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Sonoluminescence

Sonoluminescence

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Sonoluminescence is the emission of short bursts of light
Light
Light or visible light is electromagnetic radiation that is visible to the human eye, and is responsible for the sense of sight. Visible light has wavelength in a range from about 380 nanometres to about 740 nm, with a frequency range of about 405 THz to 790 THz...

 from imploding bubble
Liquid bubble
A bubble is a globule of one substance in another, usually gas in a liquid.Due to the Marangoni effect, bubbles may remain intact when they reach the surface of the immersive substance.-Common examples:...

s in a liquid
Liquid
Liquid is one of the three classical states of matter . Like a gas, a liquid is able to flow and take the shape of a container. Some liquids resist compression, while others can be compressed. Unlike a gas, a liquid does not disperse to fill every space of a container, and maintains a fairly...

 when excited by sound
Sound
Sound is a mechanical wave that is an oscillation of pressure transmitted through a solid, liquid, or gas, composed of frequencies within the range of hearing and of a level sufficiently strong to be heard, or the sensation stimulated in organs of hearing by such vibrations.-Propagation of...

.

History


The effect was first discovered at the University of Cologne
University of Cologne
The University of Cologne is one of the oldest universities in Europe and, with over 44,000 students, one of the largest universities in Germany. The university is part of the Deutsche Forschungsgemeinschaft, an association of Germany's leading research universities...

 in 1934 as a result of work on sonar
Sonar
Sonar is a technique that uses sound propagation to navigate, communicate with or detect other vessels...

. H. Frenzel and H. Schultes put an ultrasound transducer
Transducer
A transducer is a device that converts one type of energy to another. Energy types include electrical, mechanical, electromagnetic , chemical, acoustic or thermal energy. While the term transducer commonly implies the use of a sensor/detector, any device which converts energy can be considered a...

 in a tank of photograph
Photograph
A photograph is an image created by light falling on a light-sensitive surface, usually photographic film or an electronic imager such as a CCD or a CMOS chip. Most photographs are created using a camera, which uses a lens to focus the scene's visible wavelengths of light into a reproduction of...

ic developer fluid. They hoped to speed up the development process. Instead, they noticed tiny dots on the film after developing and realized that the bubbles in the fluid were emitting light with the ultrasound turned on. It was too difficult to analyze the effect in early experiments because of the complex environment of a large number of short-lived bubbles. (This experiment is also ascribed to N. Marinesco and J.J. Trillat in 1933, which also credits them with independent discovery). This phenomenon is now referred to as multi-bubble sonoluminescence (MBSL).

In 1989 a major experimental advance was introduced by Felipe Gaitan and Lawrence Crum, who produced stable single-bubble sonoluminescence (SBSL). In SBSL, a single bubble trapped in an acoustic standing wave, emits a pulse of light with each compression of the bubble within the standing wave
Standing wave
In physics, a standing wave – also known as a stationary wave – is a wave that remains in a constant position.This phenomenon can occur because the medium is moving in the opposite direction to the wave, or it can arise in a stationary medium as a result of interference between two waves traveling...

. This technique allowed a more system
System
System is a set of interacting or interdependent components forming an integrated whole....

atic study of the phenomenon
Phenomenon
A phenomenon , plural phenomena, is any observable occurrence. Phenomena are often, but not always, understood as 'appearances' or 'experiences'...

, because it isolated the complex effects into one stable, predictable bubble. It was realized that the temperature inside the bubble was hot enough to melt steel
Steel
Steel is an alloy that consists mostly of iron and has a carbon content between 0.2% and 2.1% by weight, depending on the grade. Carbon is the most common alloying material for iron, but various other alloying elements are used, such as manganese, chromium, vanadium, and tungsten...

