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Quantum mechanics




 
 
Quantum mechanics is a set of principles underlying the most fundamental known description of all physical system
Physical system

In physics the word system has a technical meaning, namely, it is the portion of the physical universe chosen for analysis. Everything outside the system is known as the environment, which in analysis is ignored except for its effects on the system....
s at the microscopic scale (at the atomic level). Notable amongst these principles are both a dual wave-like and particle-like behavior of matter and radiation, and prediction of probabilities in situations where classical physics predicts certainties.






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For those who are not shocked when they first come across quantum theory cannot possibly have understood it.

Niels Bohr, quoted in





Encyclopedia


Hatomorbitals
Quantum mechanics is a set of principles underlying the most fundamental known description of all physical system
Physical system

In physics the word system has a technical meaning, namely, it is the portion of the physical universe chosen for analysis. Everything outside the system is known as the environment, which in analysis is ignored except for its effects on the system....
s at the microscopic scale (at the atomic level). Notable amongst these principles are both a dual wave-like and particle-like behavior of matter and radiation, and prediction of probabilities in situations where classical physics predicts certainties. Classical physics can be derived as a good approximation to quantum physics, typically in circumstances with large numbers of particles. Thus quantum phenomena are particularly relevant in systems whose dimensions are close to the atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
ic scale, such as molecule
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
s, atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
s, electron
Electron

The electron is a subatomic particle that carries a negative electric charge. It has elementary particle and is believed to be a point particle....
s, proton
Proton

The proton is a subatomic particle with an electric charge of +1 elementary charge. It is found in the nucleus of each atom but is also stable by itself and has a second identity as the hydrogen ion, H+....
s and other subatomic particle
Subatomic particle

A subatomic particle is an elementary particle or composite particle particle smaller than an atom. Particle physics and nuclear physics are concerned with the study of these particles, their interactions, and non-atomic QCD matter....
s. Exceptions exist for certain systems which exhibit quantum mechanical effects on macroscopic
Macroscopic

Macroscopic is a word commonly used to describe physics objects that are measurement and observation by the naked eye. When applied to phenomena and abstract objects, it describes existence in the world as we perceive it....
 scale; superfluid
Superfluid

Superfluidity is a phase or description of heat capacity in which unusual effects are observed when liquids, typically of helium-4 or helium-3, overcome friction by surface interaction when at a stage at which the liquid's viscosity becomes zero....
ity is one well-known example. Quantum theory provides accurate
Accuracy and precision

In the fields of science, engineering, industry and statistics, accuracy is the degree of closeness of a Measure d or calculated quantity to its actual Value ....
 descriptions for many previously unexplained phenomena such as black body radiation and stable electron orbits. It has also given insight into the workings of biological systems.

Overview


The word quantum is Latin for "how great" or "how much." In quantum mechanics, it refers to a discrete unit that quantum theory assigns to certain physical quantities, such as the energy
Energy

In physics, energy is a scalar physical quantity that describes the amount of Work_ that can be performed by a force. Energy is an attribute of objects and systems that is subject to a conservation law....
 of an atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
 at rest (see Figure 1, at right). The discovery that wave
Wave

A wave is a disturbance that propagates through space and time, usually with transference of energy. While a mechanical wave exists in a medium , waves of electromagnetic radiation can travel through vacuum, that is, without a medium....
s have discrete energy packets (called quanta) that behave in a manner similar to particle
Subatomic particle

A subatomic particle is an elementary particle or composite particle particle smaller than an atom. Particle physics and nuclear physics are concerned with the study of these particles, their interactions, and non-atomic QCD matter....
s led to the branch of physics that deals with atomic and subatomic systems which we today call quantum mechanics. It is the underlying mathematical framework of many fields of physics
Physics

Physics is the natural science which examines basic concepts such as energy, force, and spacetime and all that derives from these, such as mass, charge, matter and its Motion ....
 and chemistry
Chemistry

Chemistry is the science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions....
, including condensed matter physics
Condensed matter physics

Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter. In particular, it is concerned with the "condensed" phase that appear whenever the number of constituents in a system is extremely large and the interactions between the constituents are strong....
, solid-state physics
Solid-state physics

Solid-state physics, the largest branch of condensed matter physics, is the study of rigid matter, or solids, through methods such as quantum mechanics, crystallography, electromagnetism and metallurgy....
, atomic physics
Atomic physics

Atomic physics is the field of physics that studies atoms as an isolated system of electrons and an atomic nuclei. It is primarily concerned with the Electron configuration and...
, molecular physics
Molecular physics

Molecular physics is the study of the physical properties of molecules and of the chemical bonds between atoms that bind them. Its most important experimental techniques are the various types of spectroscopy....
, computational chemistry
Computational chemistry

Computational chemistry is a branch of chemistry that uses computers to assist in solving chemical problems. It uses the results of theoretical chemistry, incorporated into efficient computer programs, to calculate the structures and properties of molecules and solids....
, quantum chemistry
Quantum chemistry

Quantum chemistry is a branch of theoretical chemistry, which applies quantum mechanics and quantum field theory to address issues and problems in chemistry....
, particle physics
Particle physics

Particle physics is a branch of physics that studies the elementary particle constituents of matter and radiation, and the interactions between them....
, and nuclear physics
Nuclear physics

Nuclear physics is the field of physics that studies the building blocks and interactions of atomic nuclei.The most commonly known applications of nuclear physics are nuclear power and nuclear weapons, but the research field is also the basis for a far wider range of applications, including in the medical sector , in materials engineering...
. The foundations of quantum mechanics were established during the first half of the twentieth century by Werner Heisenberg
Werner Heisenberg

Werner Heisenberg was a German Theoretical physics who made foundational contributions to quantum mechanics and is best known for asserting the uncertainty principle of quantum theory....
, Max Planck
Max Planck

Karl Ernst Ludwig Marx Planck, better known as Max Planck was a Germany physicist. He is considered to be the founder of the Quantum mechanics, and one of the most important physicists of the twentieth century....
, Louis de Broglie, Albert Einstein
Albert Einstein

Albert Einstein was a Germany-born theoretical physics. He is best known for his theory of relativity and specifically mass?energy equivalence, expressed by the equation E = mc2....
, Niels Bohr
Niels Bohr

Niels Henrik David Bohr was a Denmark physicist who made fundamental contributions to understanding atomic structure and quantum mechanics, for which he received the Nobel Prize in Physics in 1922....
, Erwin Schrödinger
Erwin Schrödinger

Erwin Rudolf Josef Alexander Schr?dinger was an Austrian theoretical physicist who achieved fame for his contributions to quantum mechanics, especially the Schr?dinger equation, for which he received the Nobel Prize in 1933....
, Max Born
Max Born

Max Born was a Germany physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a number of notable physicists in the 1920s and 30s....
, John von Neumann, Paul Dirac
Paul Dirac

Paul Adrien Maurice Dirac, Order of Merit , Royal Society was a United Kingdom theoretical physicist. Dirac made fundamental contributions to the early development of both quantum mechanics and quantum electrodynamics....
, Wolfgang Pauli
Wolfgang Pauli

Wolfgang Ernst Pauli was an Austrian theoretical physicist noted for his work on spin , and for the discovery of the Pauli exclusion principle underpinning the structure of matter and the whole of chemistry....
 and others
List of physicists

Below is a list of famous physicists. Many of these from the 20th and 21st centuries are found on the list of recipients of the Nobel Prize in physics....
. Some fundamental aspects of the theory are still actively studied.

Quantum mechanics is essential to understand the behavior of systems at atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
ic length scales and smaller. For example, if classical mechanics
Classical mechanics

Classical mechanics is used for describing the motion of macroscopic objects, from projectiles to parts of machinery, as well as astronomical objects, such as spacecraft, planets, stars, and galaxies....
 governed the workings of an atom, electron
Electron

The electron is a subatomic particle that carries a negative electric charge. It has elementary particle and is believed to be a point particle....
s would rapidly travel towards and collide with the nucleus
Atomic nucleus

The nucleus of an atom is the very dense region, consisting of nucleons , at the center of an atom. Although the size of the nucleus varies considerably according to the mass of the atom, the size of the entire atom is comparatively constant....
, making stable atoms impossible. However, in the natural world the electrons normally remain in an unknown orbital path around the nucleus, defying classical electromagnetism.

Quantum mechanics was initially developed to provide a better explanation of the atom, especially the spectra
Spectrum

A spectrum is a condition that is not limited to a specific set of values but can vary infinitely within a Continuum . The word saw its first scientific use within the field of optics to describe the rainbow of colors in visible light when separated using a triangular prism ; it has since been applied by analogy to many fields other than op...
 of light
Light

Light, or visible light, is electromagnetic radiation of a wavelength that is Visible spectrum to the human eye , or up to 380?750 nm. In the broader field of physics, light is sometimes used to refer to electromagnetic radiation of all wavelengths, whether visible or not....
 emitted by different atomic species
Isotope

Isotopes are any of the different types of atoms of the same chemical element, each having a different atomic mass . Isotopes of an element have atomic nucleus with the same number of protons but different numbers of neutron....
. The quantum theory of the atom was developed as an explanation for the electron's staying in its orbital
Atomic orbital

An atomic orbital is a mathematical function that describes the wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus....
, which could not be explained by Newton's laws of motion and by Maxwell's laws
Maxwell's equations

In electromagnetism, James Clerk Maxwell equations are a set of four partial differential equations that describe the properties of the electric field and magnetic field fields and relate them to their sources, charge density and current density....
 of classical electromagnetism.

