Tertiary amyl methyl ether
Encyclopedia
tert-Amyl methyl ether (TAME) is an ether
Ether
Ethers are a class of organic compounds that contain an ether group — an oxygen atom connected to two alkyl or aryl groups — of general formula R–O–R'. A typical example is the solvent and anesthetic diethyl ether, commonly referred to simply as "ether"...

 used as a fuel oxygenate. It has an ethereous odor
Odor
An odor or odour is caused by one or more volatilized chemical compounds, generally at a very low concentration, that humans or other animals perceive by the sense of olfaction. Odors are also commonly called scents, which can refer to both pleasant and unpleasant odors...

. Unlike most ethers, does not form peroxides on storage.

Uses

TAME is mostly used as an oxygenate
Oxygenate
Oxygenated chemical compounds contain oxygen as a part of their chemical structure. The term usually refers to oxygenated fuels. Oxygenates are usually employed as gasoline additives to reduce carbon monoxide that is created during the burning of the fuel....

 to gasoline. It is added for three reasons: to increase octane
Octane
Octane is a hydrocarbon and an alkane with the chemical formula C8H18, and the condensed structural formula CH36CH3. Octane has many structural isomers that differ by the amount and location of branching in the carbon chain...

 enhancement, to replace banned tetraethyl lead, and to raise the oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

 content in gasoline
Gasoline
Gasoline , or petrol , is a toxic, translucent, petroleum-derived liquid that is primarily used as a fuel in internal combustion engines. It consists mostly of organic compounds obtained by the fractional distillation of petroleum, enhanced with a variety of additives. Some gasolines also contain...

. It is known that TAME in fuel reduces exhaust
Exhaust gas
Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline/petrol, diesel fuel, fuel oil or coal. According to the type of engine, it is discharged into the atmosphere through an exhaust pipe, flue gas stack or propelling nozzle.It often disperses...

 emissions
Motor vehicle emissions
Motor vehicle emissions are composed of the by-products that comes out of the exhaust systems or other emissions such as gasoline evaporation...

 of some volatile organic compounds.

Toxicity

When exposed to lab rats at 4000 ppm only 25% survived, the rats that died, died of central nervous system depression.

See also

  • Methyl tert-butyl ether
    Methyl tert-butyl ether
    Methyl tert-butyl ether, also known as methyl tertiary butyl ether and MTBE, is an organic compound with molecular formula 3COCH3. MTBE is a volatile, flammable, and colorless liquid that is immiscible with water. It has a minty odor vaguely reminiscent of diethyl ether, leading to unpleasant taste...

  • Ethyl tert-butyl ether
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