. Interest in sonoluminescence was renewed when an inner temperature
Temperature
Temperature is a physical property of matter that quantitatively expresses the common notions of hot and cold. Objects of low temperature are cold, while various degrees of higher temperatures are referred to as warm or hot...

 of such a bubble well above one million kelvin
Kelvin
The kelvin is a unit of measurement for temperature. It is one of the seven base units in the International System of Units and is assigned the unit symbol K. The Kelvin scale is an absolute, thermodynamic temperature scale using as its null point absolute zero, the temperature at which all...

s was postulated. This temperature is thus far not conclusively proven, though recent experiments conducted by the University of Illinois at Urbana-Champaign
University of Illinois at Urbana-Champaign
The University of Illinois at Urbana–Champaign is a large public research-intensive university in the state of Illinois, United States. It is the flagship campus of the University of Illinois system...

 indicate temperatures around . Research has also been carried out by Dr. Klaus Fritsch of John Carroll University
John Carroll University
John Carroll University is a private, co-educational Jesuit Catholic university in University Heights, Ohio, United States, a suburb of Cleveland. The university was founded in 1886 by the Society of Jesus as Saint Ignatius College.The university was founded in 1886 by the Society of Jesus, as...

, University Heights, Ohio.

The US Navy studied propeller-induced sonoluminescence during the Cold War
Cold War
The Cold War was the continuing state from roughly 1946 to 1991 of political conflict, military tension, proxy wars, and economic competition between the Communist World—primarily the Soviet Union and its satellite states and allies—and the powers of the Western world, primarily the United States...

.

Properties


Sonoluminescence can occur when a sound wave of sufficient intensity induces a gaseous cavity within a liquid to collapse quickly. This cavity may take the form of a pre-existing bubble, or may be generated through a process known as cavitation
Cavitation
Cavitation is the formation and then immediate implosion of cavities in a liquidi.e. small liquid-free zones that are the consequence of forces acting upon the liquid...

. Sonoluminescence in the laboratory can be made to be stable, so that a single bubble will expand and collapse over and over again in a periodic fashion, emitting a burst of light each time it collapses. For this to occur, a standing acoustic wave is set up within a liquid, and the bubble will sit at a pressure anti-node of the standing wave. The frequencies
Frequency
Frequency is the number of occurrences of a repeating event per unit time. It is also referred to as temporal frequency.The period is the duration of one cycle in a repeating event, so the period is the reciprocal of the frequency...

 of resonance
Resonance
In physics, resonance is the tendency of a system to oscillate at a greater amplitude at some frequencies than at others. These are known as the system's resonant frequencies...

 depend on the shape and size of the container in which the bubble is contained.

Some facts about sonoluminescence:
  • The light flashes from the bubbles are extremely short—between 35 and a few hundred picosecond
    Picosecond
    A picosecond is 10−12 of a second. That is one trillionth, or one millionth of one millionth of a second, or 0.000 000 000 001 seconds. A picosecond is to one second as one second is to 31,700 years....

    s long—with peak intensities of the order of 1–.
  • The bubbles are very small when they emit the light—about 1 micrometre
    Micrometre
    A micrometer , is by definition 1×10-6 of a meter .In plain English, it means one-millionth of a meter . Its unit symbol in the International System of Units is μm...

     in diameter—depending on the ambient fluid (e.g., water
    Water
    Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

    ) and the gas content of the bubble (e.g., atmospheric air
    Earth's atmosphere
    The atmosphere of Earth is a layer of gases surrounding the planet Earth that is retained by Earth's gravity. The atmosphere protects life on Earth by absorbing ultraviolet solar radiation, warming the surface through heat retention , and reducing temperature extremes between day and night...

    ).
  • Single-bubble sonoluminescence pulses can have very stable periods and positions. In fact, the frequency of light flashes can be more stable than the rated frequency stability of the oscillator making the sound waves driving them. However, the stability analyses of the bubble show that the bubble itself undergoes significant geometric instabilities, due to, for example, the Bjerknes forces and Rayleigh–Taylor instabilities.
  • The addition of a small amount of noble gas
    Noble gas
    The noble gases are a group of chemical elements with very similar properties: under standard conditions, they are all odorless, colorless, monatomic gases, with very low chemical reactivity...