In the formalism of quantum mechanics, the state of a system at a given time is described by a complex
Complex number

In mathematics, the complex numbers are an extension of the real numbers obtained by adjoining an imaginary unit, denoted i, which satisfies:...
 wave function (sometimes referred to as orbitals in the case of atomic electrons), and more generally, elements of a complex vector space
Vector space

File:Vector addition ans scaling.pngA vector space is a mathematical structure formed by a collection of vectors: objects that may be Vector addition together and Scalar multiplication by numbers, called scalar s in this context....
. This abstract mathematical object allows for the calculation of probabilities
Probability

Probability, or wikt:chance, is a way of expressing knowledge or belief that an Event will occur or has occurred. In mathematics the concept has been given an exact meaning in probability theory, that is used extensively in such areas of study as mathematics, statistics, finance, gambling, science, and philosophy to draw conclusions about t...
 of outcomes of concrete experiments. For example, it allows one to compute the probability of finding an electron in a particular region around the nucleus at a particular time. Contrary to classical mechanics, one can never make simultaneous predictions of conjugate variables
Conjugate variables

In physics, conjugate variables are pair of variables mathematically defined in such a way that they become Fourier transform dual of one-another, or more generally are related through Pontryagin duality....
, such as position and momentum, with arbitrary accuracy. For instance, electrons may be considered to be located somewhere within a region of space, but with their exact positions being unknown. Contours of constant probability, often referred to as “clouds” may be drawn around the nucleus of an atom to conceptualize where the electron might be located with the most probability. Heisenberg's uncertainty principle
Uncertainty principle

In quantum physics, the Werner Heisenberg uncertainty principle states that certain physical quantities, like the position and momentum, cannot both have precise values at the same time....
 quantifies the inability to precisely locate the particle.

The other exemplar
Exemplar

Exemplar, in the sense developed by philosophy of science Thomas Samuel Kuhn, is a well known usage of a Scientific theories.According to Kuhn, scientific practice alternates between periods of normal science and extraordinary/revolutionary science....
 that led to quantum mechanics was the study of electromagnetic waves such as light. When it was found in 1900 by Max Planck that the energy of waves could be described as consisting of small packets or quanta, Albert Einstein
Albert Einstein

Albert Einstein was a Germany-born theoretical physics. He is best known for his theory of relativity and specifically mass?energy equivalence, expressed by the equation E = mc2....
 exploited this idea to show that an electromagnetic wave such as light could be described by a particle called the photon
Photon

In physics, the photon is an elementary particle, the quantum of the electromagnetic field and the basic unit of light and all other forms of electromagnetic radiation....
 with a discrete energy dependent on its frequency. This led to a theory of unity
Photon polarization

Photon polarization is the Quantum mechanics description of the Classical physics polarized sinusoidal plane wave electromagnetic wave. Individual photons are completely polarized....
 between subatomic particles and electromagnetic waves called wave–particle duality
Wave–particle duality

In physics and chemistry, wave?particle duality is the concept that all matter and energy exhibits both wave-like and Subatomic particle-like properties....
 in which particles and waves were neither one nor the other, but had certain properties of both. While quantum mechanics describes the world of the very small, it also is needed to explain certain “macroscopic
Macroscopic

Macroscopic is a word commonly used to describe physics objects that are measurement and observation by the naked eye. When applied to phenomena and abstract objects, it describes existence in the world as we perceive it....
 quantum systems” such as superconductors
Superconductivity

Superconductivity is a phenomenon occurring in certain materials generally at very low temperatures, characterized by exactly zero electrical resistance and the exclusion of the interior magnetic field ....
 and superfluid
Superfluid

Superfluidity is a phase or description of heat capacity in which unusual effects are observed when liquids, typically of helium-4 or helium-3, overcome friction by surface interaction when at a stage at which the liquid's viscosity becomes zero....
s.

Broadly speaking, quantum mechanics incorporates four classes of phenomena that classical physics cannot account for: (I) the quantization
Quantization (physics)

In physics, quantization is a procedure for constructing a quantum field theory starting from a classical field . This is a generalization of the procedure for building quantum mechanics from classical mechanics....
 (discretization) of certain physical quantities, (II) wave-particle duality, (III) the uncertainty principle
Uncertainty principle

In quantum physics, the Werner Heisenberg uncertainty principle states that certain physical quantities, like the position and momentum, cannot both have precise values at the same time....
, and (IV) quantum entanglement
Quantum entanglement

Quantum entanglement is a possible property of a quantum state of a system of two or more Physical bodys in which the quantum states of the constituting objects are linked together so that one object can no longer be adequately described without full mention of its counterpart ? even though the individual objects may be nonlocality....
. Each of these phenomena is described in detail in subsequent sections.

History


The history of quantum mechanics began essentially with the 1838 discovery of cathode rays by Michael Faraday
Michael Faraday

Michael Faraday, Fellow of the Royal Society was an English chemist and physicist who contributed to the fields of electromagnetism and electrochemistry....
, the 1859 statement of the black body radiation problem by Gustav Kirchhoff
Gustav Kirchhoff

Gustav Robert Kirchhoff was a Germany physicist who contributed to the fundamental understanding of electrical circuits, spectroscopy, and the emission of black-body radiation by heated objects....
, the 1877 suggestion by Ludwig Boltzmann
Ludwig Boltzmann

Ludwig Eduard Boltzmann was an Austrian physicist famous for his founding contributions in the fields of statistical mechanics and statistical thermodynamics....
 that the energy states of a physical system could be discrete, and the 1900 quantum hypothesis by Max Planck
Max Planck

Karl Ernst Ludwig Marx Planck, better known as Max Planck was a Germany physicist. He is considered to be the founder of the Quantum mechanics, and one of the most important physicists of the twentieth century....
 that any energy is radiated and absorbed in quantities divisible by discrete ‘energy elements’, E, such that each of these energy elements is proportional to the frequency
Frequency

Frequency is the number of occurrences of a repeating event per unit time. It is also referred to as temporal frequency.The period is the duration of one cycle in a repeating event, so the period is the reciprocal of the frequency....
 ? with which they each individually radiate energy
Energy

In physics, energy is a scalar physical quantity that describes the amount of Work_ that can be performed by a force. Energy is an attribute of objects and systems that is subject to a conservation law....
, as defined by the following formula:

where h is Planck's Action Constant. Although Planck insisted that this was simply an aspect of the processes of absorption and emission of radiation and had nothing to do with the physical reality of the radiation itself, in 1905, to explain the photoelectric effect
Photoelectric effect

The photoelectric effect is a phenomenon in which electrons are emitted from matter after the absorption of energy from electromagnetic wave such as x-rays or visible light....
 (1839), i.e. that shining light on certain materials can function to eject electrons from the material, Albert Einstein
Albert Einstein

Albert Einstein was a Germany-born theoretical physics. He is best known for his theory of relativity and specifically mass?energy equivalence, expressed by the equation E = mc2....
 postulated, as based on Planck’s quantum hypothesis, that light
Light

Light, or visible light, is electromagnetic radiation of a wavelength that is Visible spectrum to the human eye , or up to 380?750 nm. In the broader field of physics, light is sometimes used to refer to electromagnetic radiation of all wavelengths, whether visible or not....
 itself consists of individual quanta, which later came to be called photons (1926). From Einstein's simple postulation was borne a flurry of debating, theorizing and testing, and thus, the entire field of quantum physics.

Relativity and quantum mechanics


The modern world of physics is founded on the two tested and demonstrably sound theories of general relativity and quantum mechanics —theories which appear to contradict one another. The defining postulates of both Einstein's theory of relativity and quantum theory are indisputably supported by rigorous and repeated empirical evidence. However, while they do not directly contradict each other theoretically (at least with regard to primary claims), they are resistant to being incorporated within one cohesive model.

Einstein himself is well known for rejecting some of the claims of quantum mechanics. While clearly inventive in this field, he did not accept the more philosophical consequences and interpretations of quantum mechanics, such as the lack of deterministic causality
Causality

Causality denotes a necessary relationship between one event and another event which is the direct consequence of the first.While this informal understanding suffices in everyday use, the Philosophy analysis of how best to characterize causality extends over millennia....
 and the assertion that a single subatomic particle can occupy numerous areas of space at one time. He also was the first to notice some of the apparently exotic consequences of entanglement
Quantum entanglement

Quantum entanglement is a possible property of a quantum state of a system of two or more Physical bodys in which the quantum states of the constituting objects are linked together so that one object can no longer be adequately described without full mention of its counterpart ? even though the individual objects may be nonlocality....
 and used them to formulate the Einstein-Podolsky-Rosen paradox, in the hope of showing that quantum mechanics had unacceptable implications. This was 1935, but in 1964 it was shown by John Bell (see Bell inequality) that Einstein's assumption was correct, but had to be completed by hidden variables and thus based on wrong philosophical assumptions. According to the paper of J. Bell and the Copenhagen interpretation
Copenhagen interpretation

The Copenhagen interpretation is an Interpretations of quantum mechanics of quantum mechanics. A key feature of quantum mechanics is that the state of every Elementary particle is described by a wavefunction, which is a mathematical representation used to calculate the probability for it to be found in a location, or state of motion....
 (the common interpretation of quantum mechanics by physicists for decades), and contrary to Einstein's ideas, quantum mechanics was

  • neither a "realistic" theory (since quantum measurements do not state pre-existing properties, but rather they prepare properties)


  • nor a local
    Principle of locality

    In physics, the principle of locality states that an object is influenced directly only by its immediate surroundings. Quantum mechanics predicts through Bell's inequality the direct violation of this principle....
     theory (essentially not, because the state vector determines simultaneously the probability amplitude
    Probability amplitude

    In quantum mechanics, a probability amplitude is a complex number whose Absolute value squared represents a probability or probability density. For example, the values taken by a normalised wave function are amplitudes, since gives the probability density at position ....
    s at all sites, ).


