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Coal

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Coal



 
 
Coal is a readily combustible
Combustion

Combustion or burning is a complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames, appearance of light flickering....
 black or brownish-black sedimentary rock
Sedimentary rock

Sedimentary rock is one of the three main Rock types . Sedimentary rock is formed by deposition and consolidation of mineral and organic material and from precipitation of minerals from solution....
. The harder forms, such as anthracite coal, can be regarded as metamorphic rock
Metamorphic rock

Metamorphic rock is the result of the transformation of an existing rock type, the protolith, in a process called metamorphism, which means "change in form"....
 because of later exposure to elevated temperature and pressure. It is composed primarily of carbon
Carbon

Carbon is a chemical element with chemical symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalence?making four electrons available to form covalent bond chemical bonds....
 along with variable quantities of other elements, chiefly sulfur
Sulfur

Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
, hydrogen
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
, oxygen
Oxygen

Oxygen no O2 produced; 2) O2 produced, but absorbed in oceans & seabed rock; 3) O2 starts to gas out of the oceans, but is absorbed by land surfaces and formation of ozone layer; 4-5) O2 sinks filled and the gas accumulates]]...
 and nitrogen
Nitrogen

Nitrogen is a chemical element that has the symbol N and atomic number 7 and atomic mass 14.00674?. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78% by volume of Earth's atmosphere....
.

Coal was formed from plant remains that were protected by water and mud
MUD

In Online game, a MUD , pronounced /m?d/, is a multi-user real-time virtual world described entirely in text. It combines elements of role-playing games, hack and slash, interactive fiction, and online chat....
 against oxidization
Oxidization

Oxidization may refer to:* Oxidation* Beta oxidation* RustSee also * Redox...
 and biodegradation
Biodegradation

Biodegradation is the process by which organic compound substances are decomposition by the enzymes produced by living organisms. The term is often used in relation to ecology, waste management and natural environmental environmental remediation ....
, thus trapping atmospheric carbon in the ground.






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Coal Anthracite
Coal is a readily combustible
Combustion

Combustion or burning is a complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames, appearance of light flickering....
 black or brownish-black sedimentary rock
Sedimentary rock

Sedimentary rock is one of the three main Rock types . Sedimentary rock is formed by deposition and consolidation of mineral and organic material and from precipitation of minerals from solution....
. The harder forms, such as anthracite coal, can be regarded as metamorphic rock
Metamorphic rock

Metamorphic rock is the result of the transformation of an existing rock type, the protolith, in a process called metamorphism, which means "change in form"....
 because of later exposure to elevated temperature and pressure. It is composed primarily of carbon
Carbon

Carbon is a chemical element with chemical symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalence?making four electrons available to form covalent bond chemical bonds....
 along with variable quantities of other elements, chiefly sulfur
Sulfur

Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
, hydrogen
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
, oxygen
Oxygen

Oxygen no O2 produced; 2) O2 produced, but absorbed in oceans & seabed rock; 3) O2 starts to gas out of the oceans, but is absorbed by land surfaces and formation of ozone layer; 4-5) O2 sinks filled and the gas accumulates]]...
 and nitrogen
Nitrogen

Nitrogen is a chemical element that has the symbol N and atomic number 7 and atomic mass 14.00674?. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78% by volume of Earth's atmosphere....
.

Coal was formed from plant remains that were protected by water and mud
MUD

In Online game, a MUD , pronounced /m?d/, is a multi-user real-time virtual world described entirely in text. It combines elements of role-playing games, hack and slash, interactive fiction, and online chat....
 against oxidization
Oxidization

Oxidization may refer to:* Oxidation* Beta oxidation* RustSee also * Redox...
 and biodegradation
Biodegradation

Biodegradation is the process by which organic compound substances are decomposition by the enzymes produced by living organisms. The term is often used in relation to ecology, waste management and natural environmental environmental remediation ....
, thus trapping atmospheric carbon in the ground. Over time, the chemical and physical properties of the remains were changed by geological action to create a solid material.

Coal, a fossil fuel
Fossil fuel

Fossil fuels or mineral fuels are fossil source fuels, that is, carbon or hydrocarbons found in the earth?s Crust .Fossil fuel range from volatile materials with low carbon:hydrogen ratios like methane, to liquid petroleum to nonvolatile materials composed of almost pure carbon, like anthracite coal....
, is the largest source of energy for the generation of electricity
Electricity generation

Electricity generation is the process of converting non-electrical energy to electricity. For electric utility, it is the first process in the delivery of electricity to consumers....
 worldwide, as well as one of the largest worldwide source of carbon dioxide
Carbon dioxide

Carbon dioxide is a chemical compound composed of two oxygen atoms covalent bond to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state....
 emissions. Carbon dioxide occurs naturally and is used by plants in photosynthesis
Photosynthesis

File:Seawifs global biosphere.jpgPhotosynthesis is a metabolic pathway that converts carbon dioxide into organic compounds, especially sugars, using the energy from sunlight....
. Gross carbon dioxide emissions from coal usage are slightly more than those from petroleum
Petroleum

Petroleum or crude oil is a naturally occurring, flammable liquid found in rock formations in the Earth consisting of a complex mixture of hydrocarbons of various molecular weights, plus other organic compounds....
 and about double the amount from natural gas
Natural gas

Natural gas is a gas consisting primarily of methane. It is found associated with fossil fuels, in coal beds, as methane clathrates, and is created by methanogenic organisms in marshes, bogs, and landfills....
. Coal is extracted from the ground by mining
Coal mining

Coal mining is the extraction or removal of coal from the earth by mining. When coal is used for fuel in power generation it is referred to as steaming or thermal coal....
, either underground or in open pits.

Types of coal

As geological processes apply pressure
Pressure

Pressure is the force per unit area applied to an object in a direction surface normal to the surface. Gauge pressure is the pressure relative to the local atmospheric or ambient pressure....
 to dead biotic matter over time, under suitable conditions it is transformed successively into
  • Peat
    Peat

    Peat is an accumulation of partially decayed vegetation biological tissue. Peat forms in wetlands or peatlands, variously called bogs, Moorland, muskegs, pocosins, mires, and peat swamp forests....
    , considered to be a precursor of coal, has industrial importance as a fuel in some regions, for example, Ireland and Finland.
  • Lignite
    Lignite

    Lignite, often referred to as brown coal, or Rosebud coal by Northern Pacific Railroad,is a soft brown fuel with characteristics that put it somewhere between coal and peat....
    , also referred to as brown coal, is the lowest rank of coal and used almost exclusively as fuel for electric power generation. Jet
    Jet (lignite)

    Jet is a geological material and is considered to be a minor gemstone. Jet is not considered a true mineral, but rather a mineraloid as it has an organic origin, being derived from decaying wood under extreme pressure....
     is a compact form of lignite that is sometimes polished and has been used as an ornamental stone since the Iron Age
    Iron Age

    In archaeology, the Iron Age was the stage in the development of any people in which tools and weapons whose main ingredient was iron were prominent....
    .
  • Sub-bituminous coal
    Sub-bituminous coal

    Sub-bituminous coal is a type of coal whose properties range from those of lignite to those of bituminous coal and are used primarily as fuel for Fossil fuel power plant....
    , whose properties range from those of lignite to those of bituminous coal and are used primarily as fuel for steam-electric power generation. Additionally, it is an important source of light aromatic hydrocarbons for the chemical synthesis industry.
  • Bituminous coal
    Bituminous coal

    Bituminous coal is a relatively soft coal containing a tarlike substance called bitumen. It is of higher quality than lignite but poorer quality than Anthracite....
    , dense mineral, black but sometimes dark brown, often with well-defined bands of bright and dull material, used primarily as fuel in steam-electric power generation, with substantial quantities also used for heat and power applications in manufacturing and to make coke
    Coke (fuel)

    Cokes are the solid carbonaceous material derived from destructive distillation of low-ash, low-sulfur bituminous coal. Cokes from coal are grey, hard, and porous....
    .
  • Anthracite, the highest rank; a harder, glossy, black coal used primarily for residential and commercial space heating. It may be divided further into metamorphically altered bituminous coal and petrified oil, as from the deposits in Pennsylvania.
  • Graphite
    Graphite

    The mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Greek language ??afe?? : "to draw/write", for its use in pencils, where it is commonly called lead, as distinguished from the actual metallic element lead....
    , technically the highest rank, but difficult to ignite and is not so commonly used as fuel: it is mostly used in pencils and, when powdered, as a lubricant
    Lubricant

    A lubricant is a substance introduced between two moving surfaces to reduce the friction between them, improving efficiency and reducing wear....
    .


