Manganese(II) nitrate
Encyclopedia
Manganese nitrate is an inorganic compound
Inorganic compound
Inorganic compounds have traditionally been considered to be of inanimate, non-biological origin. In contrast, organic compounds have an explicit biological origin. However, over the past century, the classification of inorganic vs organic compounds has become less important to scientists,...

 with formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 Mn
Manganese
Manganese is a chemical element, designated by the symbol Mn. It has the atomic number 25. It is found as a free element in nature , and in many minerals...

(NO3
Nitrate
The nitrate ion is a polyatomic ion with the molecular formula NO and a molecular mass of 62.0049 g/mol. It is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically-bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a...

)2. Each formula unit
Formula unit
A formula unit in chemistry is the empirical formula of an ionic or covalent network solid compound used as an independent entity for stoichiometric calculations. It is the lowest whole number ratio of ions represented in an ionic compound...

 is composed of one Mn2+ cation and two NO3-
Nitrate
The nitrate ion is a polyatomic ion with the molecular formula NO and a molecular mass of 62.0049 g/mol. It is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically-bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a...

 anions and varying amounts of water. Most common is the tetrahydrate Mn(NO3)2·4H2O, but mono- and hexahydrates are also known as well as the anhydrous
Anhydrous
As a general term, a substance is said to be anhydrous if it contains no water. The way of achieving the anhydrous form differs from one substance to another...

 compound. Some of these compounds are useful precursors to the oxides of manganese.

Preparation

Manganese(II) nitrate can be prepared by dissolving manganese(II) carbonate
Manganese(II) carbonate
Manganese carbonate is a compound with the chemical formula MnCO3. Manganese carbonate occurs naturally as the mineral rhodochrosite. Approximately 20,000 metric tonnes were produced in 2005.-Production and uses:...

 in dilute nitric acid
Nitric acid
Nitric acid , also known as aqua fortis and spirit of nitre, is a highly corrosive and toxic strong acid.Colorless when pure, older samples tend to acquire a yellow cast due to the accumulation of oxides of nitrogen. If the solution contains more than 86% nitric acid, it is referred to as fuming...

:
MnCO3 + 2 HNO3 → Mn(NO3)2 + H2O + CO2

It can also be prepared from MnO2 and nitrogen dioxide.
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