Hsianghualite
Encyclopedia
Hsianghualite is a tectosilicate (framework silicate) of lithium
Lithium
Lithium is a soft, silver-white metal that belongs to the alkali metal group of chemical elements. It is represented by the symbol Li, and it has the atomic number 3. Under standard conditions it is the lightest metal and the least dense solid element. Like all alkali metals, lithium is highly...

, calcium
Calcium
Calcium is the chemical element with the symbol Ca and atomic number 20. It has an atomic mass of 40.078 amu. Calcium is a soft gray alkaline earth metal, and is the fifth-most-abundant element by mass in the Earth's crust...

 and beryllium
Beryllium
Beryllium is the chemical element with the symbol Be and atomic number 4. It is a divalent element which occurs naturally only in combination with other elements in minerals. Notable gemstones which contain beryllium include beryl and chrysoberyl...

, with fluorine
Fluorine
Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...

, a member of the zeolite
Zeolite
Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents. The term zeolite was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that upon rapidly heating the material stilbite, it produced large amounts of steam from water that...

 group. It was discovered in 1958 and named for the type locality
Type locality (geology)
Type locality , also called type area or type locale, is the where a particular rock type, stratigraphic unit, fossil or mineral species is first identified....

, Hsiang Hua, 香花, meaning fragrant flower.

Structure

Structure is analogous to that of analcime with Be and Si in tetrahedral co-ordination forming a three-dimensional framework.
Its space group is I213 (Previously reported as I4132). Unit cell parameters are a = 12.879 or 12.897, and Z = 8.

Environment

It occurs within phlogopite
Phlogopite
Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O102. Iron substitutes for magnesium in variable amounts...

 veins in the light-coloured band of green and white banded metamorphosed Devonian
Devonian
The Devonian is a geologic period and system of the Paleozoic Era spanning from the end of the Silurian Period, about 416.0 ± 2.8 Mya , to the beginning of the Carboniferous Period, about 359.2 ± 2.5 Mya...

 limestone
Limestone
Limestone is a sedimentary rock composed largely of the minerals calcite and aragonite, which are different crystal forms of calcium carbonate . Many limestones are composed from skeletal fragments of marine organisms such as coral or foraminifera....

 which has been intruded by beryllium-bearing granite
Granite
Granite is a common and widely occurring type of intrusive, felsic, igneous rock. Granite usually has a medium- to coarse-grained texture. Occasionally some individual crystals are larger than the groundmass, in which case the texture is known as porphyritic. A granitic rock with a porphyritic...

. Associated mineral include fluorite
Fluorite
Fluorite is a halide mineral composed of calcium fluoride, CaF2. It is an isometric mineral with a cubic habit, though octahedral and more complex isometric forms are not uncommon...

, liberite, chrysoberyl
Chrysoberyl
The mineral or gemstone chrysoberyl is an aluminate of beryllium with the formula BeAl2O4. The name chrysoberyl is derived from the Greek words χρυσός chrysos and βήρυλλος beryllos, meaning "a gold-white spar". Despite the similarity of their names, chrysoberyl and beryl are two completely...

, taaffeite
Taaffeite
Taaffeite is a mineral named after its discoverer, Count Edward Charles Richard Taaffe who found the first cut and polished gem in November 1945. As such, it is the only gemstone to have been initially identified from a faceted stone. Most pieces of the gem, prior to Taaffe, had been...

 and nigerite.

Localities

Hsianghualite has been found only at the type locality, the Xianghualing Mine in Linwu County, Hunan Province, China.

External links

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