The Einstein-Podolsky-Rosen paradox shows in any case that there exist experiments by which one can measure the state of one particle and instantaneously change the state of its entangled partner, although the two particles can be an arbitrary distance apart; however, this effect does not violate causality
Causality

Causality denotes a necessary relationship between one event and another event which is the direct consequence of the first.While this informal understanding suffices in everyday use, the Philosophy analysis of how best to characterize causality extends over millennia....
, since no transfer of information happens. These experiments are the basis of some of the most topical applications of the theory, quantum cryptography
Quantum cryptography

Quantum cryptography, or quantum key distribution , uses quantum mechanics to guarantee secure communication. It enables two parties to produce a shared random bit string known only to them, which can be used as a key to encrypt and decrypt messages....
, which works well, although at small distances of typically 1000 km, being on the market since 2004.

There do exist quantum theories which incorporate special relativity—for example, quantum electrodynamics
Quantum electrodynamics

Quantum electrodynamics is a relativity theory quantum field theory of electrodynamics. QED was developed by a number of physicists, beginning in the late 1920s....
 (QED), which is currently the most accurately tested physical theory —and these lie at the very heart of modern particle physics
Particle physics

Particle physics is a branch of physics that studies the elementary particle constituents of matter and radiation, and the interactions between them....
. Gravity is negligible in many areas of particle physics, so that unification between general relativity and quantum mechanics is not an urgent issue in those applications. However, the lack of a correct theory of quantum gravity
Quantum gravity

Quantum gravity is the field of theoretical physics attempting to unify quantum mechanics, which describes three of the Fundamental interaction , with general relativity, the theory of the fourth fundamental force: Gravitation....
 is an important issue in cosmology
Cosmology

Cosmology is study of the Universe in its totality, and by extension, humanity's place in it. Though the word cosmology is recent , study of the Universe has a long history involving science, philosophy, esotericism, and religion....
.

Attempts at a unified theory


Inconsistencies arise when one tries to join the quantum laws with general relativity
General relativity

General relativity or the general theory of relativity is the Geometry Theoretical physics of gravitation published by Albert Einstein in 1916....
, a more elaborate description of spacetime
Spacetime

In physics, spacetime is any mathematical model that combines space and Time in physics into a single continuum . Spacetime is usually interpreted with space being Three-dimensional space and time playing the role of a fourth dimension that is of a different sort than the spatial dimensions....
 which incorporates gravitation
Gravitation

Gravitation is a natural phenomenon that gives weight to objects. In everyday life, attraction due to gravity is the result of the presence of relatively large bodies, such as the Earth and the Moon....
. Resolving these inconsistencies has been a major goal of twentieth- and twenty-first-century physics. Many prominent physicists, including Stephen Hawking
Stephen Hawking

Stephen William Hawking Companion of Honour, Commander of the British Empire, Fellow of the Royal Society, Fellow of the Royal Society of Arts, Doctor of Philosophy is a British Theoretical physics....
, have labored in the attempt to discover a "Grand Unification Theory
Grand unification theory

Grand Unification, grand unified theory, or GUT refers to any of several very similar unified field theory or models in physics that predicts that at extremely high energies , the electromagnetic, weak nuclear, and strong nuclear forces are fused into a single unified field....
" that combines not only different models of subatomic physics, but also derives the universe's four forces—the strong force
Strong interaction

In particle physics, the strong interaction, or strong force, or color force, holds quarks and gluons together to form protons, neutrons and other particles....
, electromagnetism
Electromagnetism

Electromagnetism is the physics of the electromagnetic field, a field which exerts a force on Elementary particles with the property of electric charge and which is reciprocally affected by the presence and motion of such particles....
, weak force
Weak interaction

The weak interaction is one of the four fundamental interactions of nature. In the Standard Model of particle physics, it is due to the exchange of the heavy W and Z bosons....
, and gravity— from a single force or phenomenon.

Quantum mechanics and classical physics

Predictions of quantum mechanics have been verified experimentally to a very high degree of accuracy. Thus, the current logic of correspondence principle
Correspondence principle

In physics, the correspondence principle is a quantitative tool, applied in the old quantum theory as well as in Quantum mechanics, according to Jammer explicitly formulated by Niels Bohr for the first time in 1920, but used by him already in 1913 when developing the Bohr model of an atom....
 between classical and quantum mechanics is that all objects obey laws of quantum mechanics, and classical mechanics is just a quantum mechanics of large systems (or a statistical quantum mechanics of a large collection of particles). Laws of classical mechanics thus follow from laws of quantum mechanics at the limit of large systems or large quantum numbers.

Main differences between classical and quantum theories have already been mentioned above in the remarks on the Einstein-Podolsky-Rosen paradox
EPR paradox

In quantum mechanics, the EPR paradox is a thought experiment which challenged long-held ideas about the relation between the observed values of physical quantities and the values that can be accounted for by a physical theory....
. Essentially the difference boils down to the statement that quantum mechanics is coherent (addition of amplitude
Probability amplitude

In quantum mechanics, a probability amplitude is a complex number whose Absolute value squared represents a probability or probability density. For example, the values taken by a normalised wave function are amplitudes, since gives the probability density at position ....
s
), whereas classical theories are incoherent (addition of intensities). Thus, such quantities as coherence lengths and coherence times come into play. For microscopic bodies the extension of the system is certainly much smaller than the coherence length; for macroscopic bodies one expects that it should be the other way round.

This is in accordance with the following observations:

Many “macroscopic” properties of “classic” systems are direct consequences of quantum behavior of its parts. For example, stability of bulk matter (which consists of atoms and molecule
Molecule

In chemistry, a molecule is defined as a sufficiently stable, electric charge neutral group of at least two atoms in a definite arrangement held together by very strong chemical bonds....
s which would quickly collapse under electric forces alone), rigidity of this matter, mechanical, thermal, chemical, optical and magnetic properties of this matter—they are all results of interaction of electric charge
Electric charge

Electric charge is a fundamental conserved property of some subatomic particles, which determines their electromagnetic interaction. Electrically charged matter is influenced by, and produces, electromagnetic fields....
s under the rules of quantum mechanics.

While the seemingly exotic behavior of matter posited by quantum mechanics and relativity theory become more apparent when dealing with extremely fast-moving or extremely tiny particles, the laws of classical “Newtonian” physics still remain accurate in predicting the behavior of surrounding (“large”) objects—of the order of the size of large molecules and bigger—at velocities much smaller than the velocity of light.

Theory

There are numerous mathematically equivalent formulations of quantum mechanics. One of the oldest and most commonly used formulations is the transformation theory
Transformation theory (quantum mechanics)

The term transformation theory refers to a procedure used by Paul Adrien Maurice Dirac in his early formulation of Quantum mechanics, from around 1927....
 proposed by Cambridge theoretical physicist Paul Dirac
Paul Dirac

Paul Adrien Maurice Dirac, Order of Merit , Royal Society was a United Kingdom theoretical physicist. Dirac made fundamental contributions to the early development of both quantum mechanics and quantum electrodynamics....
, which unifies and generalizes the two earliest formulations of quantum mechanics, matrix mechanics
Matrix mechanics

Matrix mechanics is a formulation of quantum mechanics created by Werner Heisenberg, Max Born, and Pascual Jordan in 1925.Matrix mechanics was the first complete and correct definition of quantum mechanics....
 (invented by Werner Heisenberg
Werner Heisenberg

Werner Heisenberg was a German Theoretical physics who made foundational contributions to quantum mechanics and is best known for asserting the uncertainty principle of quantum theory....
) and wave mechanics (invented by Erwin Schrödinger
Erwin Schrödinger

Erwin Rudolf Josef Alexander Schr?dinger was an Austrian theoretical physicist who achieved fame for his contributions to quantum mechanics, especially the Schr?dinger equation, for which he received the Nobel Prize in 1933....
).

In this formulation, the instantaneous state of a quantum system
Quantum state

In quantum physics, a quantum State is a mathematical object that fully describes a Quantum system. One typically imagines some experimental apparatus and procedure which "prepares" this quantum state; the mathematical object then reflects the setup of the apparatus....
 encodes the probabilities of its measurable properties, or "observable
Observable

In physics, particularly in quantum physics, a system observable is a property of the State that can be determined by some sequence of physical operational definition....
s". Examples of observables include energy
Energy

In physics, energy is a scalar physical quantity that describes the amount of Work_ that can be performed by a force. Energy is an attribute of objects and systems that is subject to a conservation law....
, position
Position operator

In quantum mechanics, the position operator corresponds to the position observable of a particle. Consider, for example, the case of a spinless particle moving on a line....
, momentum
Momentum operator

In quantum mechanics, momentum is defined as an operator on the wave function. The Werner Heisenberg uncertainty principle defines limits on how accurately the momentum and position of a single observable system can be known at once....
, and angular momentum
Angular momentum

In physics, the angular momentum of a particle about an origin is a vector quantity related to rotation, equal to the mass of the particle multiplied by the cross product of the position vector of the particle with its velocity vector....
. Observables can be either continuous
Continuous function

In mathematics, a continuous function is a function for which, intuitively, small changes in the input result in small changes in the output. Otherwise, a function is said to be discontinuous....
 (e.g., the position of a particle) or discrete
Discrete mathematics

Discrete mathematics, also called finite mathematics, is the study of mathematical structures that are fundamentally discrete in the sense that its objects can assume only distinct, separate values, rather than a values on a continuum ....
 (e.g., the energy of an electron bound to a hydrogen atom).

