ANFO
Encyclopedia
ANFO is a widely used bulk industrial explosive mixture. It consists of 94 percent porous prilled ammonium nitrate (NH4NO3), (AN) that acts as the oxidizing agent and absorbent for the fuel — six percent Number 2 Fuel Oil (FO). Strictly speaking, compositions that do not meet the 94%AN/6%FO formulation are not ANFOs.

ANFO has found wide use in coal mining
Coal mining
The goal of coal mining is to obtain coal from the ground. Coal is valued for its energy content, and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extraction of iron from iron ore and for cement production. In the United States,...

, quarrying, metal mining
Mining
Mining is the extraction of valuable minerals or other geological materials from the earth, from an ore body, vein or seam. The term also includes the removal of soil. Materials recovered by mining include base metals, precious metals, iron, uranium, coal, diamonds, limestone, oil shale, rock...

, and civil construction in undemanding applications where the benefits of water resistance, oxygen balance, high detonation velocity, and performance in small diameters, offered by conventional industrial explosives is not outweighed by the advantages of ANFO's low cost and ease of use.

It accounts for an estimated 80% of the 6000000000 pounds (2,721,554,220 kg) of explosives used annually in North America.

The press and other media have used the term ANFO loosely and imprecisely in describing improvised explosive device
Improvised explosive device
An improvised explosive device , also known as a roadside bomb, is a homemade bomb constructed and deployed in ways other than in conventional military action...

s, in cases of fertilizer bombs.

Chemistry

ANFO under most conditions is cap-insensitive, and so it is classified as a blasting agent and not a high explosive; it decomposes through detonation
Detonation
Detonation involves a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations are observed in both conventional solid and liquid explosives, as well as in reactive gases...

 rather than deflagration
Deflagration
Deflagration is a term describing subsonic combustion that usually propagates through thermal conductivity; hot burning material heats the next layer of cold material and ignites it. Most "fire" found in daily life, from flames to explosions, is deflagration...

 with a moderate velocity of about 3,200 meters per second in 5-inch diameter, unconfined, at ambient temperature. It is a tertiary explosive consisting of distinct fuel and oxidizer phases and requires confinement for efficient detonation and brisance
Brisance
Brisance is the shattering capability of an explosive. It is a measure of the rapidity with which an explosive develops its maximum pressure. The term originates from the French verb "briser", which means to break or shatter...

. Because it is cap-insensitive, it generally requires a primer, also known as a booster
Explosive booster
An explosive booster acts as a bridge between a low energy explosive and a low sensitivity explosive such as TNT. It increases the explosive shockwave from an initiating explosive to the degree sufficient to detonate the secondary charge.Unlike C4 plastic explosive, not all explosives can be...

 (e.g., one or two sticks of dynamite
Dynamite
Dynamite is an explosive material based on nitroglycerin, initially using diatomaceous earth , or another absorbent substance such as powdered shells, clay, sawdust, or wood pulp. Dynamites using organic materials such as sawdust are less stable and such use has been generally discontinued...

, as historically used, or in more recent times, Tovex
Tovex
Tovex is a water-gel explosive composed of ammonium nitrate and methylammonium nitrate that has several advantages over traditional dynamite, including lower toxicity and safer manufacture, transport, and storage...

 or cast boosters of pentolite
Pentolite
Pentolite is a high explosive used for military and civilian purposes e.g. warheads and booster charges.Military pentolite comprises a mixture of 50% PETN and 50% TNT. A 50:50 mixture has a density of 1.65 g/cm3 and a detonation velocity of 7400 m/s. Civilian pentolite sometimes contains a lower...

 (TNT)/PETN
PETN
Pentaerythritol tetranitrate , also known as PENT, PENTA, TEN, corpent, penthrite , is the nitrate ester of pentaerythritol. Penta refers to the five carbon atoms of the neopentane skeleton.PETN is most well known as an explosive...

 or similar compositions) to ensure continuation of the detonation wave-train.

The basic chemistry of ANFO detonation is the reaction of ammonium nitrate (NH4NO3) with a long chain (hydro)carbon (CnH2n+2) to form nitrogen
Nitrogen
Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...

, carbon dioxide
Carbon dioxide
Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom...

 and water
Water
Water is a chemical substance with the chemical formula H2O. A water molecule contains one oxygen and two hydrogen atoms connected by covalent bonds. Water is a liquid at ambient conditions, but it often co-exists on Earth with its solid state, ice, and gaseous state . Water also exists in a...

