Titanium(III) phosphide
Encyclopedia
Titanium phosphide (TiP) is an inorganic chemical compound of titanium
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. It has a low density and is a strong, lustrous, corrosion-resistant transition metal with a silver color....

 and phosphorus
Phosphorus
Phosphorus is the chemical element that has the symbol P and atomic number 15. A multivalent nonmetal of the nitrogen group, phosphorus as a mineral is almost always present in its maximally oxidized state, as inorganic phosphate rocks...

. Normally encountered as a grey powder, it is high melting and a metallic conductor. It is not attacked by common acids or water. Its physical properties stand in contrast to the group 1 and group 2 phosphides that contain the P3 anion (such as Na3P
Sodium phosphide
Sodium phosphide, Na3P, is a black, ionic salt containing the alkali metal sodium and the phosphide anion. Na3P is a source of the highly reactive phosphide anion...

), which are not metallic and are readily hydrolysed. Titanium phosphide is classified as a "metal-rich phosphide", where extra valence electrons from the metal are delocalised.

Titanium phosphide can be prepared by the reaction of TiCl4 and PH3.

There are other titanium phosphide phases, including Ti3P, Ti2P, Ti7P4, Ti5P3, and Ti4P3.

Titanium phosphide should not be confused with titanium phosphate or titanium isopropoxide, both of which are sometimes known by the acronym TIP.
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