The classification of coal is generally based on the content of volatiles. However, the exact classification varies between countries. According to the German classification, coal is classified as follows:
Name Volatiles % C Carbon % H Hydrogen % O Oxygen % S Sulfur % Heat content kJ/kg
Braunkohle (Lignite)45-6560-756.0-5.834-170.5-3<28470
Flammkohle (Flame coal)40-4575-826.0-5.8>9.8~1<32870
Gasflammkohle (Gas flame coal)35-4082-855.8-5.69.8-7.3~1<33910
Gaskohle (Gas coal)28-3585-87.55.6-5.07.3-4.5~1<34960
Fettkohle (Fat coal)19-2887.5-89.55.0-4.54.5-3.2~1<35380
Esskohle (Forge coal)14-1989.5-90.54.5-4.03.2-2.8~1<35380
Magerkohle (Non baking coal)10-1490.5-91.54.0-3.752.8-3.5~135380
Anthrazit (Anthracite)7-12>91.5<3.75<2.5~1<35300
The middle six grades in the table represent a progressive transition from the English-language sub-bituminous to bituminous coal, while the last class is an approximate equivalent to anthracite, but more inclusive (the U.S. anthracite has < 6% volatiles).

Cannel coal
Cannel coal

Cannel coal, also known as candle coal, is a type of coal, also classified as terrestrial type oil shale, with a large amount of hydrogen, which burns easily with a bright light and leaves little ash....
 (sometimes called "candle coal"), is a variety of fine-grained, high-rank coal with a large amount of hydrogen. It consists primarily of "exinite
Exinite

Formerly, in coal geology, exinite was an umbrella term, used when referring to the finely-ground and macrerated remains, originally formed by spores, pollen, dinoflagellate cysts, leaf cuticles, plant resins and waxes, as found in coal deposits....
" macerals, now termed "liptinite".

Early use

Outcrop
Outcrop

Outcrop is a Geology term referring to the appearance of bedrock or superficial deposits exposed at the surface of the Earth. In most places the bedrock or superficial deposits are covered by a mantle of soil and vegetation and cannot be seen or examined closely....
 coal was used in Britain
Great Britain

Great Britain is an island lying to the northwest of Continental Europe. It is the List of islands by area, and the largest in Europe. With a population of 58.9 million people it is List of islands by population....
 during the Bronze Age
Bronze Age

The Bronze Age is, with respect to a given prehistory, the period in that society when the most advanced metalworking included smelting copper and tin from naturally-occurring outcroppings of copper and tin ores, creating a bronze alloy by melting those metals together, and casting them into bronze artifact s....
 (2000-3000 years BC), where it has been detected as forming part of the composition of funeral
Funeral

A funeral is a ceremony marking a person's death. Funerary customs comprise the complex of beliefs and practices used by a culture to remember the dead, from the funeral itself, to various monuments, prayers, and rituals undertaken in their honour....
 pyre
Pyre

A pyre is a structure, usually made of wood, for burning a body as part of a funeral rite. As a form of cremation, a body is placed upon the pyre which is then set on fire....
s. The earliest recognized use is from the Shenyang
Shenyang

Shenyang , or Mukden , is a sub-provincial city and capital city of Liaoning Provinces of China in Northeast China.Along with its nearby cities, Shenyang is an important industrial center in China, and the transportation and commercial centre of China's northeastern region....
 area 4000 BC where Neolithic
Neolithic

The Neolithic period was a period in the development of human technology, beginning about 9500 Before the Christian Era in the Middle East that is traditionally considered the last part of the Stone Age....
 inhabitants had begun carving ornaments from black lignite, but it was not until the Han Dynasty
Han Dynasty

The Han Dynasty followed the Qin Dynasty and preceded the Three Kingdoms in China. The Han Dynasty was ruled by the family known as the Liu clan who had peasant origins....
 (206 BC–220 AD) that coal was also used for fuel. In Roman Britain
Roman Britain

Roman Britain refers to those parts of the island of Great Britain controlled by the Roman Empire between AD 43 and 410. The Romans referred to their province as Britannia....
, with the exception of two modern fields, "the Romans
Ancient Rome

Ancient Rome was a civilization that grew out of a small agricultural community founded on the Italian Peninsula as early as the 10th century BC....
 were exploiting coals in all the major coalfields in England
England

native_name =|conventional_long_name = England|common_name = England|image_flag = Flag of England.svg|image_coat = England COA.svg|symbol_type = Royal Coat of Arms...
 and Wales
Wales

native_name = Cymru|conventional_long_name = Wales|common_name = Wales|image_flag = Flag of Wales 2.svg|national_motto = ...
 by the end of the second century AD". Evidence of trade in coal (dated to about AD 200) has been found at the inland port of Heronbridge, near Chester
Chester

Chester is the county town of Cheshire, England. Lying on the River Dee, Wales, close to the border with Wales, it is home to 77,040 inhabitants, and is the largest and most populous settlement of the wider local government district of the Chester , which had a population of 118,210 according to the United Kingdom Census 2001....
, and in the Fenlands
The Fens

The Fens, also known as the Fenland, is a geographic area in eastern England, in the United Kingdom.The Fenland primarily lies around the coast of the Wash; it reaches into two Government regions , four ceremonial counties , 11 District Councils and five postcode areas ....
 of East Anglia, where coal from the Midlands
English Midlands

The Midlands is an area of England which broadly corresponds to the early-mediaeval Mercia. The area lies between Southern England, Northern England, East Anglia and Wales, and its largest city is Birmingham....
 was transported via the Car Dyke
Car Dyke

The Car Dyke was, and to large extent still is, an eighty-five mile long ditch which runs along the western edge of the Fens in eastern England....
 for use in drying grain. Coal cinders have been found in the hearths of villa
Roman villa

A Roman villa is a villa that was built or lived in during the Roman republic and the Roman Empire. A villa was originally a Rome country house built for the upper class....
s and military forts
Castra

The Latin language word castra, with its singular castrum, was used by the ancient Romans to mean buildings or plots of land reserved to or constructed for use as a military defensive position....
, particularly in Northumberland
Northumberland

Northumberland is a Counties of England in the North East England of England. The non-metropolitan counties of England of Northumberland borders Cumbria to the west, County Durham to the south and Tyne and Wear to the south east, as well as having a border with the Scottish Borders council area to the north, and nearly eighty miles of Nort...
, dated to around AD 400. In the west of England contemporary writers described the wonder of a permanent brazier of coal on the altar of Minerva
Minerva

Minerva was the Roman mythology name of Greek goddess Athena. She was considered to be the virgin goddess of warriors, poetry, medicine, wisdom, commerce, weaving,crafts, and the inventor of music....
 at Aquae Sulis (modern day Bath) although in fact easily-accessible surface coal from what became the Somerset coalfield
Somerset coalfield

The Somerset coalfield included Coal mining in the north Somerset, England, area where coal was mined from the 15th century until 1973.It is part of a wider field which covered northern Somerset and southern Gloucestershire in England....
 was in common use in quite lowly dwellings locally. Evidence of coal's use for iron-working in the city during the Roman period has been found.