. In an ideal stoichiometrically balanced reaction, ANFO is composed of approximately 94.3% AN and 5.7% FO by weight. The normal ratio recommended is 2 U.S. quart
Quart
The quart is a unit of volume equal to a quarter of a gallon, two pints, or four cups. Since gallons of various sizes have historically been in use, quarts of various sizes have also existed; see gallon for further discussion. Three of these kinds of quarts remain in current use, all approximately...

s of fuel oil per 50 pounds of ammonium nitrate (80 ml/kg). In practice, a slight excess of fuel oil is added, i.e., 2.5 to 3 quarts of fuel oil per 50 pounds of ammonium nitrate, as underdosing results in reduced performance while overdosing merely results in more post-blast fumes. When detonation conditions are optimal, the aforementioned gases are the only products. In practical use, such conditions are impossible to attain, and blasts produce moderate amounts of toxic gases such as carbon monoxide
Carbon monoxide
Carbon monoxide , also called carbonous oxide, is a colorless, odorless, and tasteless gas that is slightly lighter than air. It is highly toxic to humans and animals in higher quantities, although it is also produced in normal animal metabolism in low quantities, and is thought to have some normal...

 and oxides of nitrogen
Nitrogen oxide
Nitrogen oxide can refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds:* Nitric oxide, also known as nitrogen monoxide, , nitrogen oxide* Nitrogen dioxide , nitrogen oxide...

 (NOx
NOx
NOx is a generic term for the mono-nitrogen oxides NO and NO2 . They are produced from the reaction of nitrogen and oxygen gases in the air during combustion, especially at high temperatures...

).

Industrial use

Ammonium nitrate is widely used as a fertilizer
Fertilizer
Fertilizer is any organic or inorganic material of natural or synthetic origin that is added to a soil to supply one or more plant nutrients essential to the growth of plants. A recent assessment found that about 40 to 60% of crop yields are attributable to commercial fertilizer use...

 in the agricultural industry. In many countries its purchase and use is restricted to buyers who have obtained the proper licence. This restriction is primarily because it is an attractive and simple component used in the production of fertilizer bombs.

In the mining industry, the term ANFO specifically describes a mixture of solid ammonium nitrate prill
Prill
A prill is a small aggregate of a material, most often a dry sphere, formed from a melted liquid. The material to be prilled must be a solid at room temperature and a low viscosity liquid when melted. Prills are formed by allowing drops of the melted prill substance to congeal or freeze in mid-air...

s and heating oil. In this form, it has a bulk density
Bulk density
Bulk density is a property of powders, granules and other "divided" solids, especially used in reference to mineral components , chemical substances, ingredients, foodstuff or any other masses of corpuscular or particulate matter. It is defined as the mass of many particles of the material...

 of approximately 840 kg/m3. The density of individual prills is about 1300 kg/m3, while the density of pure crystalline ammonium nitrate is 1700 kg/m3. AN prills used for explosive applications are physically different from fertilizer prills; the former contain approximately 20% air. These versions of ANFO which use prills are generally called explosives grade, low density, or industrial grade ammonium nitrate. These voids are necessary to sensitize ANFO: they create so-called "hot spots". Finely powdered aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

 can be added to ANFO to increase both sensitivity and energy; however, this has fallen out of favor due to cost. Other additions include perlite
Perlite
Perlite is an amorphous volcanic glass that has a relatively high water content, typically formed by the hydration of obsidian. It occurs naturally and has the unusual property of greatly expanding when heated sufficiently...

, chemical gassing agents, or glass air bubbles to create these voids.

AN is highly hygroscopic, readily absorbing water from air. It is dangerous when stored in humid environments, as any absorbed water interferes with its explosive function. AN is also water soluble. When used in wet mining conditions, considerable effort must be taken to dewater borehole
Borehole
A borehole is the generalized term for any narrow shaft bored in the ground, either vertically or horizontally. A borehole may be constructed for many different purposes, including the extraction of water or other liquid or gases , as part of a geotechnical investigation, environmental site...

s.

Other explosives based on the ANFO chemistry exist; the most commonly used are emulsion
Emulsion
An emulsion is a mixture of two or more liquids that are normally immiscible . Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion is used when both the dispersed and the...

s. They differ from ANFO in the physical form the reactants take. The most notable properties of emulsions are water resistance and higher bulk density.

The popularity of ANFO is largely attributable to its low cost and high stability. In most jurisdictions, ammonium nitrate need not be classified as an explosive for transport purposes; it is merely an oxidizer. Many mines prepare ANFO on-site using the same diesel fuel that powers their vehicles, although heating oil, which is nearly identical, may cost less than diesel fuel due to lower fuel tax
Fuel tax
A fuel tax is an excise tax imposed on the sale of fuel. In most countries the fuel tax is imposed on fuels which are intended for transportation...

