Nitrosonium octafluoroxenate(VI)
Encyclopedia
Nitrosonium octafluoroxenate(VI) is a chemical compound
Chemical compound
A chemical compound is a pure chemical substance consisting of two or more different chemical elements that can be separated into simpler substances by chemical reactions. Chemical compounds have a unique and defined chemical structure; they consist of a fixed ratio of atoms that are held together...

 of xenon
Xenon
Xenon is a chemical element with the symbol Xe and atomic number 54. The element name is pronounced or . A colorless, heavy, odorless noble gas, xenon occurs in the Earth's atmosphere in trace amounts...

 with nitrogen
Nitrogen
Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless, and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere...

, oxygen
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

, and fluorine
Fluorine
Fluorine is the chemical element with atomic number 9, represented by the symbol F. It is the lightest element of the halogen column of the periodic table and has a single stable isotope, fluorine-19. At standard pressure and temperature, fluorine is a pale yellow gas composed of diatomic...

, having formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 . It is an ionic compound containing well-separated nitrosonium
Nitrosonium
The nitrosonium ion is NO+, in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. This ion is usually obtained as the following salts: NOClO4, NOSO4H , and NOBF4. The ClO and BF salts are slightly soluble in CH3CN...

 cations (NO+) and octafluoroxenate(VI) anions (XeF). The molecular geometry
Molecular geometry
Molecular geometry or molecular structure is the three-dimensional arrangement of the atoms that constitute a molecule. It determines several properties of a substance including its reactivity, polarity, phase of matter, color, magnetism, and biological activity.- Molecular geometry determination...

 of the octafluoroxenate(VI) ion is square antiprism
Square antiprism
In geometry, the square antiprism is the second in an infinite set of antiprisms formed by an even-numbered sequence of triangle sides closed by two polygon caps...

atic, having Xe-F bond lengths of 1.971 Å
Ångström
The angstrom or ångström, is a unit of length equal to 1/10,000,000,000 of a meter . Its symbol is the Swedish letter Å....

, 1.946 Å, 1.958 Å, 2.052 Å, and 2.099 Å.

It is synthesized by the reaction of xenon hexafluoride
Xenon hexafluoride
Xenon hexafluoride is a noble gas compound with the formula XeF6 and the highest of the three binary fluorides of xenon, the other two being XeF2 and XeF4. All are exergonic and stable at normal temperatures. XeF6 is the strongest fluorinating agent of the series...

  with nitrosyl fluoride
Nitrosyl fluoride
Nitrosyl fluoride, NOF, is a covalently bonded nitrosyl compound.-Reactions:NOF is a highly reactive fluorinating agent that converts many metals to their fluorides, releasing nitric oxide:...

 (NOF):
+ 2 NOF →


Other compounds containing the octafluoroxenate(VI) ion include its alkali metal salts, including Cs2XeF8 and Rb2XeF8, which are stable up to 400°C.
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