     (such as helium
    Helium
    Helium is the chemical element with atomic number 2 and an atomic weight of 4.002602, which is represented by the symbol He. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas that heads the noble gas group in the periodic table...

    , argon
    Argon
    Argon is a chemical element represented by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table . Argon is the third most common gas in the Earth's atmosphere, at 0.93%, making it more common than carbon dioxide...

    , or xenon
    Xenon
    Xenon is a chemical element with the symbol Xe and atomic number 54. The element name is pronounced or . A colorless, heavy, odorless noble gas, xenon occurs in the Earth's atmosphere in trace amounts...

    ) to the gas in the bubble increases the intensity of the emitted light.


Spectral measurements have given bubble temperatures in the range from to , the exact temperatures depending on experimental conditions including the composition of the liquid and gas. Detection of very high bubble temperatures by spectral methods is limited due to the opacity of liquids to short wavelength light characteristic of very high temperatures.

Writing in Nature
Nature (journal)
Nature, first published on 4 November 1869, is ranked the world's most cited interdisciplinary scientific journal by the Science Edition of the 2010 Journal Citation Reports...

, chemists David J. Flannigan and Kenneth S. Suslick
Kenneth S. Suslick
Kenneth S. Suslick is the Marvin T. Schmidt Professor of Chemistry, Professor of Materials Science & Engineering, and Professor of the Beckman Institute for Advanced Science & Engineering at the University of Illinois at Urbana-Champaign...

 describe a method of determining temperatures based on the formation of plasmas
Plasma (physics)
In physics and chemistry, plasma is a state of matter similar to gas in which a certain portion of the particles are ionized. Heating a gas may ionize its molecules or atoms , thus turning it into a plasma, which contains charged particles: positive ions and negative electrons or ions...

. Using argon bubbles in sulfuric acid
Sulfuric acid
Sulfuric acid is a strong mineral acid with the molecular formula . Its historical name is oil of vitriol. Pure sulfuric acid is a highly corrosive, colorless, viscous liquid. The salts of sulfuric acid are called sulfates...

, their data show the presence of ionized molecular oxygen O2+, sulfur monoxide
Sulfur monoxide
Sulfur monoxide is an inorganic compound with formula . It is only found as a dilute gas phase. When concentrated or condensed, it converts to S2O2 . It has been detected in space but is rarely encountered intact otherwise.-Structure and bonding:The SO molecule has a triplet ground state similar...

, and atomic argon populating high-energy excited states, which confirms a hypothesis that the bubbles have a hot plasma core. The ionization
Ionization
Ionization is the process of converting an atom or molecule into an ion by adding or removing charged particles such as electrons or other ions. This is often confused with dissociation. A substance may dissociate without necessarily producing ions. As an example, the molecules of table sugar...

 and excitation
Excited state
Excitation is an elevation in energy level above an arbitrary baseline energy state. In physics there is a specific technical definition for energy level which is often associated with an atom being excited to an excited state....

 energy of dioxygenyl
Ozonide
Ozonide is an unstable, reactive polyatomic anion O3−, derived from ozone, or an organic compound similar to organic peroxide formed by a reaction of ozone with an unsaturated compound.-Inorganic ozonides:...

 cations, which they observed, is 18 electronvolt
Electronvolt
In physics, the electron volt is a unit of energy equal to approximately joule . By definition, it is equal to the amount of kinetic energy gained by a single unbound electron when it accelerates through an electric potential difference of one volt...

s. From this they conclude the core temperatures reaches at least 20,000 kelvins.