Generally, quantum mechanics does not assign definite values to observables. Instead, it makes predictions about probability distribution
Probability distribution

In probability theory and statistics, a probability distribution identifies either the probability of each value of an unidentified random variable , or the probability of the value falling within a particular interval ....
s; that is, the probability of obtaining each of the possible outcomes from measuring an observable. Oftentimes these results are skewed by many causes, such as dense probability clouds or quantum state nuclear attraction. Much of the time, these small anomalies are attributed to different causes such as quantum dislocation
Quantum dislocation

Quantum dislocation is when an atom or an object being measured on the quantum level is slightly affected by any atomic or quantum causes and thus skews the result of any measurement....
. Naturally, these probabilities will depend on the quantum state at the instant of the measurement. When the probability amplitudes of four or more quantum nodes are similar, it is called a quantum parallelism. There are, however, certain states that are associated with a definite value of a particular observable. These are known as "eigenstates" of the observable ("eigen" can be roughly translated from German
German language

German is a West Germanic languages, thus related to and classified alongside English language and Dutch language. It is one of the world's world language and the most widely spoken mother tongue in the European Union....
 as inherent or as a characteristic). In the everyday world, it is natural and intuitive to think of everything being in an eigenstate of every observable. Everything appears to have a definite position, a definite momentum, and a definite time of occurrence. However, quantum mechanics does not pinpoint the exact values for the position or momentum of a certain particle in a given space in a finite time; rather, it only provides a range of probabilities of where that particle might be. Therefore, it became necessary to use different words for (a) the state of something having an uncertainty relation and (b) a state that has a definite value. The latter is called the "eigenstate" of the property being measured.

For example, consider a free particle
Free particle

In physics, a free particle is a particle that, in some sense, is not bound. In classical physics, this means the particle is present in a "field-free" space....
. In quantum mechanics, there is wave-particle duality so the properties of the particle can be described as a wave. Therefore, its quantum state
Quantum state

In quantum physics, a quantum State is a mathematical object that fully describes a Quantum system. One typically imagines some experimental apparatus and procedure which "prepares" this quantum state; the mathematical object then reflects the setup of the apparatus....
 can be represented as a wave
Wave

A wave is a disturbance that propagates through space and time, usually with transference of energy. While a mechanical wave exists in a medium , waves of electromagnetic radiation can travel through vacuum, that is, without a medium....
, of arbitrary shape and extending over all of space, called a wave function. The position and momentum of the particle are observables. The Uncertainty Principle
Uncertainty principle

In quantum physics, the Werner Heisenberg uncertainty principle states that certain physical quantities, like the position and momentum, cannot both have precise values at the same time....
 of quantum mechanics states that both the position and the momentum cannot simultaneously be known with infinite precision at the same time. However, one can measure just the position alone of a moving free particle creating an eigenstate of position with a wavefunction that is very large
Dirac delta function

The Dirac delta or Dirac's delta is a mathematics construct introduced by theoretical physicist Paul Dirac. Informally, it is a function representing an infinitely sharp peak bounding unit area: a function d that has the value 0 everywhere except at x = 0 where its value is infinity in such a way that its total integral is 1....
 at a particular position x, and almost zero everywhere else. If one performs a position measurement on such a wavefunction, the result x will be obtained with almost 100% probability. In other words, the position of the free particle will almost be known. This is called an eigenstate of position (mathematically more precise: a generalized eigenstate (eigendistribution
Distribution (mathematics)

In mathematical analysis, distributions are objects which generalize function s. They extend the concept of derivative to all locally integrable functions and beyond, and are used to formulate generalized solutions of partial differential equations....
)
). If the particle is in an eigenstate of position then its momentum is completely unknown. An eigenstate of momentum, on the other hand, has the form of a plane wave
Plane wave

In the physics of wave propagation, a plane wave is a constant-frequency wave whose wavefronts are infinite parallel planes of constant amplitude normal to the phase velocity vector....
. It can be shown that the wavelength
Wavelength

In physics, wavelength is the distance between repeating units of a propagating wave of a given frequency. It is commonly designated by the Greek language letter lambda ....
 is equal to h/p, where h is Planck's constant and p is the momentum of the eigenstate. If the particle is in an eigenstate of momentum then its position is completely blurred out.

Usually, a system will not be in an eigenstate of whatever observable we are interested in. However, if one measures the observable, the wavefunction will instantaneously be an eigenstate (or generalized eigenstate) of that observable. This process is known as wavefunction collapse
Wavefunction collapse

In quantum mechanics, wave function collapse is the process by which a wave function, initially in a Quantum superposition of different eigenstates, appears to reduce to a single one of the states after interaction with the external world....
. It involves expanding the system under study to include the measurement device, so that a detailed quantum calculation would no longer be feasible and a classical description must be used. If one knows the corresponding wave function at the instant before the measurement, one will be able to compute the probability of collapsing into each of the possible eigenstates. For example, the free particle in the previous example will usually have a wavefunction that is a wave packet
Wave packet

In physics, a wave packet is an envelope or packet containing a number of plane waves having different wavenumbers or wavelengths, chosen such that their phases and amplitudes interfere constructively over a small region of space....
 centered around some mean position x0, neither an eigenstate of position nor of momentum. When one measures the position of the particle, it is impossible to predict with certainty the result that we will obtain. It is probable, but not certain, that it will be near x0, where the amplitude of the wave function is large. After the measurement is performed, having obtained some result x, the wave function collapses into a position eigenstate centered at x.

Wave functions can change as time progresses. An equation known as the Schrödinger equation
Schrödinger equation

In physics, especially quantum mechanics, the Schr?dinger equation is an equation that describes how the quantum state of a physical system changes in time....
 describes how wave functions change in time, a role similar to Newton's second law in classical mechanics. The Schrödinger equation, applied to the aforementioned example of the free particle, predicts that the center of a wave packet will move through space at a constant velocity, like a classical particle with no forces acting on it. However, the wave packet will also spread out as time progresses, which means that the position becomes more uncertain. This also has the effect of turning position eigenstates (which can be thought of as infinitely sharp wave packets) into broadened wave packets that are no longer position eigenstates.

Some wave functions produce probability distributions that are constant in time. Many systems that are treated dynamically in classical mechanics are described by such "static" wave functions. For example, a single electron
Electron

The electron is a subatomic particle that carries a negative electric charge. It has elementary particle and is believed to be a point particle....
 in an unexcited atom
Atom

|-! bgcolor=gray | Properties|-||}The atom is a basic unit of matter consisting of a dense, central atomic nucleus surrounded by a electron cloud of electric charge electrons....
 is pictured classically as a particle moving in a circular trajectory around the atomic nucleus
Atomic nucleus

The nucleus of an atom is the very dense region, consisting of nucleons , at the center of an atom. Although the size of the nucleus varies considerably according to the mass of the atom, the size of the entire atom is comparatively constant....
, whereas in quantum mechanics it is described by a static, spherically symmetric
Spherical coordinate system

In mathematics, the spherical coordinate system is a coordinate system for representing geometric figures in three dimensions using three coordinates: the radial distance of a point from a fixed origin, the zenith angle from the positive z-axis to the point, and the azimuth angle from the positive x-axis to the orthogonal projection of the...
 wavefunction surrounding the nucleus (Fig. 1). (Note that only the lowest angular momentum states, labeled s, are spherically symmetric).

The time evolution of wave functions is deterministic
Determinism

Determinism is the philosophy proposition that every event, including human cognition and behavior, decision and action, is causality determined by an unbroken chain of prior occurrences. With numerous historical debates, many varieties and philosophical positions on the subject of determinism exist from traditions throughout...
 in the sense that, given a wavefunction at an initial time, it makes a definite prediction of what the wavefunction will be at any later time. During a measurement, the change of the wavefunction into another one is not deterministic, but rather unpredictable, i.e., random.

The probabilistic
Probability

Probability, or wikt:chance, is a way of expressing knowledge or belief that an Event will occur or has occurred. In mathematics the concept has been given an exact meaning in probability theory, that is used extensively in such areas of study as mathematics, statistics, finance, gambling, science, and philosophy to draw conclusions about t...
 nature of quantum mechanics thus stems from the act of measurement. This is one of the most difficult aspects of quantum systems to understand. It was the central topic in the famous Bohr-Einstein debates
Bohr-Einstein debates

The Bohr?Einstein debates is a popular name given to what was actually a series of epistemology challenges presented by Albert Einstein against what has come to be called the standard or Copenhagen interpretation of quantum mechanics....
, in which the two scientists attempted to clarify these fundamental principles by way of thought experiments. In the decades after the formulation of quantum mechanics, the question of what constitutes a "measurement" has been extensively studied. Interpretations
Interpretation of quantum mechanics

An interpretation of quantum mechanics is a statement which attempts to explain how quantum mechanics informs our understanding of nature. Although quantum mechanics has received thorough experimental testing, many of these experiments are open to different interpretations....
 of quantum mechanics have been formulated to do away with the concept of "wavefunction collapse"; see, for example, the relative state interpretation. The basic idea is that when a quantum system interacts with a measuring apparatus, their respective wavefunctions become entangled, so that the original quantum system ceases to exist as an independent entity. For details, see the article on measurement in quantum mechanics
Measurement in quantum mechanics

The framework of quantum mechanics requires a careful definition of measurement, and a thorough discussion of its practical and philosophical implications....
.

