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Fire triangle



 
 
The fire triangle or combustion triangle is a simple model, from the practitioners of firefighting
Firefighter

Firefighters are rescuers extensively trained primarily to put out hazardous fires that threaten civilian populations and property, to rescue people from car accidents, collapsed and burning buildings and other such situations....
, for understanding the ingredients necessary for most fire
Fire

Fire is the oxidation of a combustion material releasing heat, light, and various Chemical reaction products such as carbon dioxide and water....
s. It has largely been replaced in the industry by the fire tetrahedron, which add further aspects, but still doesn't explain fire fighting sufficiently.






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Fire Triangle
The fire triangle or combustion triangle is a simple model, from the practitioners of firefighting
Firefighter

Firefighters are rescuers extensively trained primarily to put out hazardous fires that threaten civilian populations and property, to rescue people from car accidents, collapsed and burning buildings and other such situations....
, for understanding the ingredients necessary for most fire
Fire

Fire is the oxidation of a combustion material releasing heat, light, and various Chemical reaction products such as carbon dioxide and water....
s. It has largely been replaced in the industry by the fire tetrahedron, which add further aspects, but still doesn't explain fire fighting sufficiently. It is also described below.

The problem with the fire triangle is that it mixes two physical substances with the energy content. This problem increases when it is made to a tetrahedron: a chemical limitation is added.

The triangle illustrates the rule that in order to ignite and burn, a fire requires three elements: heat
Heat

In physics and thermodynamics, heat is any transfer of energy from one body or thermodynamic system to another due to a difference in temperature....
, fuel
Fuel

Fuel is any material that is burned or altered in order to obtain energy and to heat or to move an object. Fuel releases its energy either through a chemical reaction means, such as combustion, or nuclear means, such as nuclear fission or nuclear fusion....
, and an oxidizing agent
Oxidizing agent

An oxidizing agent can be defined as either:#a chemical compound that readily transfers oxygen atoms, or#a substance that gains electrons in a redox chemical reaction...
, usually oxygen
Oxygen

Oxygen no O2 produced; 2) O2 produced, but absorbed in oceans & seabed rock; 3) O2 starts to gas out of the oceans, but is absorbed by land surfaces and formation of ozone layer; 4-5) O2 sinks filled and the gas accumulates]]...
. The fire is prevented or extinguished by removing any one of them. A fire naturally occurs when the elements are combined in the right mixture. But, which is essential, fires commonly stops due to lack of heat. This leads to a decreased temperature. When the temperature has fallen sufficiently low (approx 1600K if you calculate the adiabatic temperature), the flames go out.

Without sufficient heat, a fire cannot begin, and it cannot continue. Heat can be removed by dousing with water; the water turns to steam and the steam is further heated, taking the heat with it. Introducing particles of powder or any gas in the flame removes heat in the same manner. Separating burning fuels from each other also reduces the heat. In forest fires, burning logs are separated and placed into safe areas where there is no other fuel. Scraping ember
Ember

For the book series by Jeanne DuPrau, see The City of Ember.Embers are the glowing, hot coals made of greatly heated wood, coal or other carbon based material that remain after, or sometimes precede a fire....
s from a burning structure also removes the heat source. Turning off the electricity in an electrical fire removes the ignition source.


Without fuel, a fire will stop. Fuel can be removed naturally, as where the fire has consumed all the burnable fuel, or manually, by mechanically or chemically removing the fuel from the fire. Fuel separation is an important factor in wildland fire
Wildfire

A wildfire is any uncontrolled, non-structure fire that occurs in the wilderness, wildland, or The Bush. Synonyms such as wildland fire, forest fire, brush fire, vegetation fire, grass fire, Peat#Fires, bushfire , and hill fire are commonly used....
 suppression, and is the basis for most major tactics, such as controlled burn
Controlled burn

Controlled or prescribed burning, also known as hazard reduction burning is a technique sometimes used in forest management, farming, prairie restoration or Greenhouse gas abatement....
s. Note, however, that the fire stops because a lower concentration of fuel vapor in the flame leads to a decrease in energy release and a lower temperature. Removing the fuel thereby decreases the heat.


Without sufficient Oxygen, a fire cannot begin, and it cannot continue. With a decreased oxygen concentration, the combustion velocity gets lower. But, in most cases there is plenty of air left when the fire goes out so this is commonly not a major factor. An example of this is that when adding inert gases, you need about 30% carbon dioxide, but about 40% nitrogen to suppress a flame. If the removal of oxygen was the point, the concentrations should be equal. The explanation is that carbon dioxide requires more energy to be heated and therfore a lower concentration. So, once again, it is all about reducing the temperature in the flame below the level where radicals can exist.