Rayleigh–Plesset equation


The dynamics of the motion of the bubble is characterized to a first approximation by the Rayleigh-Plesset equation (named after Lord Rayleigh
John Strutt, 3rd Baron Rayleigh
John William Strutt, 3rd Baron Rayleigh, OM was an English physicist who, with William Ramsay, discovered the element argon, an achievement for which he earned the Nobel Prize for Physics in 1904...

 and Milton Plesset
Milton S. Plesset
Milton Spinoza Plesset was an American applied physicist who worked in the field of fluid mechanics and nuclear energy. He was elected to the National Academy of Engineering in 1979 for his fundamental contributions to multiphase flows, bubble dynamics, and safety of nuclear reactors...

):


This is an approximate equation that is derived from the incompressible Navier-Stokes equations
Navier-Stokes equations
In physics, the Navier–Stokes equations, named after Claude-Louis Navier and George Gabriel Stokes, describe the motion of fluid substances. These equations arise from applying Newton's second law to fluid motion, together with the assumption that the fluid stress is the sum of a diffusing viscous...

 (written in spherical coordinate system
Spherical coordinate system
In mathematics, a spherical coordinate system is a coordinate system for three-dimensional space where the position of a point is specified by three numbers: the radial distance of that point from a fixed origin, its inclination angle measured from a fixed zenith direction, and the azimuth angle of...

) and describes the motion of the radius of the bubble R as a function of time t. Here, μ is the viscosity
Viscosity
Viscosity is a measure of the resistance of a fluid which is being deformed by either shear or tensile stress. In everyday terms , viscosity is "thickness" or "internal friction". Thus, water is "thin", having a lower viscosity, while honey is "thick", having a higher viscosity...

, p the pressure
Pressure
Pressure is the force per unit area applied in a direction perpendicular to the surface of an object. Gauge pressure is the pressure relative to the local atmospheric or ambient pressure.- Definition :...

, and γ the surface tension
Surface tension
Surface tension is a property of the surface of a liquid that allows it to resist an external force. It is revealed, for example, in floating of some objects on the surface of water, even though they are denser than water, and in the ability of some insects to run on the water surface...

. The over-dots represent time derivatives. This equation, though approximate, has been shown to give good estimates on the motion of the bubble under the acoustically
Acoustics
Acoustics is the interdisciplinary science that deals with the study of all mechanical waves in gases, liquids, and solids including vibration, sound, ultrasound and infrasound. A scientist who works in the field of acoustics is an acoustician while someone working in the field of acoustics...

 driven field except during the final stages of collapse. Both simulation and experimental measurement show that during the critical final stages of collapse, the bubble wall velocity exceeds the speed of sound of the gas inside the bubble. Thus a more detailed analysis of the bubble's motion is needed beyond Rayleigh-Plesset to explore the additional energy focusing that an internally formed shock wave might produce.

Mechanism of phenomenon



The mechanism of the phenomenon of sonoluminescence remains unsettled. Theories include: hotspot, bremsstrahlung
Bremsstrahlung
Bremsstrahlung is electromagnetic radiation produced by the deceleration of a charged particle when deflected by another charged particle, typically an electron by an atomic nucleus. The moving particle loses kinetic energy, which is converted into a photon because energy is conserved. The term is...

 radiation, collision-induced radiation and corona discharge
Corona discharge
In electricity, a corona discharge is an electrical discharge brought on by the ionization of a fluid surrounding a conductor that is electrically energized...

s, nonclassical light
Nonclassical light
Nonclassical light is any state of light that cannot be described using classical electromagnetism; its characteristics are described by the quantised electromagnetic field and quantum mechanics...

, proton tunneling
Quantum tunnelling
Quantum tunnelling refers to the quantum mechanical phenomenon where a particle tunnels through a barrier that it classically could not surmount. This plays an essential role in several physical phenomena, such as the nuclear fusion that occurs in main sequence stars like the sun, and has important...

, electrodynamic jets
Jet (fluid)
A jet is an efflux of fluid that is projected into a surrounding medium, usually from some kind of a nozzle, aperture or orifice. Jets can travel long distances without dissipating...

 and fractoluminescent jets (now largely discredited due to contrary experimental evidence).