Mathematical formulation


In the mathematically rigorous formulation of quantum mechanics, developed by Paul Dirac
Paul Dirac

Paul Adrien Maurice Dirac, Order of Merit , Royal Society was a United Kingdom theoretical physicist. Dirac made fundamental contributions to the early development of both quantum mechanics and quantum electrodynamics....
 and John von Neumann
John von Neumann

John von Neumann was a Hungarian American mathematician who made major contributions to a vast range of fields, including set theory, functional analysis, quantum mechanics, ergodic theory, continuous geometry, economics and game theory, computer science, numerical analysis, hydrodynamics , and statistics, as well as many other mathematical...
, the possible states of a quantum mechanical system are represented by unit vectors (called "state vectors") residing in a complex
Complex number

In mathematics, the complex numbers are an extension of the real numbers obtained by adjoining an imaginary unit, denoted i, which satisfies:...
 separable
Separable space

In mathematics a topological space is called separable if it contains a countable set dense subset; that is, there exists a sequence of elements of the space such that every nonempty open subset of the space contains at least one element of the sequence....
 Hilbert space
Hilbert space

The mathematics concept of a Hilbert space, named after David Hilbert, generalizes the notion of Euclidean space. It extends the methods of vector algebra from the two-dimensional plane and three-dimensional space to infinite-dimensional spaces....
 (variously called the "state space" or the "associated Hilbert space" of the system) well defined up to a complex number of norm 1 (the phase factor). In other words, the possible states are points in the projectivization
Projective space

In mathematics a projective space is a set of elements similar to the set P of lines through the origin of a vector space V. The cases when V=R2 or V=R3 are the projective line and the projective plane, respectively....
 of a Hilbert space, usually called the complex projective space
Complex projective space

In mathematics, complex projective space, P, Pn or CPn, in fact preferablyis the projective space of line in Cn+1....
. The exact nature of this Hilbert space is dependent on the system; for example, the state space for position and momentum states is the space of square-integrable functions, while the state space for the spin of a single proton is just the product of two complex planes. Each observable is represented by a maximally-Hermitian
Hermitian

A number of mathematical entities are named Hermitian, after the mathematician Charles Hermite:*Hermitian adjoint*Hermitian connection*Sesquilinear form...
 (precisely: by a self-adjoint
Self-adjoint operator

In mathematics, on a finite-dimensional inner product space, a self-adjoint operator is one that is its own Adjoint of an operator, or, equivalently, one whose matrix is Hermitian matrix, where a Hermitian matrix is one which is equal to its own conjugate transpose....
) linear operator
Operator

In mathematics, an operator is a function which operates on another function. Often, an "operator" is a function which acts on functions to produce other functions ; or it may be a generalization of such a function, as in linear algebra, where some of the terminology reflects the origin of the subject in operations on the functions which ar...
 acting on the state space. Each eigenstate of an observable corresponds to an eigenvector of the operator, and the associated eigenvalue corresponds to the value of the observable in that eigenstate. If the operator's spectrum is discrete, the observable can only attain those discrete eigenvalues.

The time evolution of a quantum state is described by the Schrödinger equation
Schrödinger equation

In physics, especially quantum mechanics, the Schr?dinger equation is an equation that describes how the quantum state of a physical system changes in time....
, in which the Hamiltonian
Hamiltonian (quantum mechanics)

In quantum mechanics, the Hamiltonian H is the observable corresponding to the total energy of the system. As with all observables, the Spectrum of the Hamiltonian is the set of possible outcomes when one measures the total energy of a system....
, the operator
Operator (physics)

In physics, an operator is a Function acting on the space of physical states. As a resultof its application on a physical state, another physical state is obtained, very often along with...
 corresponding to the total energy of the system, generates time evolution.

The inner product between two state vectors is a complex number known as a probability amplitude
Probability amplitude

In quantum mechanics, a probability amplitude is a complex number whose Absolute value squared represents a probability or probability density. For example, the values taken by a normalised wave function are amplitudes, since gives the probability density at position ....
. During a measurement, the probability that a system collapses from a given initial state to a particular eigenstate is given by the square of the absolute value
Absolute value

In mathematics, the absolute value of a real number is its numerical value without regard to its Negative and non-negative numbers. So, for example, 3 is the absolute value of both 3 and -3....
 of the probability amplitudes between the initial and final states. The possible results of a measurement are the eigenvalues of the operator - which explains the choice of Hermitian operators, for which all the eigenvalues are real. We can find the probability distribution of an observable in a given state by computing the spectral decomposition
Spectral theorem

In mathematics, particularly linear algebra and functional analysis, the spectral theorem is any of a number of results about linear operators or about matrix_....
 of the corresponding operator. Heisenberg's uncertainty principle
Uncertainty principle

In quantum physics, the Werner Heisenberg uncertainty principle states that certain physical quantities, like the position and momentum, cannot both have precise values at the same time....
 is represented by the statement that the operators corresponding to certain observables do not commute
Commutator

In mathematics, the commutator gives an indication of the extent to which a certain binary operation fails to be commutative. There are different definitions used in group theory and ring theory....
.

The Schrödinger equation acts on the entire probability amplitude, not merely its absolute value. Whereas the absolute value of the probability amplitude encodes information about probabilities, its phase
Phase (waves)

The phase of an oscillation or wave is the fraction of a complete cycle corresponding to an offset in the displacement from a specified reference point at time t = 0....
 encodes information about the interference
Interference

In physics, interference is the addition of two or more waves that result in a new wave pattern.Interference usually refers to the interaction of waves which are correlated or Coherence with each other, either because they come from the same source or because they have the same or nearly the same frequency....
 between quantum states. This gives rise to the wave-like behavior of quantum states.

It turns out that analytic solutions of Schrödinger's equation are only available for a small number of model Hamiltonians
List of quantum mechanical systems with analytical solutions

Much insight in quantum mechanics can be gained from understanding the solutions to the time-dependent non-relativistic Schr?dinger equation in an appropriate configuration space....
, of which the quantum harmonic oscillator
Quantum harmonic oscillator

The quantum harmonic oscillator is the quantum mechanics analogue of the harmonic oscillator. It is one of the most important model systems in quantum mechanics because an arbitrary potential can be approximated as a harmonic potential at the vicinity of a stable equilibrium point....
, the particle in a box
Particle in a box

In physics, the particle in a box is a problem consisting of a single particle inside of an infinitely deep potential well, from which it cannot escape, and which loses no energy when it collides with the walls of the box....
, the hydrogen molecular ion
Hydrogen molecular ion

The hydrogen molecular ion, dihydrogen cation, or H2+, is the simplest molecular ion. It is composed of two positively-charged protons and one negatively-charged electron, and can be formed from ionization of a neutral hydrogen molecule....
 and the hydrogen atom
Hydrogen atom

A hydrogen atom is an atom of the chemical element hydrogen. The Electric charge neutral atom contains a single positively-charged proton and a single negatively-charged electron bound to the nucleus by the Coulomb force....
 are the most important representatives. Even the helium
Helium

Helium is a colorless, odorless, tasteless, non-toxic, inert monatomic chemical element that heads the noble gas group in the periodic table and whose atomic number is 2....
 atom, which contains just one more electron than hydrogen, defies all attempts at a fully analytic treatment. There exist several techniques for generating approximate solutions. For instance, in the method known as perturbation theory
Perturbation theory (quantum mechanics)

In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation theory for describing a complicated quantum system in terms of a simpler one....
 one uses the analytic results for a simple quantum mechanical model to generate results for a more complicated model related to the simple model by, for example, the addition of a weak potential energy
Potential energy

Potential energy can be thought of as energy stored within a physical system. It is called potential energy because it has the potential to be converted into other forms of energy, such as kinetic energy, and to do Mechanical work in the process....
. Another method is the "semi-classical equation of motion" approach, which applies to systems for which quantum mechanics produces weak deviations from classical behavior. The deviations can be calculated based on the classical motion. This approach is important for the field of quantum chaos
Quantum chaos

Quantum chaos is a branch of physics which studies how chaotic classical systems can be shown to be limits of quantum-mechanical systems.The phenomena covered by quantum chaos so far are mainly related to wave theory....
.

An alternative formulation of quantum mechanics is Feynman
Feynman

Feynman may refer to:* Richard Feynman** Feynman diagram** Feynman graph** Feynman-Kac formula** The Feynman Lectures on Physics** Feynman integral, see Path integral formulation...
's path integral formulation
Path integral formulation

The path integral formulation of quantum mechanics is a description of quantum theory which generalizes the action of classical mechanics. It replaces the classical notion of a single, unique trajectory for a system with a sum, or functional integral, over an infinity of possible trajectories to compute a probability amplitude....
, in which a quantum-mechanical amplitude is considered as a sum over histories between initial and final states; this is the quantum-mechanical counterpart of action principles in classical mechanics.

Interactions with other scientific theories

The fundamental rules of quantum mechanics are very broad. They assert that the state space of a system is a Hilbert space
Hilbert space

The mathematics concept of a Hilbert space, named after David Hilbert, generalizes the notion of Euclidean space. It extends the methods of vector algebra from the two-dimensional plane and three-dimensional space to infinite-dimensional spaces....
 and the observables are Hermitian operators acting on that space, but do not tell us which Hilbert space or which operators, or if it even exists. These must be chosen appropriately in order to obtain a quantitative description of a quantum system. An important guide for making these choices is the correspondence principle
Correspondence principle

In physics, the correspondence principle is a quantitative tool, applied in the old quantum theory as well as in Quantum mechanics, according to Jammer explicitly formulated by Niels Bohr for the first time in 1920, but used by him already in 1913 when developing the Bohr model of an atom....
, which states that the predictions of quantum mechanics reduce to those of classical physics when a system moves to higher energies or equivalently, larger quantum numbers. In other words, classic mechanics is simply a quantum mechanics of large systems. This "high energy" limit is known as the classical or correspondence limit. One can therefore start from an established classical model of a particular system, and attempt to guess the underlying quantum model that gives rise to the classical model in the correspondence limit.

