University of Genoa is...

  • 1995 - Recipient of a Senior Fellowship of the Alexander von Humboldt Foundation
    Alexander von Humboldt Foundation
    The Alexander von Humboldt Foundation is a foundation set-up by the government of the Federal Republic and funded by the German Foreign Office, the Ministry of Education and Research, the Ministry of Economic Cooperation and Development and others for the promotion of international co-operation...

  • 1995 - Recipient of the 1995 Lippincott Award of the Optical Society of America
    Optical Society of America
    The Optical Society is a scientific society dedicated to advancing the study of light—optics and photonics—in theory and application, by means of publishing, organizing conferences and exhibitions, partnership with industry, and education. The organization has members in more than 100 countries...

    , the Coblentz Society, and the Society for Applied Spectroscopy
    Society for Applied Spectroscopy
    The Society for Applied Spectroscopy is an organization promoting research and education in the fields of spectroscopy, optics, and analytical chemistry. Founded in 1958, it is currently headquartered in Frederick, MD...

  • 1986 -Senior Killam Fellowship.
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