Trisaccharides
Encyclopedia
Trisaccharides are oligosaccharide
Oligosaccharide
An oligosaccharide is a saccharide polymer containing a small number of component sugars, also known as simple sugars...

s composed of three monosaccharide
Monosaccharide
Monosaccharides are the most basic units of biologically important carbohydrates. They are the simplest form of sugar and are usually colorless, water-soluble, crystalline solids. Some monosaccharides have a sweet taste. Examples of monosaccharides include glucose , fructose , galactose, xylose...

s with two glycosidic bonds connecting them. Similar to the disaccharide
Disaccharide
A disaccharide or biose is the carbohydrate formed when two monosaccharides undergo a condensation reaction which involves the elimination of a small molecule, such as water, from the functional groups only. Like monosaccharides, disaccharides form an aqueous solution when dissolved in water...

s, each glycosidic bond can be formed between any hydroxyl group on the component monosaccharides. Even if all three component sugars are the same (e.g., glucose
Glucose
Glucose is a simple sugar and an important carbohydrate in biology. Cells use it as the primary source of energy and a metabolic intermediate...

), different bond combinations (regiochemistry) and stereochemistry (alpha- or beta-) result in triaccharides that are diastereoisomers with different chemical and physical properties.

Examples

Trisaccharide Unit 1 Bond Unit 2 Bond Unit 3
>-
| Isomaltotriose 
glucose α(1→6) glucose α(1→6) >-
| Nigerotriose 
glucose
Glucose
Glucose is a simple sugar and an important carbohydrate in biology. Cells use it as the primary source of energy and a metabolic intermediate...

 
α(1→3) glucose α(1→3) >-
| Maltotriose
Maltotriose
Maltotriose is a trisaccharide consisting of three glucose molecules linked with α-1,4 glycosidic bonds.It is most commonly produced by the digestive enzyme alpha-amylase on amylose in starch...

 
glucose α(1→4) glucose α(1→4) glucose
| α(1→3) >-
| Maltotriulose 
glucose α(1→4) glucose α(1→4) >-
| Raffinose
Raffinose
Raffinose is a trisaccharide composed of galactose, fructose, and glucose. It can be found in beans, cabbage, brussels sprouts, broccoli, asparagus, other vegetables, and whole grains. Raffinose can be hydrolyzed to D-galactose and sucrose by the enzyme α-galactosidase , an enzyme not found in the...

 
galactose
Galactose
Galactose , sometimes abbreviated Gal, is a type of sugar that is less sweet than glucose. It is a C-4 epimer of glucose....

α(1→6) glucose β(1→2) >-
(1→2)
fructose β(1→2) fructose
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