There is no evidence that the product was of great importance in Britain before the High Middle Ages
High Middle Ages

The High Middle Ages was the periodization of history of Europe in the 11th, 12th, and 13th centuries . The High Middle Ages were preceded by the Early Middle Ages and followed by the Late Middle Ages, which by convention end around 1500....
, after about AD 1000. Mineral
Mineral

A mineral is a naturally occurring solid formed through Geology processes that has a characteristic chemical composition, a highly ordered atomic structure, and specific physical properties....
 coal came to be referred to as "seacoal," probably because it came to many places in eastern England, including London
London

London is the capital of both England and the United Kingdom, and the most populous municipality in the European Union. An important settlement for two millennia, History of London goes back to its founding by the Roman Empire....
, by sea. This is accepted as the more likely explanation for the name than that it was found on beaches, having fallen from the exposed coal seams above or washed out of underwater coal seam outcrops. These easily accessible sources had largely become exhausted (or could not meet the growing demand) by the 13th century, when underground mining from shafts
Shaft mining

Shaft mining or Shaft sinking refers to the method of excavating a vertical or near-vertical tunnel from the top down, where there is initially no access to the bottom....
 or adit
Adit

An adit is a type of entrance to an underground mine which is horizontal or nearly horizontal. Adits are usually built into the side of a hill or mountain, and often occur when a measure of coal or an ore body is located inside the mountain but above the adjacent valley floor or coastal plain....
s was developed. In London there is still a Seacoal Lane and a Newcastle Lane (from the coal-shipping city of Newcastle
Newcastle upon Tyne

Newcastle upon Tyne is a City status in the United Kingdom and metropolitan borough of Tyne and Wear, in North East England. Situated on the north bank of the River Tyne, the city developed from a Roman Empire settlement called Pons Aelius, though it owes its name to the Newcastle Castle built in 1080, by Robert Curthose, the eldest son of...
) where in the seventeenth century coal was unloaded at wharves along the River Fleet
River Fleet

The River Fleet is the largest of London's Subterranean rivers of Londons. Its two headwaters are two streams on Hampstead Heath; each is now dammed into a series of ponds made in the 18th century, the Hampstead Ponds and the Highgate Ponds....
. An alternative name was "pitcoal," because it came from mines. It was, however, the development of the Industrial Revolution
Industrial Revolution

The Industrial Revolution was a period in the late 18th and early 19th centuries when major changes in agriculture, manufacturing, production, and transportation had a profound effect on the socioeconomics and cultural conditions in United Kingdom....
 that led to the large-scale use of coal, as the steam engine
Steam engine

File:Steam-powered fire engine.jpgA steam engine is a heat engine that performs mechanical work using steam as its working fluid.Steam engines have a long history, going back at least 2000 years....
 took over from the water wheel
Water wheel

A water wheel is a machine for converting the energy of flowing or falling water into more useful forms of power, a process otherwise known as hydropower....
.

Uses today

Dscn4524 Ashtabulacoalcars E2

Coal as fuel


Coal is primarily used as a solid fuel
Fuel

Fuel is any material that is burned or altered in order to obtain energy and to heat or to move an object. Fuel releases its energy either through a chemical reaction means, such as combustion, or nuclear means, such as nuclear fission or nuclear fusion....
 to produce electricity and heat through combustion. World coal consumption is about 6.2 billion tons annually. China
Coal power in China

The People's Republic of China is the largest consumer of coal in the world,Gives:China: 1,310,000,000 Billion short tons of coal consumed per yearUnited States: 1,060,000,000 and is about to become the largest user of coal-derived electicity, getting 1.95 trillion kilowatt-hours per year, or 68.7% of its electric...
 produced 2.38 billion tons in 2006 and India
India

India, officially the Republic of India , is a country in South Asia. It is the List of countries and outlying territories by total area country by geographical area, the List of countries by population country, and the most populous liberal democracy in the world....
 produced about 447.3 million tons in 2006. 68.7%
Coal power in China

The People's Republic of China is the largest consumer of coal in the world,Gives:China: 1,310,000,000 Billion short tons of coal consumed per yearUnited States: 1,060,000,000 and is about to become the largest user of coal-derived electicity, getting 1.95 trillion kilowatt-hours per year, or 68.7% of its electric...
 of China's electricity comes from coal. The USA consumes about 1.053 billion tons of coal each year, using 90% of it for generation of electricity. The world in total produced 6.19 billion tons of coal in 2006.

When coal is used for electricity generation
Electricity generation

Electricity generation is the process of converting non-electrical energy to electricity. For electric utility, it is the first process in the delivery of electricity to consumers....
, it is usually pulverized and then burned in a furnace
Furnace

File:Piec krepa.JPGA furnace is a device used for heating. The name derives from Latin fornax, oven. The earliest furnace was excavated at Balakot, a site of the Indus Valley Civilization, dating back to its mature phase ....
 with a boiler
Boiler

A boiler is a closed Pressure vessel in which water or other fluid is heated. The heated or vaporized fluid exits the boiler for use in various processes or heating applications....
. The furnace heat converts boiler water to steam
Steam

In physical chemistry, and in engineering, steam refers to vaporized water. It is a pure, completely invisible gaseous phase . At standard temperature and pressure, pure steam occupies about 1,600 times the volume of an equal mass of liquid water....
, which is then used to spin turbine
Turbine

A turbine is a rotary engine that extracts energy from a fluid flow. Claude Burdin coined the term from the Latin turbo, or vortex, during an 1828 engineering competition....
s which turn generator
Electrical generator

In electricity generation, an electrical generator is a device that converts mechanical energy to electrical energy, generally using electromagnetic induction....
s and create electricity. The thermodynamic efficiency of this process has been improved over time. "Standard" steam turbines have topped out with some of the most advanced reaching about 35% thermodynamic efficiency for the entire process, which means 65% of the coal energy is waste heat released into the surrounding environment. Old coal power plants, especially "grandfathered" plants, are significantly less efficient and produce higher levels of waste heat. About 40% of the world's electricity comes from coal, and approximately 49% of the United States electricity comes from coal. The emergence of the supercritical turbine
Steam turbine

A steam turbine is a mechanical device that extracts thermal energy from pressurized steam, and converts it into rotary motion. Its modern manifestation was invented by Charles Algernon Parsons in 1884....
 concept envisions running a boiler at extremely high temperatures and pressures with projected efficiencies of 46%, with further theorized increases in temperature and pressure perhaps resulting in even higher efficiencies.

Other efficient ways to use coal are combined cycle power plants
Combined cycle

A combined cycle is characteristic of a power producing engine or plant that employs more than one thermodynamic cycle. Heat engines are only able to use a portion of the energy their fuel generates ....
, combined heat and power cogeneration
Cogeneration

Cogeneration is the use of a heat engine or a power station to simultaneously generate both electricity and useful heat.Conventional power plants emit the heat created as a by-product of electricity generation into the environment through cooling towers, flue gas, or by other means....
, and an MHD topping cycle.

Approximately 40% of the world electricity production uses coal. The total known deposits recoverable by current technologies, including highly polluting, low energy content types of coal (i.e., lignite
Lignite

Lignite, often referred to as brown coal, or Rosebud coal by Northern Pacific Railroad,is a soft brown fuel with characteristics that put it somewhere between coal and peat....
, bituminous
Bituminous coal

Bituminous coal is a relatively soft coal containing a tarlike substance called bitumen. It is of higher quality than lignite but poorer quality than Anthracite....
), might be sufficient for 300 years' use at current consumption levels, although maximal production could be reached within decades (see World Coal Reserves
Coal

Coal is a readily combustion black or brownish-black sedimentary rock. The harder forms, such as anthracite, can be regarded as metamorphic rock because of later exposure to elevated temperature and pressure....
, below).