In 2002, M. Brenner, S. Hilgenfeldt, and D. Lohse published a 60-page review bubble sonoluminescence" (Reviews of Modern Physics 74, 425) that contains a detailed explanation of the mechanism. An important factor is that the bubble contains mainly inert noble gas such as argon or xenon (air contains about 1% argon, and the amount dissolved in water is too great; for sonoluminescence to occur, the concentration must be reduced to 20–40% of its equilibrium value) and varying amounts of water vapor
Water vapor
Water vapor or water vapour , also aqueous vapor, is the gas phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Under typical atmospheric conditions, water vapor is continuously...

. Chemical reactions cause nitrogen
Nitrogen
Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...

 and oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

 to be removed from the bubble after about one hundred expansion-collapse cycles. The bubble will then begin to emit light for Gas Exchange in Single-Bubble Sonoluminescence", Matula and Crum, Phys. Rev. Lett. 80 (1998), 865-868). The light emission of highly compressed noble gas is exploited technologically in the argon flash
Argon flash
Argon flash, also known as argon bomb, argon flash bomb, argon candle, and argon light source, is a single-use source of very short and extremely bright flashes of light. The light is generated by a shock wave in argon or, less commonly, other noble gas. The shock wave is usually produced by an...

 devices.

During bubble collapse, the inertia of the surrounding water causes high pressure and high temperature, reaching around 10,000 kelvins in the interior of the bubble, causing the ionization of a small fraction of the noble gas present. The amount ionized is small enough for the bubble to remain transparent, allowing volume emission; surface emission would produce more intense light of longer duration, dependent on wavelength
Wavelength
In physics, the wavelength of a sinusoidal wave is the spatial period of the wave—the distance over which the wave's shape repeats.It is usually determined by considering the distance between consecutive corresponding points of the same phase, such as crests, troughs, or zero crossings, and is a...

, contradicting experimental results. Electrons from ionized atoms interact mainly with neutral atoms, causing thermal bremsstrahlung radiation. As the wave hits a low energy trough, the pressure drops, allowing electrons to recombine
Carrier generation and recombination
In the solid state physics of semiconductors, carrier generation and recombination are processes by which mobile charge carriers are created and eliminated. Carrier generation and recombination processes are fundamental to the operation of many optoelectronic semiconductor devices, such as...

 with atoms and light emission to cease due to this lack of free electrons. This makes for a 160-picosecond light pulse for argon (even a small drop in temperature causes a large drop in ionization, due to the large ionization energy
Ionization energy
The ionization energy of a chemical species, i.e. an atom or molecule, is the energy required to remove an electron from the species to a practically infinite distance. Large atoms or molecules have a low ionization energy, while small molecules tend to have higher ionization energies.The property...

 relative to photon energy). This description is simplified from the literature above, which details various steps of differing duration from 15 microseconds (expansion) to 100 picoseconds (emission).

Computations based on the theory presented in the review produce radiation parameters (intensity and duration time versus wavelength) that match experimental results with errors no larger than expected due to some simplifications (e.g. assuming a uniform temperature in the entire bubble), so it seems the phenomenon of sonoluminescence is at least roughly explained, although some details of the process remain obscure.

Any discussion of sonoluminescence(SL) must include a detailed analysis of metastability. SL in this respect is what is physically termed a bounded phenomenon meaning that the SL exists in a bounded region of parameter space for the bubble; a coupled magnetic field being one such parameter. The magnetic aspects of SL are very well documented.

Please see in High Magnetic Fields, J.B. Young, T. Schiemedel and Woowan Kang" (Physical Review Letters 77, 4816)

Exotic proposals


An unusually exotic theory of sonoluminescence, which has received much popular attention, is the Casimir energy theory suggested by noted physicist Julian Schwinger
Julian Schwinger
Julian Seymour Schwinger was an American theoretical physicist. He is best known for his work on the theory of quantum electrodynamics, in particular for developing a relativistically invariant perturbation theory, and for renormalizing QED to one loop order.Schwinger is recognized as one of the...

 and more thoroughly considered in a paper by Claudia Eberlein of the University of Sussex
University of Sussex
The University of Sussex is an English public research university situated next to the East Sussex village of Falmer, within the city of Brighton and Hove. The University received its Royal Charter in August 1961....

