Dibasic ester
Encyclopedia
In chemistry, a dibasic ester or DBE is an ester
Ester
Esters are chemical compounds derived by reacting an oxoacid with a hydroxyl compound such as an alcohol or phenol. Esters are usually derived from an inorganic acid or organic acid in which at least one -OH group is replaced by an -O-alkyl group, and most commonly from carboxylic acids and...

 of a dicarboxylic acid
Dicarboxylic acid
Dicarboxylic acids are organic compounds that contain two carboxylic acid functional groups. In molecular formulae for dicarboxylic acids, these groups are often written as HOOC-R-COOH, where R may be an alkyl, alkenyl, alkynyl, or aryl group...

. Depending on the application, the alcohol may be methanol or higher molecular weight monoalcohols.

Mixtures of different methyl dibasic esters are commercially produced from short-chain acids such as adipic acid
Adipic acid
Adipic acid is the organic compound with the formula 42. From the industrial perspective, it is the most important dicarboxylic acid: About 2.5 billion kilograms of this white crystalline powder are produced annually, mainly as a precursor for the production of nylon...

, glutaric acid
Glutaric acid
Glutaric acid is the organic compound with the formula HO2C3CO2H. Although the related "linear" dicarboxylic acids adipic and succinic acids are water-soluble only to a few percent at room temperature, the water-solubility of glutaric acid is over 50%....

, and succinic acid
Succinic acid
Succinic acid is a dicarboxylic acid. Succinate plays a biochemical role in the citric acid cycle. The name derives from Latin succinum, meaning amber, from which the acid may be obtained....

. They are non-flammable, readily biodegradable, non-corrosive, and have a mild, fruity odour.

Dibasic esters of phthalates, adipates, and azelates with C8 - C10 alcohols have found commercial use as lubricants, spin finishes, and additives.

Applications

Dibasic esters are used in paint
Paint
Paint is any liquid, liquefiable, or mastic composition which after application to a substrate in a thin layer is converted to an opaque solid film. One may also consider the digital mimicry thereof...

s, paint stripper
Paint stripper
Paint stripper, or paint remover, is the generic name given to solvent mixtures designed to remove paint and other finishes and also to clean the underlying surface. The principal active ingredient is usually dichloromethane...

s, coatings, plasticisers, resin
Resin
Resin in the most specific use of the term is a hydrocarbon secretion of many plants, particularly coniferous trees. Resins are valued for their chemical properties and associated uses, such as the production of varnishes, adhesives, and food glazing agents; as an important source of raw materials...

s, binder
Binder
The reaper-binder, or binder, was a farm implement that improved upon the reaper. The binder was invented in 1872 by Charles Withington. In addition to cutting the small-grain crop, it would also tie the stems into small bundles, or sheaves...

s, solvent
Solvent
A solvent is a liquid, solid, or gas that dissolves another solid, liquid, or gaseous solute, resulting in a solution that is soluble in a certain volume of solvent at a specified temperature...

s, polyol
Polyol
A polyol is an alcohol containing multiple hydroxyl groups. In two technological disciplines the term "polyol" has a special meaning: food science and polymer chemistry.- Polyols in food science :...

s, soil stabilization
Geotechnical engineering
Geotechnical engineering is the branch of civil engineering concerned with the engineering behavior of earth materials. Geotechnical engineering is important in civil engineering, but is also used by military, mining, petroleum, or any other engineering concerned with construction on or in the ground...

, chemical grouting
Grout
Grout is a construction material used to embed rebars in masonry walls, connect sections of pre-cast concrete, fill voids, and seal joints . Grout is generally composed of a mixture of water, cement, sand, often color tint, and sometimes fine gravel...

, oilfield drilling fluids
Drilling fluid
In geotechnical engineering, drilling fluid is a fluid used to aid the drilling of boreholes into the earth. Often used while drilling oil and natural gas wells and on exploration drilling rigs, drilling fluids are also used for much simpler boreholes, such as water wells. Liquid drilling fluid...

, crop protection products
Agrichemical
Agrochemical , a contraction of agricultural chemical, is a generic term for the various chemical products used in agriculture. In most cases, agrichemical refers to the broad range of pesticides, including insecticides, herbicides, and fungicides...

, and adhesives.
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