A more energy-efficient way of using coal for electricity production would be via solid-oxide fuel cell
Solid-oxide fuel cell

A solid oxide fuel cell is an electrochemical conversion device that produces electricity directly from oxidizing a fuel. Fuel cells are characterized by their electrolyte material and, as the name implies, the SOFC has a solid oxide, or ceramic, electrolyte....
s or molten-carbonate fuel cell
Molten-carbonate fuel cell

Molten-carbonate fuel cells are high-temperature fuel cells, that operate at temperatures of 600?C and above.Molten carbonate fuel cells are currently being developed for natural gas and coal-based power plants for electrical utility, industrial, and military applications....
s (or any oxygen ion transport based fuel cells that do not discriminate between fuels, as long as they consume oxygen), which would be able to get 60%–85% combined efficiency (direct electricity + waste heat steam turbine). Currently these fuel cell technologies can only process gaseous fuels, and they are also sensitive to sulfur poisoning, issues which would first have to be worked out before large scale commercial success is possible with coal. As far as gaseous fuels go, one idea is pulverized coal
Coal dust

Coal dust is a fine Powder form of coal, which is created by the crushing, grinding, or pulverizing of coal. Because of the brittle nature of coal, coal dust can be created during mining, transportation, or by mechanically handling coal....
 in a gas carrier, such as nitrogen. Another option is coal gas
Coal gas

Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities....
ification with water, which may lower fuel cell voltage by introducing oxygen to the fuel side of the electrolyte, but may also greatly simplify carbon sequestration. However, this technology has been criticised as being inefficient, slow, risky and costly, while doing nothing about total emissions from mining, processing and combustion. Another efficient and clean way of coal combustion in a form of coal-water slurry fuel
Coal-water slurry fuel

Coal-water slurry fuel is a fuel which consists of fine coal particles suspended in water. Presence of water in CWS reduces harmful emissions into the atmosphere, makes the coal explosion-proof, makes use of coal equivalent to use of liquid fuel , and gives other benefits ....
 (CWS) was well developed in Russia (since the Soviet Union time). CWS
Coal-water slurry fuel

Coal-water slurry fuel is a fuel which consists of fine coal particles suspended in water. Presence of water in CWS reduces harmful emissions into the atmosphere, makes the coal explosion-proof, makes use of coal equivalent to use of liquid fuel , and gives other benefits ....
 significantly reduces emissions saving the heating value of coal.

Coking and use of coke

Coke
Coke (fuel)

Cokes are the solid carbonaceous material derived from destructive distillation of low-ash, low-sulfur bituminous coal. Cokes from coal are grey, hard, and porous....
 is a solid carbonaceous residue derived from low-ash, low-sulfur bituminous coal
Bituminous coal

Bituminous coal is a relatively soft coal containing a tarlike substance called bitumen. It is of higher quality than lignite but poorer quality than Anthracite....
 from which the volatile constituents are driven off by baking in an oven without oxygen at temperatures as high as 1,000 °C (1,832 °F) so that the fixed carbon and residual ash are fused together. Metallurgic coke is used as a fuel and as a reducing agent in smelting iron
Iron

Iron is a chemical element with the symbol Fe and atomic number 26. Iron is a Group 8 element and period 4 element. Iron is lustrous and silvery in color....
 ore in a blast furnace
Blast furnace

A blast furnace is a type of metallurgy furnace used for smelting to produce metals, generally iron.In a blast furnace, fuel and ore are continuously supplied through the top of the furnace, while air is blown into the bottom of the chamber, so that the chemical reactions take place throughout the furnace as the material moves downward....
. Coke from coal is grey, hard, and porous and has a heating value of 24.8 million Btu/ton (29.6 MJ/kg). Some cokemaking processes produce valuable by-products that include coal tar
Coal tar

Coal tar is a brown or black liquid of high viscosity, which smells of naphthalene and aromatic hydrocarbons. Coal tar is among the by-products when coal is...
, ammonia
Ammonia

Ammonia is a chemical compound with the chemical formula nitrogenhydrogen. It is normally encountered as a gas with a characteristic pungent odor....
, light oils, and "coal gas
Coal gas

Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities....
".

Petroleum coke
Petroleum coke

Petroleum coke is a carbonaceous solid derived from oil refinery coker units or other cracking processes. Other Coke has traditionally been derived from coal....
 is the solid residue obtained in oil refining, which resembles coke but contains too many impurities to be useful in metallurgical applications.

Gasification
Coal gasification can be used to produce syngas
Syngas

Syngas is the name given to a gas mixture that contains varying amounts of carbon monoxide and hydrogen. Examples of production methods include steam reforming of natural gas or liquid hydrocarbons to produce hydrogen, the gasification of coal and in some types of waste-to-energy gasification facilities....
, a mixture of carbon monoxide
Carbon monoxide

Carbon monoxide, with the chemical formula CO, is a colorless and odorless, tasteless, yet highly toxic gas. Its molecules consist of one carbon atom covalent bond to one oxygen atom....
 (CO) and hydrogen
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
 (H2) gas. This syngas can then be converted into transportation fuels like gasoline and diesel through the Fischer-Tropsch process
Fischer-Tropsch process

The Fischer-Tropsch process is a catalyst chemistry in which synthesis gas , a mixture of carbon monoxide and hydrogen, is converted into liquid hydrocarbons of various forms....
. Currently, this technology is being used by the Sasol
Sasol

Sasol is a South African company involved in mining, energy, chemicals and synthetic fuel. In particular, they produce petrol and diesel profitably from coal and natural gas using Fischer-Tropsch synthesis....
 chemical company of South Africa to make gasoline from coal and natural gas. Alternatively, the hydrogen obtained from gasification can be used for various purposes
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
 such as powering a hydrogen economy
Hydrogen economy

The hydrogen economy is a proposed system of meeting energy needs by using hydrogen as a fuel source that could be generated from alternative fuels or other energy sources that don't give off greenhouse gases....
, making ammonia
Ammonia

Ammonia is a chemical compound with the chemical formula nitrogenhydrogen. It is normally encountered as a gas with a characteristic pungent odor....
, or upgrading fossil fuels.

During gasification, the coal is mixed with oxygen and steam (water vapor) while also being heated and pressurized. During the reaction, oxygen and water molecules oxidize the coal into carbon monoxide
Carbon monoxide

Carbon monoxide, with the chemical formula CO, is a colorless and odorless, tasteless, yet highly toxic gas. Its molecules consist of one carbon atom covalent bond to one oxygen atom....
 (CO) while also releasing hydrogen
Hydrogen

Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
 (H2) gas. This process has been conducted in both underground coal mines
Underground Coal Gasification

Underground coal gasification is an in-situ gasification process carried out in non-mined coal seams using injection and production wells drilled from the surface, which enables the coal to be converted into product gas....
 and in coal refineries.

(Coal) + O2 + H2O ? H2 + CO


If the refiner wants to produce gasoline, the syngas is collected at this state and routed into a Fischer-Tropsch reaction. If hydrogen is the desired end-product, however, the syngas is fed into the water gas shift reaction
Water gas shift reaction

The water-gas shift reaction is a chemical reaction in which carbon monoxide reacts with water to form carbon dioxide and hydrogen:The water-gas shift reaction is an important industrial reaction....
 where more hydrogen is liberated.

CO + H2O ? CO2 + H2


High prices of oil and natural gas are leading to increased interest in "BTU Conversion" technologies such as gasification
Gasification

Gasification is a process that converts carbonaceous materials, such as coal, petroleum, biofuel, or biomass, into carbon monoxide and hydrogen by reacting the raw material at high temperatures with a controlled amount of oxygen and/or steam....
, methanation and liquefaction. The Synthetic Fuels Corporation
Synthetic Fuels Corporation

The Synthetic Fuels Corporation was a U.S. government-funded corporation established in 1980 by the Synthetic Fuels Corporation Act to create a market for alternatives to imported fossil fuels ....
 was a U.S. government-funded corporation established in 1980 to create a market for alternatives to imported fossil fuels (such as coal gasification). The corporation was discontinued in 1985.

In the past, coal was converted to make coal gas
Coal gas

Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities....
, which was piped to customers to burn for illumination, heating, and cooking. At present, the safer natural gas
Natural gas

Natural gas is a gas consisting primarily of methane. It is found associated with fossil fuels, in coal beds, as methane clathrates, and is created by methanogenic organisms in marshes, bogs, and landfills....
 is used instead.