. Eberlein's paper suggests that the light in sonoluminescence is generated by the vacuum within the bubble in a process similar to Hawking radiation
Hawking radiation
Hawking radiation is a thermal radiation with a black body spectrum predicted to be emitted by black holes due to quantum effects. It is named after the physicist Stephen Hawking, who provided a theoretical argument for its existence in 1974, and sometimes also after the physicist Jacob Bekenstein...

, the radiation generated at the event horizon
Event horizon
In general relativity, an event horizon is a boundary in spacetime beyond which events cannot affect an outside observer. In layman's terms it is defined as "the point of no return" i.e. the point at which the gravitational pull becomes so great as to make escape impossible. The most common case...

 of black hole
Black hole
A black hole is a region of spacetime from which nothing, not even light, can escape. The theory of general relativity predicts that a sufficiently compact mass will deform spacetime to form a black hole. Around a black hole there is a mathematically defined surface called an event horizon that...

s. According to this vacuum energy explanation, since quantum theory holds that vacuum contains virtual particle
Virtual particle
In physics, a virtual particle is a particle that exists for a limited time and space. The energy and momentum of a virtual particle are uncertain according to the uncertainty principle...

s, the rapidly moving interface between water and gas converts virtual photons into real photons. This is related to the Unruh effect
Unruh effect
The Unruh effect , was first described by Stephen Fulling in 1973, Paul Davies in 1975 and Bill Unruh in 1976. It is the prediction that an accelerating observer will observe black-body radiation where an inertial observer would observe none...

 or the Casimir effect
Casimir effect
In quantum field theory, the Casimir effect and the Casimir–Polder force are physical forces arising from a quantized field. The typical example is of two uncharged metallic plates in a vacuum, like capacitors placed a few micrometers apart, without any external electromagnetic field...

. If true, sonoluminescence may be the first observable example of quantum vacuum radiation
Vacuum state
In quantum field theory, the vacuum state is the quantum state with the lowest possible energy. Generally, it contains no physical particles...

. The argument has been made that sonoluminescence releases too large an amount of energy and releases the energy on too short a time scale to be consistent with the vacuum energy explanation, although other credible sources argue the vacuum energy explanation might yet prove to be correct.

Nuclear reactions


Some have argued that the Rayleigh-Plesset equation described above is unreliable for predicting bubble temperatures and that actual temperatures in sonoluminescing systems can be far higher than 20,000 kelvins. Some research claims to have measured temperatures as high as 100,000 kelvins, and speculates temperatures can reach into the millions of kelvins. Temperatures this high could cause thermonuclear fusion. This possibility is sometimes referred to as bubble fusion
Bubble fusion
Bubble fusion, also known as sonofusion, is the non-technical name for a nuclear fusion reaction hypothesized to occur during a high-pressure version of sonoluminescence, an extreme form of acoustic cavitation...

.

On January 27, 2006, researchers at Rensselaer Polytechnic Institute
Rensselaer Polytechnic Institute
Stephen Van Rensselaer established the Rensselaer School on November 5, 1824 with a letter to the Rev. Dr. Samuel Blatchford, in which van Rensselaer asked Blatchford to serve as the first president. Within the letter he set down several orders of business. He appointed Amos Eaton as the school's...

 claimed to have produced fusion in sonoluminescence experiments.

Experiments (2002, 2005) of R. P. Taleyarkhan
Rusi Taleyarkhan
Rusi P. Taleyarkhan is a faculty member in the Department of Nuclear Engineering at Purdue University since 2003. Prior to that, he was on staff at the Oak Ridge National Laboratory in Oak Ridge, Tennessee...