When quantum mechanics was originally formulated, it was applied to models whose correspondence limit was non-relativistic
Theory of relativity

File:spacetime curvature.pngThe theory of relativity, or simply relativity, generally refers specifically to two theories of Albert Einstein: special relativity and general relativity....
 classical mechanics
Classical mechanics

Classical mechanics is used for describing the motion of macroscopic objects, from projectiles to parts of machinery, as well as astronomical objects, such as spacecraft, planets, stars, and galaxies....
. For instance, the well-known model of the quantum harmonic oscillator
Quantum harmonic oscillator

The quantum harmonic oscillator is the quantum mechanics analogue of the harmonic oscillator. It is one of the most important model systems in quantum mechanics because an arbitrary potential can be approximated as a harmonic potential at the vicinity of a stable equilibrium point....
 uses an explicitly non-relativistic expression for the kinetic energy
Kinetic energy

The kinetic energy of an object is the extra energy which it possesses due to its motion. It is defined as the mechanical work needed to accelerate a body of a given mass from rest to its current velocity....
 of the oscillator, and is thus a quantum version of the classical harmonic oscillator
Harmonic oscillator

In classical mechanics, a harmonic oscillator is a system which, when displaced from its equilibrium position, experiences a restoring force proportional to the displacement according to Hooke's law:...
.

Early attempts to merge quantum mechanics with special relativity
Special relativity

Special relativity is the physical theory of measurement in inertial frames of reference proposed in 1905 by Albert Einstein in the paper "Annus Mirabilis Papers#Special relativity"....
 involved the replacement of the Schrödinger equation with a covariant equation such as the Klein-Gordon equation
Klein-Gordon equation

The Klein?Gordon equation is a special relativity version of the Schr?dinger equation.It is the equation of motion of a quantum field theory, a field whose quanta are spinless particles....
 or the Dirac equation
Dirac equation

In physics, the Dirac equation is a theory of relativity quantum mechanics wave equation formulated by British physicist Paul Dirac in 1928 and provides a description of elementary particle spin-? particles, such as electrons, consistent with both the principles of quantum mechanics and the theory of special relativity....
. While these theories were successful in explaining many experimental results, they had certain unsatisfactory qualities stemming from their neglect of the relativistic creation and annihilation of particles. A fully relativistic quantum theory required the development of quantum field theory
Quantum field theory

Quantum field theory or QFT provides a theoretical framework for constructing quantum mechanics models of systems classically described by field or of Many-body problem....
, which applies quantization to a field rather than a fixed set of particles. The first complete quantum field theory, quantum electrodynamics
Quantum electrodynamics

Quantum electrodynamics is a relativity theory quantum field theory of electrodynamics. QED was developed by a number of physicists, beginning in the late 1920s....
, provides a fully quantum description of the electromagnetic interaction
Electromagnetism

Electromagnetism is the physics of the electromagnetic field, a field which exerts a force on Elementary particles with the property of electric charge and which is reciprocally affected by the presence and motion of such particles....
.

The full apparatus of quantum field theory is often unnecessary for describing electrodynamic systems. A simpler approach, one employed since the inception of quantum mechanics, is to treat charged
Electric charge

Electric charge is a fundamental conserved property of some subatomic particles, which determines their electromagnetic interaction. Electrically charged matter is influenced by, and produces, electromagnetic fields....
 particles as quantum mechanical objects being acted on by a classical electromagnetic field. For example, the elementary quantum model of the hydrogen atom
Hydrogen atom

A hydrogen atom is an atom of the chemical element hydrogen. The Electric charge neutral atom contains a single positively-charged proton and a single negatively-charged electron bound to the nucleus by the Coulomb force....
 describes the electric field of the hydrogen atom using a classical Coulomb potential. This "semi-classical" approach fails if quantum fluctuations in the electromagnetic field play an important role, such as in the emission of photon
Photon

In physics, the photon is an elementary particle, the quantum of the electromagnetic field and the basic unit of light and all other forms of electromagnetic radiation....
s by charged particles.

Quantum field theories for the strong nuclear force and the weak nuclear force have been developed. The quantum field theory of the strong nuclear force is called quantum chromodynamics
Quantum chromodynamics

Quantum chromodynamics is a theory of the strong interaction , a fundamental force describing the interactions of the quarks and gluons making up hadrons ....
, and describes the interactions of the subnuclear particles: quark
Quark

Quarks are a type of elementary particle and major constituents of matter. They are the only particles in the Standard Model to experience all four fundamental interaction, which are also known as fundamental interactions....
s and gluon
Gluon

Gluons are elementary particles that cause quarks to interact, and are indirectly responsible for the binding of protons and neutrons together in atomic nuclei....
s. The weak nuclear force and the electromagnetic force were unified, in their quantized forms, into a single quantum field theory known as electroweak theory, by the physicists Abdus Salam
Abdus Salam

Abdus Salam was a Demographics of Pakistan theoretical physicist, Astrophysicist and Nobel laureate in Physics for his work in electroweak theory....
, Sheldon Glashow and Steven Weinberg
Steven Weinberg

Steven Weinberg is an United States physicist and Nobel Prize in Physics for his contributions with Abdus Salam and Sheldon Lee Glashow to the Electroweak interaction of the weak force and electromagnetism interaction between elementary particles....
.

It has proven difficult to construct quantum models of gravity, the remaining fundamental force. Semi-classical approximations are workable, and have led to predictions such as Hawking radiation
Hawking radiation

Hawking radiation is a thermal radiation with a black body predicted to be emitted by black holes due to quantum physics effects. It is named after the physicist Stephen Hawking who provided the theoretical argument for its existence in 1974, and sometimes also after the physicist Jacob Bekenstein who predicted that black holes should have a...
. However, the formulation of a complete theory of quantum gravity
Quantum gravity

Quantum gravity is the field of theoretical physics attempting to unify quantum mechanics, which describes three of the Fundamental interaction , with general relativity, the theory of the fourth fundamental force: Gravitation....
 is hindered by apparent incompatibilities between general relativity
General relativity

General relativity or the general theory of relativity is the Geometry Theoretical physics of gravitation published by Albert Einstein in 1916....
, the most accurate theory of gravity currently known, and some of the fundamental assumptions of quantum theory. The resolution of these incompatibilities is an area of active research, and theories such as string theory
String theory

String theory is a developing branch of theoretical physics that combines quantum mechanics and general relativity into a quantum gravity. The String s of string theory are one-dimensional oscillating lines, but they are no longer considered fundamental to the theory, which can be formulated in terms of points or surfaces too....
 are among the possible candidates for a future theory of quantum gravity.

Example

The particle in a 1-dimensional potential energy box is the most simple example where restraints lead to the quantization of energy levels. The box is defined as zero potential energy inside a certain interval and infinite everywhere outside that interval. For the 1-dimensional case in the direction, the time-independent Schrödinger equation can be written as:



The general solutions are:
or
(by Euler's formula
Euler's formula

Euler's formula, named after Leonhard Euler, is a mathematics formula in complex analysis that shows a deep relationship between the trigonometric functions and the complex exponential function....
)


The presence of the walls of the box restricts the acceptable solutions of the wavefunction. At each wall:



Consider x = 0
  • sin 0 = 0, cos 0 = 1. To satisfy the cos term has to be removed. Hence D = 0


Now consider:
  • at x = L,
  • If C = 0 then for all x. This would conflict with the Born interpretation
  • therefore sin kL = 0 must be satisfied, yielding the condition




In this situation, n must be an integer showing the quantization of the energy levels.

Applications

Quantum mechanics has had enormous success in explaining many of the features of our world. The individual behaviour of the subatomic particles that make up all forms of matter
Matter

In common usage, matter is anything that has both mass and volume . A more rigorous definition is used in science: matter is what atoms and molecules are made of....
electron
Electron

The electron is a subatomic particle that carries a negative electric charge. It has elementary particle and is believed to be a point particle....
s, proton
Proton

The proton is a subatomic particle with an electric charge of +1 elementary charge. It is found in the nucleus of each atom but is also stable by itself and has a second identity as the hydrogen ion, H+....
s, neutron
Neutron

The neutron is a subatomic particle with no net electric charge and a mass slightly larger than that of a proton.Neutrons are usually found in atomic nucleus....
s, photon
Photon

In physics, the photon is an elementary particle, the quantum of the electromagnetic field and the basic unit of light and all other forms of electromagnetic radiation....
s and others—can often only be satisfactorily described using quantum mechanics. Quantum mechanics has strongly influenced string theory
String theory

String theory is a developing branch of theoretical physics that combines quantum mechanics and general relativity into a quantum gravity. The String s of string theory are one-dimensional oscillating lines, but they are no longer considered fundamental to the theory, which can be formulated in terms of points or surfaces too....
, a candidate for a theory of everything
Theory of everything

The theory of everything is a putative theory of theoretical physics that fully explains and links together all known physical phenomena. Initially, the term was used with an ironic connotation to refer to various overgeneralized theories....
 (see reductionism
Reductionism

Reductionism can either mean an approach to understanding the nature of complex things by reducing them to the interactions of their parts, or to simpler or more fundamental things or a philosophical position that a complex system is nothing but the sum of its parts, and that an account of it can be reduced to accounts of individual consti...
) and the multiverse
Multiverse

The multiverse is the hypothetical set of multiple possible universes that together comprise all of reality.Multiverse may also refer to:...
 hypothesis. It is also related to statistical mechanics
Statistical mechanics

Statistical mechanics is the application of probability theory, which includes Mathematics tools for dealing with large populations, to the field of mechanics, which is concerned with the motion of particles or objects when subjected to a force....
.