Liquefaction - Coal-To-Liquids (CTL)
Coals can also be converted into liquid fuels
Synthetic fuel

Synthetic fuel or synfuel is any liquid fuel obtained from coal, natural gas, or biomass. It can sometimes refer to fuels derived from other solids such as oil shale, tar sand, waste plastics, or from the fermentation of biomatter....
 like gasoline
Gasoline

File:GasCan.jpgGasoline or petrol is a petroleum-derived liquid mixture, primarily used as fuel in internal combustion engines.It consists mostly of aliphatic hydrocarbons, enhanced with iso-octane or the aromatic hydrocarbons toluene and benzene to increase its octane rating....
 or diesel
Diesel

Diesel or diesel fuel in general is any fuel used in diesel engines. The most common is a specific fractional distillation of petroleum fuel oil, but alternatives that are not derived from petroleum, such as biodiesel, biomass to liquid or gas to liquid diesel, are increasingly being developed and adopted....
 by several different processes. In the direct liquefaction processes, the coal is either hydrogenated
Hydrogenation

Hydrogenation is the chemical reaction that results from the addition of hydrogen . The process is usually employed to a redox or Saturation organic compounds....
 or carbonized
Carbonization

Carbonization or Carbonisation is the term for the conversion of an organic substance into carbon or a carbon-containing residue through pyrolysis or destructive distillation....
. Alternatively, coal can be converted into a gas first, and then into a liquid, by using the Fischer-Tropsch process
Fischer-Tropsch process

The Fischer-Tropsch process is a catalyst chemistry in which synthesis gas , a mixture of carbon monoxide and hydrogen, is converted into liquid hydrocarbons of various forms....
.

In the Bergius process
Bergius process

The Bergius Process is a method of production of liquid hydrocarbons for use as synthetic fuel by hydrogenation of high-volatile bituminous coal at high temperature and pressure....
, coal is liquefied by mixing it with hydrogen gas and heating the system (hydrogenation
Hydrogenation

Hydrogenation is the chemical reaction that results from the addition of hydrogen . The process is usually employed to a redox or Saturation organic compounds....
). This process was used by Germany
Germany

Germany , officially the Federal Republic of Germany , is a country in Central Europe. It is bordered to the north by the North Sea, Denmark, and the Baltic Sea; to the east by Poland and the Czech Republic; to the south by Austria and Switzerland; and to the west by France, Luxembourg, Belgium, and the Netherlands....
 during World War I
World War I

World War I, or the First World War , was a global military conflict which involved the Great powers, organized into two opposing military alliances: the Allies of World War I and the Central Powers....
 and World War II
World War II

World War II, or the Second World War , was a global military conflict which involved a Participants in World War II, including all of the great powers, organised into two opposing military alliances: the Allies of World War II and the Axis powers....
 and has been explored by SASOL
Sasol

Sasol is a South African company involved in mining, energy, chemicals and synthetic fuel. In particular, they produce petrol and diesel profitably from coal and natural gas using Fischer-Tropsch synthesis....
 in South Africa. Several other direct liquefaction processes have been developed, among these being the SRC-I and SRC-II (Solvent Refined Coal) processes developed by Gulf Oil
Gulf Oil

Gulf Oil was a major global petroleum Corporation from the 1900s to the 1980s. The eighth-largest American manufacturing company in 1941 and the ninth-largest in 1979, Gulf Oil was one of the so-called Seven Sisters oil companies....
 and implemented as pilot plants in the United States in the 1960s and 1970s. The NUS Corporation developed another hydrogenation process which was patented by Wilburn C. Schroeder in 1976. The process involved dried, pulverized coal mixed with roughly 1wt% molybdenum
Molybdenum

Molybdenum , is a Group 6 element chemical element with the symbol Mo and atomic number 42. It has the List of elements by melting point melting point of any element....
 catalysts. Hydrogenation occurred by use of high temperature and pressure synthesis gas
Syngas

Syngas is the name given to a gas mixture that contains varying amounts of carbon monoxide and hydrogen. Examples of production methods include steam reforming of natural gas or liquid hydrocarbons to produce hydrogen, the gasification of coal and in some types of waste-to-energy gasification facilities....
 produced in a separate gasifier. The process ultimately yielded a synthetic crude product, Naphtha
Naphtha

Naphtha normally refers to a number of different flammable liquid mixtures of hydrocarbons, i.e. a distillation product from petroleum or coal tar boiling in a certain range and containing certain hydrocarbons, a broad term encompassing any volatile, flammable liquid hydrocarbon mixture....
, a limited amount of C3/C4 gas, light-medium weight liquids (C5-C10) suitable for use as fuels, small amounts of NH3 and significant amounts of CO2.

The process of low temperature carbonization
Carbonization

Carbonization or Carbonisation is the term for the conversion of an organic substance into carbon or a carbon-containing residue through pyrolysis or destructive distillation....
 (LTC) can also convert coal into a liquid fuel. Coal is coked at temperatures between 450 and 700°C compared to 800 to 1000°C for metallurgical coke. These temperatures optimize the production of coal tars richer in lighter hydrocarbons than normal coal tar. The coal tar is then further processed into fuels. The Karrick process
Karrick process

The Official Seal of Relevance and Integrity:The Karrick process is a low-temperature carbonization of coal, Oil shale, lignite or any carbonaceous materials....
 was developed by Lewis C. Karrick, an oil shale technologist at the U.S. Bureau of Mines
United States Bureau of Mines

For most of the 20th century, the U.S. Bureau of Mines was the primary Federal government of the United States agency conducting scientific research and disseminating information on the extraction, processing, use, and conservation of mineral natural resource....
 in the 1920s.

In the Fischer-Tropsch process
Fischer-Tropsch process

The Fischer-Tropsch process is a catalyst chemistry in which synthesis gas , a mixture of carbon monoxide and hydrogen, is converted into liquid hydrocarbons of various forms....
, an indirect route, coal is first gasified to make syngas
Syngas

Syngas is the name given to a gas mixture that contains varying amounts of carbon monoxide and hydrogen. Examples of production methods include steam reforming of natural gas or liquid hydrocarbons to produce hydrogen, the gasification of coal and in some types of waste-to-energy gasification facilities....
 (a balanced purified mixture of CO and H2 gas). Next, Fischer-Tropsch catalysts
Catalysis

Catalysis is the process in which the reaction rate of a chemical reaction is either increased or decreased by means of a chemical substance known as a catalyst....
 are used to convert the syngas into light hydrocarbons (like ethane
Ethane

Ethane is a chemical compound with chemical formula C2H6. It is the only two-carbon alkane, that is, an aliphatic hydrocarbon....
) which are further processed into gasoline and diesel. This method was used on a large technical scale in Germany
Germany

Germany , officially the Federal Republic of Germany , is a country in Central Europe. It is bordered to the north by the North Sea, Denmark, and the Baltic Sea; to the east by Poland and the Czech Republic; to the south by Austria and Switzerland; and to the west by France, Luxembourg, Belgium, and the Netherlands....
 between 1934 and 1945 and is currently being used by Sasol
Sasol

Sasol is a South African company involved in mining, energy, chemicals and synthetic fuel. In particular, they produce petrol and diesel profitably from coal and natural gas using Fischer-Tropsch synthesis....
 in South Africa. In addition to creating gasoline, syngas can also be converted into methanol
Methanol

Methanol, also known as methyl alcohol, carbinol, wood alcohol, wood naphtha or wood spirits, is a chemical compound with chemical formula carbonhydrogen3oxygenhydrogen ....
, which can be used as a fuel, or into a fuel additive
Gasoline additive

Gasoline additives increase gasoline's octane rating or act as corrosion inhibitors or lubricant, thus allowing the use of higher compression ratios for greater efficiency and power, however some carry heavy environmental risks....
.

All of these liquid fuel production methods release carbon dioxide (CO2) in the conversion process, far more than is released in the extraction and refinement of liquid fuel production from petroleum. If these methods were adopted to replace declining petroleum supplies, carbon dioxide emissions would be greatly increased on a global scale. For future liquefaction projects, Carbon dioxide sequestration is proposed to avoid releasing it into the atmosphere, though no pilot projects have confirmed the feasibility of this approach on a wide scale. As CO2 is one of the process streams, sequestration is easier than from flue gases produced in combustion
Combustion

Combustion or burning is a complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames, appearance of light flickering....
 of coal with air
Earth's atmosphere

The Earth's atmosphere is a layer of gases surrounding the planet Earth that is retained by the Earth's gravity. Dry air contains roughly 78.08% nitrogen, 20.95% oxygen, 0.93% argon, 0.038% Carbon dioxide in the Earth's atmosphere, and trace amounts of other gases....
, where CO2 is diluted by nitrogen
Nitrogen

Nitrogen is a chemical element that has the symbol N and atomic number 7 and atomic mass 14.00674?. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78% by volume of Earth's atmosphere....
 and other gases. Sequestration will, however, add to the cost.