. Many fuels can theoretically be used; the low volatility and cost of fuel oil makes it ideal.

Disasters

Unmixed ammonium nitrate can decompose explosively and has been responsible for industrial disasters, such as the Texas City disaster
Texas City Disaster
The Texas City Disaster was the deadliest industrial accident in U.S. history. The incident took place on April 16, 1947, and began with a mid-morning fire on board the French-registered vessel SS Grandcamp which was docked in the Port of Texas City...

 in Texas City
Texas City, Texas
Texas City is a city in Chambers and Galveston counties in the U.S. state of Texas. The population was 41,521 at the 2000 census. It is a part of the Houston–Sugar Land–Baytown, Texas Metropolitan Statistical Area.-History:...

 in 1947 and the Ryongchon disaster
Ryongchon disaster
The Ryongchŏn disaster was a train disaster that occurred in the town of Ryongchŏn, North Korea, near the border with the People's Republic of China on April 22, 2004....

 in North Korea
North Korea
The Democratic People’s Republic of Korea , , is a country in East Asia, occupying the northern half of the Korean Peninsula. Its capital and largest city is Pyongyang. The Korean Demilitarized Zone serves as the buffer zone between North Korea and South Korea...

 in 2004.

Terrorist use

Variants of ANFO have been used in terrorist bombings. First used in 1970 by student protesters at the University of Wisconsin–Madison
University of Wisconsin–Madison
The University of Wisconsin–Madison is a public research university located in Madison, Wisconsin, United States. Founded in 1848, UW–Madison is the flagship campus of the University of Wisconsin System. It became a land-grant institution in 1866...

, who learned how to make and use ANFO from a Wisconsin Conservation Department booklet entitled Pothole Blasting for Wildlife, the ANFO car bomb
Car bomb
A car bomb, or truck bomb also known as a Vehicle Borne Improvised Explosive Device , is an improvised explosive device placed in a car or other vehicle and then detonated. It is commonly used as a weapon of assassination, terrorism, or guerrilla warfare, to kill the occupants of the vehicle,...

 was adopted by the Provisional IRA in 1972 and used for the 1993 Bishopsgate bombing
1993 Bishopsgate bombing
The Bishopsgate bombing occurred on 24 April 1993, when the Provisional Irish Republican Army detonated a truck bomb in London's financial district in Bishopsgate, City of London, England. One person was killed in the explosion and 44 injured, and damage initially estimated at £1 billion was caused...

. It has also seen use by groups such as the Revolutionary Armed Forces of Colombia
Revolutionary Armed Forces of Colombia
The Revolutionary Armed Forces of Colombia – People's Army is a Marxist–Leninist revolutionary guerrilla organization based in Colombia which is involved in the ongoing Colombian armed conflict, currently involved in drug dealing and crimes against the civilians..FARC-EP is a peasant army which...

 (FARC), ETA
ETA
ETA , an acronym for Euskadi Ta Askatasuna is an armed Basque nationalist and separatist organization. The group was founded in 1959 and has since evolved from a group promoting traditional Basque culture to a paramilitary group with the goal of gaining independence for the Greater Basque Country...

, and Ramzi Yousef
Ramzi Yousef
Ramzi Yousef was one of the main perpetrators of the 1993 World Trade Center bombing and a co-conspirator in the Bojinka plot. In 1995, he was arrested at a guest house in Islamabad, by the Pakistani Inter-Services Intelligence and United States Diplomatic Security Service, then extradited to the...

's terrorists when they first tried to destroy the World Trade Center in 1993. A more sophisticated variant of ANFO (ammonium nitrate with nitromethane as the fuel called ANNM) was used in the 1995 Oklahoma City bombing
Oklahoma City bombing
The Oklahoma City bombing was a terrorist bomb attack on the Alfred P. Murrah Federal Building in downtown Oklahoma City on April 19, 1995. It was the most destructive act of terrorism on American soil until the September 11, 2001 attacks. The Oklahoma blast claimed 168 lives, including 19...

. Improvised bombs made with agricultural-grade AN are less sensitive and less efficient than the explosive-grade variety.

In November 2009, a ban on ammonium sulfate
Ammonium sulfate
Ammonium sulfate , 2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen as ammonium cations, and 24% sulfur as sulfate anions...

, ammonium nitrate and calcium ammonium nitrate
Calcium ammonium nitrate
Calcium ammonium nitrate, often abbreviated CAN, is a fertilizer which is a blend of about 20%-30% CaCO3 and 70%-80% Ammonium nitrate. It is used as a general plant fertilizer. It is an example for nitrogenous fertiliser.-References:Ammonium nitrate...

 fertilizers was imposed in the former Malakand Division
Malakand Division
Malakand Division was an administrative division of the North West Frontier Province of Pakistan, until the reforms of 2000 abolished the third tier of government....