, et al., using deuterated acetone
Acetone
Acetone is the organic compound with the formula 2CO, a colorless, mobile, flammable liquid, the simplest example of the ketones.Acetone is miscible with water and serves as an important solvent in its own right, typically as the solvent of choice for cleaning purposes in the laboratory...

 show measurements of tritium
Tritium
Tritium is a radioactive isotope of hydrogen. The nucleus of tritium contains one proton and two neutrons, whereas the nucleus of protium contains one proton and no neutrons...

 and neutron output consistent with fusion, but these measurements remain controversial.

In November 2006, in the midst of charges leveled at Taleyarkhan as regards his research standards, Dr. Edward R. Forringer and undergraduates David Robbins and Jonathan Martin of LeTourneau University
LeTourneau University
LeTourneau University is a private, interdenominational Christian university located in Longview, Texas, United States with flagship programs in engineering, aeronautical science, business and education...

 presented two papers at the American Nuclear Society
American Nuclear Society
The American Nuclear Society is an international, not-for-profit 501 scientific and educational organization with a membership of approximately 11,000 scientists, engineers, educators, students, and other associate members. Approximately 900 members live outside the United States in 40 countries....

 Winter Meeting that reported replication of neutron emission during a visit to the meta-stable fluids research lab at Purdue University. Their experimental setup was similar to the preceding experiments in that it used a mixture of deuterated acetone, deuterated benzene
Deuterated benzene
Deuterated benzene , is a form of benzene in which the hydrogen atom is replaced with deuterium isotope . Deuterated benzene is a common solvent used in NMR spectroscopy....

, tetrachloroethylene
Tetrachloroethylene
Tetrachloroethylene, also known under its systematic name tetrachloroethene and many other names, is a chlorocarbon with the formula Cl2C=CCl2. It is a colourless liquid widely used for dry cleaning of fabrics, hence it is sometimes called "dry-cleaning fluid." It has a sweet odor detectable by...

 and uranyl nitrate
Uranyl nitrate
Uranyl nitrate is a water soluble yellow uranium salt. The yellow-green crystals of uranium nitrate hexahydrate are triboluminescent.Uranyl nitrate can be prepared by reaction of uranium salts with nitric acid...

. Notably, however, it operated without an external neutron source and used two types of neutron detectors
Neutron detection
Neutron detection is the effective detection of neutrons entering a well-positioned detector. There are two key aspects to effective neutron detection: hardware and software. Detection hardware refers to the kind of neutron detector used and to the electronics used in the detection setup...

.

Biological sonoluminescence


Pistol shrimp
Alpheidae
Alpheidae is a family of caridean snapping shrimp characterized by having asymmetrical claws, the larger of which is typically capable of producing a loud snapping sound. Other common names of these species include pistol shrimp or alpheid shrimp.The family is diverse and worldwide in distribution,...

 (also called "snapping shrimp") produce a type of sonoluminescence from a collapsing bubble caused by quickly snapping a specialized claw. The light produced is of lower intensity than the light produced by typical sonoluminescence and is not visible to the naked eye. The light and heat produced may have no direct significance, as it is the shockwave produced by the rapidly collapsing bubble which these shrimp use to stun or kill prey. However, it is the first known instance of an animal producing light by this effect and was whimsically dubbed "shrimpoluminescence" upon its discovery in 2001. It has subsequently been discovered that another group of crustaceans, the mantis shrimp
Mantis shrimp
Mantis shrimp or stomatopods are marine crustaceans, the members of the order Stomatopoda. They are neither shrimp nor mantids, but receive their name purely from the physical resemblance to both the terrestrial praying mantis and the shrimp. They may reach in length, although exceptional cases of...

, contains species whose club-like forelimbs can strike so quickly and with such force as to induce sonoluminescent cavitation bubbles upon impact.

General references


External links


Newer research papers largely rule out the vacuum energy explanation