The reaction of coal and water using high temperature
Temperature

In physics, temperature is a physical property of a Physical system that underlies the common notions of hot and cold; something that feels hotter generally has the greater temperature....
 heat from a nuclear reactor offers promise of liquid transport fuels that could prove carbon-neutral compared to petroleum use. The development of a reliable nuclear reactor that could provide 900 to 1000 deg C process heat, such as the pebble bed reactor, would be necessary.

Refined Coal

Refined coal is the product of a coal upgrading technology that removes moisture and certain pollutants from lower-rank coals such as sub-bituminous and lignite (brown) coals.[1] It is one form of several pre-combustion treatments and processes for coal that alter coal's characteristics before it is burned. The goals of pre-combustion coal technologies are to increase efficiency and reduce emissions when the coal is burned. Depending on the situation, pre-combustion technology can be used in place of or as a supplement to post-combustion technologies to control emissions from coal-fueled boilers.

Coal as a traded commodity


The price of coal has gone up from around $30 per short ton
Short ton

The short ton is a unit of weight equal to 2,000 Pound . In the United States it is often called simply ton without distinguishing it from the metric ton or the long ton ; rather, the other two are specifically noted....
 in 2000 to around $150.00 per short ton as of September 26th, 2008. As of October 31, 2008, the price per short ton has declined to $111.50.

In North America, a Central Appalachian coal futures contract
Futures contract

In finance, a futures contract is a standardized contract, traded on a futures exchange, to buy or sell a standardized quantity of a specified commodity of standardized quality at a certain date in the future, at a price determined by the instantaneous equilibrium between the forces of supply and demand among competing buy and sell orders...
 is currently traded on the New York Mercantile Exchange (trading symbol QL). The trading unit is 1,550 short tons per contract, and is quoted in U.S. dollars and cents per ton. Since coal is the principal fuel for generating electricity in the United States, the futures contract provides coal producers and the electric power industry an important tool for hedging
Hedge (finance)

In finance, a hedge is a position established in one market in an attempt to offset exposure to the price Risk#In_finance of an equal but opposite obligation or position in another market ? usually, but not always, in the context of one's commercial activity....
 and risk management.

In addition to the NYMEX contract, the IntercontinentalExchange (ICE)
IntercontinentalExchange

IntercontinentalExchange is an United States financial company that operates Internet-based exchange which trade futures contract and over-the-counter energy and commodity contracts as well as derivative financial products....
 has European (Rotterdam) and South African (Richards Bay) coal futures available for trading. The trading unit for these contracts is 5,000 metric tons, and are also quoted in U.S. dollars and cents per ton.

Cultural usage


Coal is the official state mineral
List of U.S. state minerals, rocks, stones and gemstones

Not every state has an official state mineral, rock, stone or gemstone. ...
 of Kentucky
Kentucky

The Commonwealth of Kentucky is a U.S. state located in the East Central United States of America. Kentucky is normally included in the group of Southern United States , but it is uncommonly included, geographically and culturally, in the Midwestern United States....
 and the official state rock
List of U.S. state minerals, rocks, stones and gemstones

Not every state has an official state mineral, rock, stone or gemstone. ...
 of Utah
Utah

The State of Utah is a western United States U.S. state of the United States. It was the List of U.S. states by date of statehood admitted to the United States on January 4, 1896....
. Both U.S. state
U.S. state

A U.S. state is any one of the 50 state of the United States that share sovereignty with the federal government of the United States . Because of this shared sovereignty, an United States is a citizen both of the federal entity and of his or her state of Domicile ....
s have an historic link to coal mining.

Some cultures uphold that children who misbehave will receive only a lump of coal from Santa Claus
Santa Claus

Santa Claus is a folklore figure in various cultures who distributes gifts to children, normally on Christmas Eve. Each name is a variation of Saint Nicholas, but refers to Santa Claus....
 for Christmas in their stocking
Christmas stocking

A Christmas stocking is an empty sock or sock-shaped bag that children hang on Christmas Eve so that Santa Claus can fill it with small toys, candy, fruit, coins, or other small gifts when he arrives....
s instead of presents.

It is also customary and lucky in Scotland to give coal as a gift on New Year's Day. It happens as part of First-Foot
First-Foot

In United Kingdom folklore, the first-foot, also known in Manx Gaelic as quaaltagh or qualtagh, is the first person to cross the threshold of a home on New Year's Day and a bringer of good fortune for the coming year....
ing and represents warmth for the year to come.

Environmental effects

There are a number of adverse environmental effects of coal mining
Coal mining

Coal mining is the extraction or removal of coal from the earth by mining. When coal is used for fuel in power generation it is referred to as steaming or thermal coal....
 and burning, specially in power stations.

These effects include:
  • release of carbon dioxide
    Carbon dioxide

    Carbon dioxide is a chemical compound composed of two oxygen atoms covalent bond to a single carbon atom. It is a gas at standard temperature and pressure and exists in Earth's atmosphere in this state....
    , a greenhouse gas
    Greenhouse gas

    Greenhouse gases are gases in an atmosphere that Absorption and Emission radiation within the Infrared#Different regions in the infrared range....
    , which causes climate change
    Climate change

    Climate change is any long-term significant change in the expected patterns of average weather of a specific region over an appropriately significant period of time....
     and global warming
    Global warming

    Global warming is the increase in the Instrumental temperature record of the Earth's near-surface air and the oceans since the mid-twentieth century and its projected continuation....
     according to the IPCC. Coal is the largest contributor to the human-made increase of CO2 in the air.
  • generation of hundred of millions of tons of waste products, including fly ash
    Fly ash

    Fly ash is one of the residues generated in the combustion of coal. Fly ash is generally captured from the chimneys of Fossil fuel power plant, and is one of two types of ash that jointly are known as coal ash; the other, bottom ash, is removed from the bottom of coal furnaces....
    , bottom ash
    Bottom ash

    Bottom ash refers to the non-combustible constituents of coal with traces of combustibles embedded in forming clinkers and sticking to hot side walls of a coal-burning furnace during its operation....
    , flue gas desulfurization
    Flue gas desulfurization

    Flue gas desulfurization is commonly known as FGD and is the technology used for removing sulfur dioxide from the exhaust Flue gas emissions from fossil fuel combustion in Fossil fuel power plant that burn coal or oil to produce steam for the steam turbines that drive their electricity generators....
     sludge, that contain mercury
    Mercury (element)

    Mercury , also called quicksilver or hydrargyrum , is a chemical element with the symbol Hg and atomic number 80. A heavy, silvery d-block metal, mercury is one of six elements that are liquid at or near room temperature and pressure....
    , uranium
    Uranium

    Uranium is a silvery-gray metallic chemical element in the actinide series of the periodic table that has the chemical symbol U and atomic number 92....
    , thorium
    Thorium

    Thorium is a chemical element with the symbol Th and atomic number 90. As a naturally occurring, slightly radioactive metal, it has been considered as an alternative nuclear fuel to uranium....
    , arsenic
    Arsenic

    Arsenic is a well-known chemical element that has the symbol As and atomic number 33. Arsenic was first documented by Albertus Magnus in 1250....
    , and other heavy metals
    Heavy metals

    A heavy metal is a member of an ill-defined subset of elements that exhibit metallic properties, which would mainly include the transition metals, some metalloids, lanthanides, and actinides....
  • acid rain
    Acid rain

    Acid rain is rain or any other form of Precipitation that is unusually acidic. It has harmful effects on plants, aquatic animals, and infrastructure....
     from high sulphur coal
  • interference with groundwater
    Groundwater

    Groundwater is water located beneath the ground surface in soil porosity spaces and in the fractures of lithologic formations. A unit of rock or an unconsolidated deposit is called an aquifer when it can yield a usable quantity of water....
     and water table levels
  • impact of water use on flows of rivers and consequential impact on other land-uses
  • dust nuisance
  • subsidence above tunnels, sometimes damaging infrastructure
  • rendering land unfit for other uses
  • coal-fired power plants without effective fly ash capture are one of the largest sources of human-caused background radiation
    Background radiation

    File:Kozloduy Nuclear Power Plant - Background radiation displays.jpgBackground radiation is the ionizing radiation constantly present in the environment, emitted from a variety of natural and artificial sources....
     exposure
  • coal-fired power plants shorten nearly 24,000 lives a year, including 2,800 from lung cancer.
  • coal-fired power plant releases emissions including mercury, selenium, and arsenic which are harmful to human health and the environment.