Quantum mechanics is important for understanding how individual atoms combine covalently to form chemicals or molecules. The application of quantum mechanics to chemistry
Chemistry

Chemistry is the science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions....
 is known as quantum chemistry
Quantum chemistry

Quantum chemistry is a branch of theoretical chemistry, which applies quantum mechanics and quantum field theory to address issues and problems in chemistry....
. (Relativistic) quantum mechanics can in principle mathematically describe most of chemistry. Quantum mechanics can provide quantitative insight into ionic and covalent bonding processes by explicitly showing which molecules are energetically favorable to which others, and by approximately how much. Most of the calculations performed in computational chemistry
Computational chemistry

Computational chemistry is a branch of chemistry that uses computers to assist in solving chemical problems. It uses the results of theoretical chemistry, incorporated into efficient computer programs, to calculate the structures and properties of molecules and solids....
 rely on quantum mechanics.

Much of modern technology
Technology

Technology is a broad concept that deals with an animal species' usage and knowledge of tools and crafts, and how it affects an animal species' ability to control and adapt to its Natural environment....
 operates at a scale where quantum effects are significant. Examples include the laser
Laser

A laser is a device that emits light through a process called stimulated emission. The term laser is an acronym for light amplification by stimulated emission of radiation....
, the transistor
Transistor

In electronics, a transistor is a semiconductor device commonly used to Electronic amplifier or switch Electronics signals. A transistor is made of a solid piece of a semiconductor material, with at least three terminals for connection to an external circuit....
, the electron microscope
Electron microscope

An electron microscope is a type of microscope that uses a particle beam of electrons to illuminate a specimen and create a highly-magnified image....
, and magnetic resonance imaging
Magnetic resonance imaging

GaneshMagnetic resonance imaging , or nuclear magnetic resonance imaging , is primarily a medical imaging technique most commonly used in radiology to visualize the structure and function of the body....
. The study of semiconductors led to the invention of the diode
Diode

In electronics, a diode is a two-terminal device .Diodes have two active electrodes between which the signal of interest may flow, and most are used for their unidirectional electric current property....
 and the transistor
Transistor

In electronics, a transistor is a semiconductor device commonly used to Electronic amplifier or switch Electronics signals. A transistor is made of a solid piece of a semiconductor material, with at least three terminals for connection to an external circuit....
, which are indispensable for modern electronics
Electronics

Electronics refers to the flow of charge through nonmetal electrical conductor , whereas electrical refers to the flow of charge through metal electrical conductor....
.

Researchers are currently seeking robust methods of directly manipulating quantum states. Efforts are being made to develop quantum cryptography
Quantum cryptography

Quantum cryptography, or quantum key distribution , uses quantum mechanics to guarantee secure communication. It enables two parties to produce a shared random bit string known only to them, which can be used as a key to encrypt and decrypt messages....
, which will allow guaranteed secure transmission of information
Information

Information as a Conveyed concept has a diversity of meanings, from everyday usage to technical settings. Generally speaking, the concept of information is closely related to notions of constraint, communication, control system, data, form, instruction, knowledge, Meaning , stimulation, pattern, perception, and knowledge representation....
. A more distant goal is the development of quantum computer
Quantum computer

A quantum computer is a device for computation that makes direct use of quantum mechanical phenomena, such as quantum superposition and quantum entanglement, to perform operations on data....
s, which are expected to perform certain computational tasks exponentially faster than classical computer
Computer

A computer is a machine that manipulates Data according to a list of Code .The first devices that resemble modern computers date to the mid-20th century , although the computer concept and various machines similar to computers existed earlier....
s. Another active research topic is quantum teleportation
Quantum teleportation

Quantum teleportation, or entanglement-assisted teleportation, is a technique used to transfer Physical information on a quantum level, usually from one Elementary particle to another particle in another location via quantum entanglement....
, which deals with techniques to transmit quantum states over arbitrary distances.

In many devices, even the simple light switch
Light switch

A light switch is a switch, most commonly used to operate electric lights, permanently connected equipment, or electrical outlets.In modern homes most lights are operated using switches set in walls, usually 6-10 inches away from a door, to operate overhead ceiling lights....
, quantum tunneling is vital, as otherwise the electrons in the electric current could not penetrate the potential barrier made up, in the case of the light switch, of a layer of oxide. Flash memory
Flash memory

Flash memory is a non-volatile memory computer storage that can be electrically erased and reprogrammed. It is a technology that is primarily used in memory cards and USB flash drives for general storage and transfer of data between computers and other digital products....
 chips found in USB drives also use quantum tunneling to erase their memory cells.

Philosophical consequences


Since its inception, the many counter-intuitive results of quantum mechanics have provoked strong philosophical
Philosophy

Philosophy is the study of general problems concerning matters such as existence, knowledge, truth, beauty, justice, validity, mind, and language....
 debate and many interpretations. Even fundamental issues such as Max Born
Max Born

Max Born was a Germany physicist and mathematician who was instrumental in the development of quantum mechanics. He also made contributions to solid-state physics and optics and supervised the work of a number of notable physicists in the 1920s and 30s....
's basic rules
Born rule

The Born rule is a Physical law of quantum mechanics which gives the probability that a measurement on a quantum system will yield a given result....
 concerning probability amplitude
Probability amplitude

In quantum mechanics, a probability amplitude is a complex number whose Absolute value squared represents a probability or probability density. For example, the values taken by a normalised wave function are amplitudes, since gives the probability density at position ....
s and probability distribution
Probability distribution

In probability theory and statistics, a probability distribution identifies either the probability of each value of an unidentified random variable , or the probability of the value falling within a particular interval ....
s took decades to be appreciated.

The Copenhagen interpretation
Copenhagen interpretation

The Copenhagen interpretation is an Interpretations of quantum mechanics of quantum mechanics. A key feature of quantum mechanics is that the state of every Elementary particle is described by a wavefunction, which is a mathematical representation used to calculate the probability for it to be found in a location, or state of motion....
, due largely to the Danish theoretical physicist Niels Bohr
Niels Bohr

Niels Henrik David Bohr was a Denmark physicist who made fundamental contributions to understanding atomic structure and quantum mechanics, for which he received the Nobel Prize in Physics in 1922....
, is the interpretation of quantum mechanics most widely accepted amongst physicists. According to it, the probabilistic nature of quantum mechanics predictions cannot be explained in terms of some other deterministic theory, and does not simply reflect our limited knowledge. Quantum mechanics provides probabilistic results because the physical universe is itself probabilistic rather than deterministic
Determinism

Determinism is the philosophy proposition that every event, including human cognition and behavior, decision and action, is causality determined by an unbroken chain of prior occurrences. With numerous historical debates, many varieties and philosophical positions on the subject of determinism exist from traditions throughout...
.

Albert Einstein
Albert Einstein

Albert Einstein was a Germany-born theoretical physics. He is best known for his theory of relativity and specifically mass?energy equivalence, expressed by the equation E = mc2....
, himself one of the founders of quantum theory, disliked this loss of determinism in measurement
Bohr-Einstein debates

The Bohr?Einstein debates is a popular name given to what was actually a series of epistemology challenges presented by Albert Einstein against what has come to be called the standard or Copenhagen interpretation of quantum mechanics....
 (this dislike is the source of his famous quote, "God does not play dice with the universe."). Einstein held that there should be a local hidden variable theory
Local hidden variable theory

In quantum mechanics, a local hidden variable theory is one in which distant events are assumed to have no instantaneous effect on local ones....
 underlying quantum mechanics and that, consequently, the present theory was incomplete. He produced a series of objections to the theory, the most famous of which has become known as the EPR paradox
EPR paradox

In quantum mechanics, the EPR paradox is a thought experiment which challenged long-held ideas about the relation between the observed values of physical quantities and the values that can be accounted for by a physical theory....
. John Bell
John Stewart Bell

John Stewart Bell was a physicist, and the originator of Bell's Theorem, one of the most important theorems in quantum mechanics....
 showed that the EPR paradox led to experimentally testable differences
Bell's theorem

Bell's theorem is a theorem that shows that the predictions of quantum mechanics are counter intuitive, touching upon several fundamental philosophical issues related to modern physics....
 between quantum mechanics and local realistic theories. Experiments
Bell test experiments

The Bell test experiments serve to investigate the validity of the quantum entanglement effect in quantum mechanics by using some kind of Bell inequality....
 have been performed confirming the accuracy of quantum mechanics, thus demonstrating that the physical world cannot be described by local realistic theories.

The Bohr-Einstein debates
Bohr-Einstein debates

The Bohr?Einstein debates is a popular name given to what was actually a series of epistemology challenges presented by Albert Einstein against what has come to be called the standard or Copenhagen interpretation of quantum mechanics....
 provide a vibrant critique of the Copenhagen Interpretation from an epistemological point of view.