Fire tetrahedron

Fire Tetrahedron
Just heat explain suppression in far most cases. However, the suppression effect of Halon
Halon

Halon can refer to:* Haloalkane, or halogenoalkane, a group of chemical compounds consisting of alkanes with linked halogens. In particular, bromine-containing haloalkanes....
 can be explained only to approx 95% by regarding the thermal theory. The remaining 5% can be explained by its chemical inhibiton. That means that it reacts chemically to reduce the concentration of radicals in the flame. The radicals are essential in the chemical reactions. This has led to development of the fire tetrahedron: a triangular pyramid having four sides including the bottom representing the sustaining of chemical reaction
Chemical reaction

A chemical reaction is a process that always results in the interconversion of chemical substances. The substance or substances initially involved in a chemical reaction are called reactants....
s.

Combustion
Combustion

Combustion or burning is a complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames, appearance of light flickering....
 is the chemical reaction that feeds on a fire more heat and allows it to continue. When the fire involves burning metals like lithium
Lithium

Lithium is a chemical element with the symbol Li and atomic number 3. It is a soft alkali metal with a silver-white color. Under standard conditions for temperature and pressure, it is the lightest metal and the least dense solid element....
, magnesium
Magnesium

Magnesium is a chemical element with the symbol Mg, atomic number 12, atomic weight 24.3050 and common oxidation number +2.Magnesium, an alkaline earth metal, is the ninth most abundance of the chemical elements in the universe by mass....
, steel
Steel

Steel is an alloy consisting mostly of iron, with a carbon content between 0.2% and 2.14% by weight , depending on grade. Carbon is the most cost-effective alloying material for iron, but various other alloying elements are used such as manganese, chromium, vanadium, and tungsten....
,aluminum etc.(known as a class-D fire
Fire classes

In firefighting, fires are identified according to one or more fire classes. Each class designates the fuel involved in the fire, and thus the most appropriate fire control....
 in the American fire classification system), it becomes even more important to consider the energy release. The metals react faster with water than with oxygen and thereby more energy is released. Putting water on such a fire results in the fire getting hotter or even exploding
Explosion

An explosion is a sudden increase in volume and release of energy in an extreme manner, usually with the generation of high temperatures and the release of gases....
 because the metals react with water in an exothermic reaction
Exothermic reaction

An exothermic reaction is a chemical reaction that releases energy in the form of heat. It is the opposite of an endothermic reaction. Expressed in a chemical equation:...
. Therefore, inert agents (eg dry sand) must be used to break the chain reaction of metallic combustion.

Fire square

The fire square is a model created by fire ecologist Richard W. Halsey. It shows how catastrophic wild fires, like the 2003 Cedar Fire
Cedar Fire

The Cedar Fire was a human-caused wildfire which burned out of control through a large area of Southern California in October 2003. Driven by Santa Ana wind, the fire burned 2,820 buildings and had killed 15 people including one firefighter before being contained on November 3, making it the largest fire in recorded California history....
, are formed. It includes the three original elements from the Fire Triangle, but adds an extra side, showing Extreme Weather as another important element. Extreme weather is however affecting the fuel side of the triangle giving more easily pyrolysed materials, and also the heat side of the triangle. This means that the original triangle accounts also for the extreme weather situation.

Another graphical method for showing the fire tetrahedron is a causal relationship that allows any element to me removed via a Root Cause Analysis technique. If any of the three elements are taken away then there is no fire.

See also

  • Carbon dioxide
    Carbon dioxide

    Carbon dioxide is a chemical compound composed of two oxygen atoms covalent bond to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state....
  • Combustion
    Combustion

    Combustion or burning is a complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames, appearance of light flickering....
  • Glossary of firefighting terms
    Glossary of firefighting terms

    Firefighting jargon includes a diverse lexicon of both common and idiosyncratic terms. One problem that exists in trying to create a list such as this is that much of the terminology used by a particular department is specifically defined in their particular SOPs, such that two departments may have completely different terms for the same thing....
  • Inert gas
    Inert gas

    An inert gas is any gas that is not reactive with elements.Like the noble gases an inert gas is not necessarily elemental and are often compound gases....
  • Oxygen
    Oxygen

    Oxygen no O2 produced; 2) O2 produced, but absorbed in oceans & seabed rock; 3) O2 starts to gas out of the oceans, but is absorbed by land surfaces and formation of ozone layer; 4-5) O2 sinks filled and the gas accumulates]]...
  • Fire classes
    Fire classes

    In firefighting, fires are identified according to one or more fire classes. Each class designates the fuel involved in the fire, and thus the most appropriate fire control....