Economic aspects

Coal liquefaction is one of the backstop
Backstop resources

Backstop resources theory states that as a heavily utilized limited resources becomes expensive, alternative resources will become cheap by comparison, therefore making the alternatives economically viable options....
 technologies that could potentially limit escalation of oil prices and mitigate
Mitigation

Mitigate: To lower, to reduce the amount of... To make less in intensity.Mitigation may refer to:* Mitigation of global warming* Emergency_management#Mitigation_2 ...
 the effects of transportation energy shortage that some authors have suggested could occur under peak oil
Peak oil

Peak oil is the point in time when the maximum rate of global petroleum Extraction of petroleum is reached, after which the rate of production enters terminal decline....
. This is contingent on liquefaction production capacity becoming large enough to satiate the very large and growing demand for petroleum. Estimates of the cost of producing liquid fuels from coal suggest that domestic U.S. production of fuel from coal becomes cost-competitive with oil priced at around 35 USD per barrel, (break-even cost). With oil prices back at around USD 40 per barrel as of December 15, 2008, liquid coal has once again lost much of its economic allure.

Among commercially mature technologies, advantage for indirect coal liquefaction over direct coal liquefaction are reported by Williams and Larson (2003).

Intensive research and project developments have been implemented from 2001. The is granted to personalities having brought eminent contribution to the understanding and development of Coal liquefaction. The 2009 presentation ceremony will take place in Washington DC (USA) at the Conference (25-27 March, 2009).

Energy density


The energy density of coal, i.e. its heating value, is roughly 24 megajoules per kilogram
Kilogram

The kilogram or kilogrammeThe spelling kilogram is used by the International Committee for Weights and Measures and the U.S....
.

The energy density of coal can also be expressed in kilowatt-hours
Watt-hour

The kilowatt hour, also written kilowatt-hour, is a unit of energy.Energy delivered by electric utilities is usually expressed and charged for in kWh....
 for some unit of mass, the units that electricity is most commonly sold in, to estimate how much coal is required to power electrical appliances. One kilowatt-hour is 3.6 MJ, so the energy density of coal is 6.67 kW·h/kg. The typical thermodynamic efficiency of coal power plants is about 30%, so of the 6.67 kW·h of energy per kilogram of coal, 30% of that—2.0 kW·h/kg—can successfully be turned into electricity; the rest is waste heat. So coal power plants obtain approximately 2.0 kW·h per kilogram of burned coal.

As an example, running one 100 watt computer for one year requires 876 kW·h (100 W × 24 h/day × 365 = 876000 W·h = 876 kW·h). Converting this power usage into physical coal consumption:

It takes 438 kg (966 lb) of coal to power a computer for one full year. One should also take into account transmission and distribution losses
Power Line

Power Line is an United States politics of the United States blog, providing news and commentary from a Conservatism point-of-view. It is written by three lawyers who attended Dartmouth College together: John H....
 caused by resistance and heating in the power lines, which is in the order of 5–10%, depending on distance from the power station and other factors.

Relative carbon cost


Because coal is at least 50% carbon (by mass), then 1 kg of coal contains at least 0.5 kg of carbon, which is where 1 mol
Mole (unit)

The mole is a Units of measurement of amount of substance: it is an SI base unit, and one of the few units used to measure this physical quantity....
 is equal to NA (Avogadro Number) particles.

This combines with oxygen in the atmosphere during combustion, producing carbon dioxide, with an atomic weight of (12 + 16 × 2 = mass(CO2) = 44 kg/kmol), so kmol of CO2 is produced from the kmol present in every kilogram of coal, which once trapped in CO2 weighs approximately .

This can be used to put a carbon-cost of energy on the use of coal power. Since the useful energy output of coal is about 30% of the 6.67 kW·h/kg(coal), we can say about 2 kW·h/kg(coal) of energy is produced. Since 1 kg coal roughly translates as 1.83 kg of CO2, we can say that using electricity from coal produces CO2 at a rate of about 0.915 kg/(kW·h), or about 0.254 kg/MJ.

This estimate compares favourably with the U.S. Energy Information Agency's 1999 report on CO2 emissions for energy generation, which quotes a specific emission rate of 950 g CO2/(kW·h). By comparison, generation from oil in the U.S. was 890 g CO2/(kW·h), while natural gas was 600 g CO2/(kW·h). Estimates for specific emission from nuclear power, hydro, and wind energy vary, but are about 100 times lower. See environmental effects of nuclear power
Environmental effects of nuclear power

Nuclear power, as with all power sources, has an effect on the environment through the nuclear fuel cycle, through operation, and from the lingering effects of the Chernobyl accident....
 for estimates.

Underground fires

There are hundreds of coal fires burning around the world. Those burning underground can be difficult to locate and many cannot be extinguished. Fires can cause the ground above to subside, their combustion gases are dangerous to life, and breaking out to the surface can initiate surface wildfires. Coal seams can be set on fire by spontaneous combustion
Spontaneous combustion

Spontaneous combustion may refer to:* Spontaneous combustion, the self-ignition of a mass, for example, a pile of oily rags.* Spontaneous Combustion , a 2007 album by Liquid Trio Experiment...
 or contact with a mine fire
Mine fire

A coal seam fire or mine fire is the underground smouldering of a coal deposit, often in a coal mine. Such fires have economic, social and ecological impacts....
 or surface fire. A grass fire in a coal area can set dozens of coal seams on fire. Coal fires in China burn 109 million tons of coal a year, emitting 360 million metric tons of CO2. This contradicts the ratio of 1:1.83 given earlier, but it amounts to 2-3% of the annual worldwide production of CO2 from fossil fuels, or as much as emitted from all of the cars and light trucks in the United States. In Centralia, Pennsylvania
Centralia, Pennsylvania

Centralia is a Borough in Columbia County, Pennsylvania, United States. Its population has dwindled from over 1,000 residents in 1981 to 12 in 2005 and 9 in 2007, as a result of a mine fire burning beneath the borough since 1962....
 (a borough
Borough

A borough is an administrative division of various countries. In principle, the term borough designates a self-governing township although, in practice, official use of the term varies widely....
 located in the Coal Region
Coal Region

The Coal Region is a term used to refer to an area of Northeastern Pennsylvania in the central Appalachian Mountains comprising Lackawanna County, Pennsylvania, Luzerne County, Pennsylvania, Columbia County, Pennsylvania, Carbon County, Pennsylvania, Schuylkill County, Pennsylvania, Northumberland County, Pennsylvania, and the extreme n...
 of the United States
United States

The United States of America is a Federal government constitutional republic comprising U.S. state and a federal district. The country is situated mostly in central North America, where its Contiguous United States and Washington, D.C., the Capital districts and territories, lie between the Pacific Ocean and Atlantic Oceans, Borders of the U...
) an exposed vein of coal ignited in 1962 due to a trash fire in the borough landfill, located in an abandoned anthracite
Anthracite coal

Anthracite is a hard, compact variety of mineral coal that has a high lustre . It has the highest carbon count and contains the fewest impurities of all coals, despite its lower Heating value content....
 strip mine pit. Attempts to extinguish the fire were unsuccessful, and it continues to burn underground to this day. The Australia
Australia

Australia, officially the Commonwealth of Australia, is a country in the southern hemisphere comprising the Australia of the world's smallest continent, the major island of Tasmania, and numerous list of islands of Australia in the Indian Ocean and Pacific Oceans....
n Burning Mountain
Burning Mountain

Burning Mountain is a feature near Wingen, New South Wales, New South Wales, Australia, approximately 300km north of Sydney just off the New England Highway....
 was originally believed to be a volcano, but the smoke and ash comes from a coal fire which may have been burning for over 5,500 years.