The Everett many-worlds interpretation, formulated in 1956, holds that all the possibilities described by quantum theory simultaneously occur in a "multiverse
Multiverse (science)

The multiverse is the hypothetical set of multiple possible universes that together comprise all of reality. The different universes within the multiverse are sometimes called parallel universes....
" composed of mostly independent parallel universes. This is not accomplished by introducing some new axiom to quantum mechanics, but on the contrary by removing the axiom of the collapse of the wave packet: All the possible consistent states of the measured system and the measuring apparatus (including the observer) are present in a real physical (not just formally mathematical, as in other interpretations) quantum superposition
Quantum superposition

Quantum superposition is the fundamental law of quantum mechanics. It defines the allowed state space of a quantum mechanical system.In Probability theory, every possible event has a non-negative real number between zero and one associated to it, the probability, which gives the chance that it happens....
. (Such a superposition of consistent state combinations of different systems is called an entangled state.) While the multiverse is deterministic, we perceive non-deterministic behavior governed by probabilities, because we can observe only the universe, i.e. the consistent state contribution to the mentioned superposition, we inhabit. Everett's interpretation is perfectly consistent with John Bell
John Stewart Bell

John Stewart Bell was a physicist, and the originator of Bell's Theorem, one of the most important theorems in quantum mechanics....
's experiments and makes them intuitively understandable. However, according to the theory of quantum decoherence
Quantum decoherence

In quantum mechanics, quantum decoherence is the mechanism by which quantum systems interact with their environments to exhibit probabilistically additive behavior....
, the parallel universes will never be accessible to us. This inaccessibility can be understood as follows: once a measurement is done, the measured system becomes entangled
Entanglement

Entanglement may refer to:* Quantum entanglement* Orientation entanglement* Wire entanglement* By-catch, the unintended capture of animals in fishing nets...
 with both the physicist who measured it and a huge number of other particles, some of which are photon
Photon

In physics, the photon is an elementary particle, the quantum of the electromagnetic field and the basic unit of light and all other forms of electromagnetic radiation....
s flying away towards the other end of the universe; in order to prove that the wave function did not collapse one would have to bring all these particles back and measure them again, together with the system that was measured originally. This is completely impractical, but even if one could theoretically do this, it would destroy any evidence that the original measurement took place (including the physicist's memory).

See also

  • Correspondence rules
    Correspondence rules

    In quantum mechanics, correspondence rules refers to the principle of replacing physical quantities with operators.Such replacements include energy and momentum, which can be derived informally from taking the time and space derivities of the plane wave function....
  • Interpretation of quantum mechanics
    Interpretation of quantum mechanics

    An interpretation of quantum mechanics is a statement which attempts to explain how quantum mechanics informs our understanding of nature. Although quantum mechanics has received thorough experimental testing, many of these experiments are open to different interpretations....
  • Copenhagen interpretation
    Copenhagen interpretation

    The Copenhagen interpretation is an Interpretations of quantum mechanics of quantum mechanics. A key feature of quantum mechanics is that the state of every Elementary particle is described by a wavefunction, which is a mathematical representation used to calculate the probability for it to be found in a location, or state of motion....
  • Schrödinger's cat
    Schrödinger's cat

    Schr?dinger's cat is a thought experiment, often described as a paradox, devised by Austrian physicist Erwin Schr?dinger in 1935. It illustrates what he saw as the problem of the Copenhagen interpretation of quantum mechanics being applied to everyday objects....
  • Introduction to quantum mechanics
    Introduction to quantum mechanics

    Quantum mechanics is a branch of physics dealing with the behavior of matter and energy on the minute scale of atoms and subatomic particles. Quantum mechanics is fundamental to our understanding of all of the fundamental forces of nature except gravity....
  • Many-worlds interpretation
    Many-worlds interpretation

    The many-worlds interpretation is an interpretation of quantum mechanics.It is also known as MWI, the relative state formulation, theory of the universal wavefunction, parallel universes, many-universes interpretation or just many worlds....
  • Measurement in quantum mechanics
    Measurement in quantum mechanics

    The framework of quantum mechanics requires a careful definition of measurement, and a thorough discussion of its practical and philosophical implications....
  • Photon dynamics in the double-slit experiment
    Photon dynamics in the double-slit experiment

    The dynamics of photons in the double-slit experiment describes the relationship between classical electromagnetic waves and photons, the quantum counterpart of classical electromagnetic waves, in the context of the double-slit experiment....
  • Photon polarization
    Photon polarization

    Photon polarization is the Quantum mechanics description of the Classical physics polarized sinusoidal plane wave electromagnetic wave. Individual photons are completely polarized....
  • Quantum chemistry
    Quantum chemistry

    Quantum chemistry is a branch of theoretical chemistry, which applies quantum mechanics and quantum field theory to address issues and problems in chemistry....
  • Quantum chromodynamics
    Quantum chromodynamics

    Quantum chromodynamics is a theory of the strong interaction , a fundamental force describing the interactions of the quarks and gluons making up hadrons ....
  • Quantum computer
    Quantum computer

    A quantum computer is a device for computation that makes direct use of quantum mechanical phenomena, such as quantum superposition and quantum entanglement, to perform operations on data....
    s
  • Quantum decoherence
    Quantum decoherence

    In quantum mechanics, quantum decoherence is the mechanism by which quantum systems interact with their environments to exhibit probabilistically additive behavior....
  • Quantum Zeno effect
    Quantum Zeno effect

    The quantum Zeno effect is a name coined by George Sudarshan and Baidyanaith Misra of the University of Texas at Austin in 1977 in their analysis of the situation in which an unstable particle, if observed continuously, will never decay....
  • Quantum pseudo-telepathy
    Quantum pseudo-telepathy

    Quantum pseudo-telepathy is a phenomenon in quantum game theory resulting in anomalously high success rates in coordination games between separated players....
  • Measurement problem
    Measurement problem

    The measurement problem in quantum mechanics is the unresolved problem of how wavefunction collapse occurs. The inability to observe this process directly has given rise to different interpretations of quantum mechanics, and poses a key set of questions that each interpretation must answer....
  • Quantum electrochemistry
    Quantum electrochemistry

    The scientific school of Quantum electrochemistry began to form in the 1960s under Revaz Dogonadze. Generally speaking, the field comprises the notions arising in electrodynamics, quantum mechanics, and electrochemistry; and so is studied by a very large array of different professional researchers....
  • Quantum electronics
    Quantum electronics

    Quantum electronics is the area of physics dealing with the effects of quantum mechanics on the behaviour of electrons in matter, and their interactions with photons....
  • Quantum field theory
    Quantum field theory

    Quantum field theory or QFT provides a theoretical framework for constructing quantum mechanics models of systems classically described by field or of Many-body problem....
  • Quantum information
    Quantum information

    In quantum mechanics, quantum information is physical information that is held in the "state" of a quantum system. The most popular unit of quantum information is the qubit, a two-level quantum system....
  • Quantum mind
    Quantum mind

    Quantum mind theories are based on the premise that quantum mechanics is necessary to fully understand the mind and brain, particularly concerning an explanation of consciousness....
  • Quantum optics
    Quantum optics

    Quantum optics is a field of research in physics, dealing with the application of quantum mechanics to phenomena involving light and its interactions with matter....
  • Quantum thermodynamics
    Quantum thermodynamics

    In the physical sciences, quantum thermodynamics is the study of heat and Work dynamics in quantum systems. Approximately, quantum thermodynamics attempts to combine thermodynamics and quantum mechanics into a coherent whole....
  • Quasi-set theory
    Quasi-set theory

    Quasi-set theory is a formal mathematical theory of collections of indistinguishable objects, mainly motivated by the assumption that certain objects treated in quantum physics are indistinguishable....
  • Relation between Schrödinger's equation and the path integral formulation of quantum mechanics
    Relation between Schrödinger's equation and the path integral formulation of quantum mechanics

    This article relates the Schr?dinger equation with the path integral formulation of quantum mechanics using a simple nonrelativistic one-dimensional single-particle Hamiltonian composed of kinetic and potential energy....
  • Theoretical and experimental justification for the Schrödinger equation
    Theoretical and experimental justification for the Schrödinger equation

    The theoretical and experimental justification for the Schr?dinger equation motivates the discovery of the Schr?dinger equation, the equation that describes the dynamics of nonrelativistic particles....
  • Theoretical chemistry
    Theoretical chemistry

    Theoretical chemistry involves the use of physics to explain or predict chemistry phenomena. In recent years, it has consisted primarily of quantum chemistry, i.e., the application of quantum mechanics to problems in chemistry....


External links


General
  • - an online textbook
  • J. O'Connor and E. F. Robertson:
  • : three video lectures by Hans Bethe
    Hans Bethe

    Hans Albrecht Bethe was a Germany-United States physicist, and Nobel laureate in Nobel Prize in Physics for his work on the theory of stellar nucleosynthesis....


Course material
  • MIT OpenCourseWare
    MIT OpenCourseWare

    MIT OpenCourseWare is an initiative of the Massachusetts Institute of Technology to put all of the educational materials from its Post-secondary education- and Quaternary education courses online, Public domain and Open access to anyone, anywhere, by the end of the year 2007....
    : . See , , and
  • MIT OpenCourseWare: . See , , and
  • Doron Cohen:


FAQs


Media
  • — archive of articles from New Scientist
    New Scientist

    New Scientist is a liberal weekly international science magazine and website covering recent developments in science and technology for a general English language-speaking audience....
     magazine.
  • from Science Daily
    Science Daily

    Science Daily is a free online news source. It features news and articles on a variety of topics including: computer science, nanotechnology, medicine, psychology, biology, climate, space, physics, mathematics, chemistry, archeology, paleontology, and others....
Philosophy*