Skull crucible
Encyclopedia
The Skull Crucible process was developed at the Lebedev Physical Institute
Lebedev Physical Institute
The Lebedev Physics Institute of the Russian Academy of Sciences , situated in Moscow, is one of the leading Russian research institutes specializing in physics. It is also one of the oldest research institutions in Russia: its history dates back to a collection of physics equipment established by...

 in Moscow
Moscow
Moscow is the capital, the most populous city, and the most populous federal subject of Russia. The city is a major political, economic, cultural, scientific, religious, financial, educational, and transportation centre of Russia and the continent...

 to manufacture cubic zirconia
Cubic zirconia
Cubic zirconia is the cubic crystalline form of zirconium dioxide . The synthesized material is hard, optically flawless and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zirconium silicate...

. Zirconium oxide powder is heated then gradually allowed to cool. Heating is accomplished by radio frequency induction using a coil wrapped around the apparatus. The outside of the device is water-cooled
Water jacket
A water jacket is a water-filled void surrounding a device, typically a metal sheath having intake and outlet vents to allow water to be pumped through the void. The flow of water to an external heating or cooling device allows precise temperature control of the device.-Applications:Water jackets...

 in order to keep the RF coil from melting and also to cool the outside of the zirconium oxide and thus maintain the shape of the zirconium powder.

Since zirconium oxide in its solid state does not conduct electricity
Electricity
Electricity is a general term encompassing a variety of phenomena resulting from the presence and flow of electric charge. These include many easily recognizable phenomena, such as lightning, static electricity, and the flow of electrical current in an electrical wire...

 a piece of zirconium
Zirconium
Zirconium is a chemical element with the symbol Zr and atomic number 40. The name of zirconium is taken from the mineral zircon. Its atomic mass is 91.224. It is a lustrous, grey-white, strong transition metal that resembles titanium...

 metal is placed inside the gob of zirconium oxide. As the zirconium melts it oxidizes and blends with the now molten zirconium oxide which now will conduct electricity and be heated by RF induction.

When the zirconium oxide is melted on the inside (but not completely, since the outside needs to remain solid) the amplitude of the RF induction coil is gradually reduced and crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...

s form as the material cools. Normally this would form zirconium oxide crystals with a monoclinic
Monoclinic crystal system
In crystallography, the monoclinic crystal system is one of the 7 lattice point groups. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal length, as in the orthorhombic system. They form a rectangular prism with a...

 crystal structure
Crystal structure
In mineralogy and crystallography, crystal structure is a unique arrangement of atoms or molecules in a crystalline liquid or solid. A crystal structure is composed of a pattern, a set of atoms arranged in a particular way, and a lattice exhibiting long-range order and symmetry...

. In order to maintain a cubic crystal structure
Cubic crystal system
In crystallography, the cubic crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals....

 a stabilizer is added, magnesium
Magnesium oxide
Magnesium oxide , or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium . It has an empirical formula of and consists of a lattice of Mg2+ ions and O2– ions held together by ionic bonds...

, calcium
Calcium oxide
Calcium oxide , commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline crystalline solid at room temperature....

 or yttrium oxide as well as any material add to color the crystal.

After the mixture cools the outer shell is broken off and the interior of the gob is then used to manufacture gemstone
Gemstone
A gemstone or gem is a piece of mineral, which, in cut and polished form, is used to make jewelry or other adornments...

s.
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