At Kuh i Malik in Yagnob Valley, Tajikistan
Tajikistan

Tajikistan , officially the Republic of Tajikistan , is a mountainous landlocked country in Central Asia. Afghanistan borders to the south, Uzbekistan to the west, Kyrgyzstan to the north, and People's Republic of China to the east....
, coal deposits have been burning for thousands of years, creating vast underground labyrinths full of unique minerals, some of them very beautiful. Local people once used this method to mine ammoniac. This place has been well-known since the time of Herodotus
Herodotus

Herodotus of Halicarnassus was a Greeks historian who lived in the 5th century BC and is regarded as the "Father of History" in Western culture....
, but European geographers misinterpreted the Ancient Greek descriptions as the evidence of active volcanism in Turkestan
Turkestan

Turkestan is a region in Central Asia, which today is largely inhabited by Turkic peoples. It has been referenced in many Turkic and Persian sagas and is an integral part of Turan ....
 (up to the 19th century, when the Russian army invaded the area).

The reddish siltstone rock that caps many ridges and buttes in the Powder River Basin
Powder River Basin

The Powder River Basin is a region in southeast Montana and northeast Wyoming about east to west and north to south known for its coal deposits....
 (Wyoming
Wyoming

The State of Wyoming is a sparsely populated U.S. state in the Northwestern United States of the United States. The majority of the state is dominated by the mountain ranges and rangelands of the Rocky Mountains, while the easternmost section of the state is a high altitude prairie region known as the High Plains ....
), and in western North Dakota
North Dakota

North Dakota is a U.S. state located in the Midwestern United States and Western United States regions of the United States of America. North Dakota is the 19th largest state by area in the US; it is the 48th most populous, with just over 640,000 residents as of 2006....
 is called porcelanite, which also may resemble the coal burning waste "clinker" or volcanic "scoria
Scoria

Scoria is a textural term for Vesicular texturevolcanic rock. It is commonly, but not exclusively, basaltic or andesite in composition. Scoria is light as a result of numerous macroscopic ellipsoidal vesicles, but most scoria has a specific gravity greater than 1, and sinks in water....
". Clinker is rock that has been fused by the natural burning of coal. In the Powder River Basin approximately 27 to 54 billion tons of coal burned within the past three million years. Wild coal fires in the area were reported by the Lewis and Clark Expedition
Lewis and Clark Expedition

The Lewis and Clark Expedition , headed by Meriwether Lewis and William Clark , was the first United States overland expedition to the Pacific coast and back....
 as well as explorers and settlers in the area.

Production trends

Coal Mine Wyoming
In 2006, China was the top producer of coal with 38% share followed by the USA and India, reports the British Geological Survey
British Geological Survey

The British Geological Survey is a partly publicly-funded body which aims to advance geoscience knowledge of the United Kingdom landmass and its continental shelf by means of systematic surveying, monitoring and research....
.

World coal reserves


At the end of 2006 the recoverable coal reserves amounted around 800 or 900 gigatons. The United States Energy Information Administration
Energy Information Administration

The United States Energy Information Administration , created by United States Congress in 1977, is the independent statistical agency within the United States Department of Energy....
 gives world reserves as 998 billion short tons (equal to 905 gigatons), approximately half of it being hard coal. At the current production rate, this would last 164 years. At the current global total energy consumption of 15 terawatt, there is enough coal to provide the entire planet with all of its energy for 57 years.

The 998 billion tons of recoverable coal reserves estimated by the Energy Information Administration are equal to about 4,417 BBOE (billion barrels of oil equivalent
Barrel of oil equivalent

The barrel of oil equivalent is a units of energy based on the approximate energy released by burning one Barrel of crude oil. The US Internal Revenue Service defines it as equal to 5.8 ? 106 BTU....
). The amount of coal burned during 2001 was calculated as 2.337 GTOE (gigatonnes of oil equivalent), which is about 46 million barrels of oil equivalent per day. Were consumption to continue at that rate those reserves would last about 263 years As a comparison, natural gas provided 51 million barrels (oil equivalent), and oil 76 million barrels, per day during 2001.

British Petroleum, in its annual report 2007, estimated at 2006 end, there were 909,064 million tons of proven coal reserves worldwide, or 147 years reserves-to-production ratio
Reserves-to-production ratio

The Reserves-to-production ratio is the remaining amount of a Resource_depletion natural resource, expressed in years. The RPR is most commonly applied to fossil fuels....
. This figure only includes reserves classified as "proven"; exploration drilling programs by mining companies, particularly in under-explored areas, are continually providing new reserves. In many cases, companies are aware of coal deposits that have not been sufficiently drilled to qualify as "proven". However, some nations haven't updated their information and assume reserves remain at the same levels even with withdrawals.

Us Coal Regions 1996
Of the three fossil fuels coal has the most widely distributed reserves; coal is mined in over 100 countries, and on all continents except Antarctica. The largest reserves are found in the USA, Russia, Australia, China, India and South Africa.

Note the table below.

Proved recoverable coal reserves at end-2006 (million tonnes (teragrams))
CountryBituminous & anthraciteSubBituminous & ligniteTOTALShare
111,338135,305246,64327.1
49,088107,922157,01017.3
62,20052,300114,50012.6
90,0852,36092,44510.2
38,60039,90078,5008.6
48,750048,7505.4
16,27417,87934,1533.8
28,1513,12831,2793.4
14,000014,0001.5
010,11310,1131.1
1836,5566,7390.7
6,2303816,6110.7
3,4713,1076,5780.7
2,0943,4585,5520.6
7404,2284,9680.5
2783,9084,1860.5
03,9003,9000.4
1983,1593,3570.4
03,3003,3000.3
42,1832,1870.2
01,3541,3540.1
3003006000.1
335385710.1
2003305300.1
50205020.1
224724940.1
47904790.1
TOTAL 478,771430,293909,064100.0
  • Recent discoveries in the Thar region of Pakistan have given rise to a discovery of nearly 185 billion tonnes.

Major coal producers

The reserve life is an estimate based only on current production levels for the countries shown, and makes no assumptions of future production or even current production trends.
Production of Coal by Country and year (million tonnes)
Country2003200420052006ShareReserve Life (years)
1722.0 1992.3 2204.7 2380.0 38.4 % 48
972.3 1008.9 1026.5 1053.6 17.0 % 234
375.4 407.7 428.4 447.3 7.2 % 207
351.5 366.1 378.8 373.8 6.0 % 210
276.7 281.7 298.5 309.2 5.0 % 508
237.9 243.4 244.4 256.9 4.1 % 190
204.9 207.8 202.8 197.2 3.2 % 34
114.3 132.4 146.9 195.0 3.1 % 25
163.8 162.4 159.5 156.1  90
Total
Total

Total may refer to:...
 World
World

World is a common name for the planet Earth seen from a human worldview, as a place inhabited by human beings. It is often used to signify the sum of human experience and history, or the 'human condition' in general....
5187.6 5585.3 5886.7 6195.1 100 % 142


Major coal exporters

Exports of Coal by Country and year (million short tons)
Country200320042005Share
238.1 247.6 257.6 .320
107.8 131.4 147.6 .134
103.4 95.5 79.0 .098
78.7 74.9 77.5 .096
41.0 55.7 62.3 .077
43.0 48.0 49.9 .062
27.7 28.8 31.0 .039
16.4 16.3 16.4 .020
N/A 10.3 14.1 .018
Total
Total

Total may refer to:...
713.9 764.0 804.2 1


See also


Further reading


External links

  • (Japanese Coal Energy Center)
  • from the University of Wyoming
  • , Nightly Business Report