 - comprising the Upper Dir, Lower Dir, Swat, Chitral
Chitral
Chitral or Chetrar , translated as field in the native language Khowar, is the capital of the Chitral District, situated on the western bank of the Kunar River , in Pakistan. The town is at the foot of Tirich Mir, the highest peak of the Hindu Kush, high...

 and Malakand
Malakand District
Malakand District is a district of the province of Khyber Pakhtunkhwa in Pakistan.The District was formed in 1970 as a Provincially Administered Tribal Area, It had previously been a Tribal Area known as the Malakand Protected Area, part of the Malakand Agency...

 districts of the North West Frontier Province (NWFP) of Pakistan
Pakistan
Pakistan , officially the Islamic Republic of Pakistan is a sovereign state in South Asia. It has a coastline along the Arabian Sea and the Gulf of Oman in the south and is bordered by Afghanistan and Iran in the west, India in the east and China in the far northeast. In the north, Tajikistan...

, by the NWFP government, following reports that those chemicals were used by militants to make explosives.

In April 2010, police in Greece confiscated 180 kilograms of ANFO and other related material stashed in a hideaway in the Athens suburb of Kareas. The material was believed to be linked to attacks previously carried out by the "Revolutionary Struggle" terrorist group.

In January 2010, President Hamid Karzai
Hamid Karzai
Hamid Karzai, GCMG is the 12th and current President of Afghanistan, taking office on 7 December 2004. He became a dominant political figure after the removal of the Taliban regime in late 2001...

 of Afghanistan
Afghanistan
Afghanistan , officially the Islamic Republic of Afghanistan, is a landlocked country located in the centre of Asia, forming South Asia, Central Asia and the Middle East. With a population of about 29 million, it has an area of , making it the 42nd most populous and 41st largest nation in the world...

 also issued a decree banning the use, production, storage, purchase or sale of ammonium nitrate, after an investigation showed that militants in the Taliban insurgency
Taliban insurgency
The Taliban insurgency took root shortly after the group's fall from power following the 2001 war in Afghanistan. The Taliban continue to attack Afghan, U.S., and other ISAF troops and many terrorist incidents attributable to them have been registered. The war has also spread over the southern and...

 had used the substance in bomb attacks.

On July 22. 2011, an aluminium
Aluminium
Aluminium or aluminum is a silvery white member of the boron group of chemical elements. It has the symbol Al, and its atomic number is 13. It is not soluble in water under normal circumstances....

-powder enriched ANNM explosive, with total size of 950 kg (150 kg of aluminum powder), increasing demolition power by 10-30 percent over plain ANFO, was used in the Oslo bombing
2011 Norway attacks
The 2011 Norway attacks were two sequential terrorist attacks against the government, the civilian population and a summer camp in Norway on 22 July 2011....

.

ANNM

ANNM, or Ammonium Nitrate and Nitromethane
Nitromethane
Nitromethane is an organic compound with the chemical formula . It is the simplest organic nitro compound. It is a slightly viscous, highly polar liquid commonly used as a solvent in a variety of industrial applications such as in extractions, as a reaction medium, and as a cleaning solvent...

, is one of the most powerful improvised types of AN-based explosives. The relative effectiveness factor
Relative effectiveness factor
Relative effectiveness factor or R.E. factor is a measurement of an explosive's power for military demolitions purposes. It is used to compare an explosive's effectiveness relative to TNT by weight only. This enables engineers to substitute one explosive for another when they are calculating...

 of ANNM varies depending on the mix but does not exceed 1 (annmal = RE 1-1.1). ANNM usually contains a 60:40 (kinepak) mix of AN and NM (60% ammonium nitrate, 40% nitromethane by mass), though this results in a wet slurry. Sometimes more AN is added to reduce liquidity and make it easier to store and handle, as well as providing an oxygen-balanced mix. ANNM is also more sensitive to shock than standard ANFO and is therefore easier to detonate. When ANNM detonates, the primary byproducts produced are H2O, CO2 and N2, but NOx and other toxic gases are inevitably formed because of a negative oxygen balance. The balanced equation is as follows:

3NH4NO3 + 2CH3NO2 -> 4N2 + 2CO2 + 9H2O

However, depending on the detonation impetus (for example a #6 versus a #10 detonator
Detonator
A detonator is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the latter two being the most common....

), the products of the detonation can be decidedly unstoichiometric.

External links

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