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Silicate minerals
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The silicate minerals make up the largest and most important class of rock-forming minerals, comprising approximately 90 percent of the crust of the Earth. They are classified based on the structure of their silicate group. Silicate minerals all contain silicon and oxygen.
silicates, or orthosilicates, have isolated [SiO4]4- tetrahedra that are connected only by interstitial cations.
*Al2SiO5 group
silicates have isolated double tetrahedra groups with (Si2O7)6- or a ratio of 2:7.
osilicates, or ring silicates, have linked tetrahedra with (SixO3x)2x- or a ratio of 1:3.

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Encyclopedia
The silicate minerals make up the largest and most important class of rock-forming minerals, comprising approximately 90 percent of the crust of the Earth. They are classified based on the structure of their silicate group. Silicate minerals all contain silicon and oxygen.
Nesosilicates or isosilicates
Nesosilicates, or orthosilicates, have isolated [SiO4]4- tetrahedra that are connected only by interstitial cations.
*Al2SiO5 group
Sorosilicates
Sorosilicates have isolated double tetrahedra groups with (Si2O7)6- or a ratio of 2:7.
Cyclosilicates
Cyclosilicates, or ring silicates, have linked tetrahedra with (SixO3x)2x- or a ratio of 1:3. These exists as 3-member (Si3O9)6-, 4-member (Si4O12)8- and 6-member (Si6O18)12- rings.
- 3-member ring
- 4-member ring
- Axinite - (Ca,Fe,Mn)3Al2(BO3)(Si4O12)(OH)
- 6-member ring
Inosilicates
Inosilicates, or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3, 1:3 ratio, for single chains or Si4O11, 4:11 ratio, for double chains.
Single chain inosilicates
- Pyroxene group
- Enstatite - orthoferrosilite series
- Pigeonite - Ca0.25(Mg,Fe)1.75Si2O6
- Diopside - hedenbergite series
- Sodium pyroxene series
- Spodumene - LiAlSi2O6
- Pyroxenoid group
Double chain inosilicates
- Amphibole group
- Anthophyllite - (Mg,Fe)7Si8O22(OH)2
- Cumingtonite series
- Tremolite series
- Hornblende - (Ca,Na)2-3(Mg,Fe,Al)5Si6(Al,Si)2O22(OH)2
- Sodium amphibole group
Phyllosilicates
Phyllosilicates (from Greek f????? phyllon, leaf), or sheet silicates, form parallel sheets of silicate tetrahedra with Si2O5 or a 2:5 ratio.
- Serpentine group
- Antigorite - Mg3Si2O5(OH)4
- Chrysotile - Mg3Si2O5(OH)4
- Lizardite - Mg3Si2O5(OH)4
- Clay mineral group
- Kaolinite - Al2Si2O5(OH)4
- Illite - (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2,(H2O)]
- Smectite -
- Montmorillonite - (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2·nH2O
- Vermiculite - (MgFe,Al)3(Al,Si)4O10(OH)2·4H2O
- Talc - Mg3Si4O10(OH)2
- Palygorskite - (Mg,Al)2Si4O10(OH)·4(H2O)
- Pyrophyllite - Al2Si4O10(OH)2
- Mica group
- Chlorite group
- Chlorite - (Mg,Fe)3(Si,Al)4O10(OH)2•(Mg,Fe)3(OH)6
Tectosilicates
Tectosilicates, or "framework silicates", have a three-dimensional framework of silicate tetrahedra with SiO2 or a 1:2 ratio. This group comprises nearly 75% of the crust of the Earth. Tectosilicates, with the exception of the quartz group, are aluminosilicates.
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