Formula unit
Encyclopedia
A formula unit in chemistry
Chemistry
Chemistry is the science of matter, especially its chemical reactions, but also its composition, structure and properties. Chemistry is concerned with atoms and their interactions with other atoms, and particularly with the properties of chemical bonds....

 is the empirical formula
Empirical formula
In chemistry, the empirical formula of a chemical compound is the simplest positive integer ratio of atoms of each element present in a compound. An empirical formula makes no reference to isomerism, structure, or absolute number of atoms. The empirical formula is used as standard for most ionic...

 of an ionic
Ionic compound
In chemistry, an ionic compound is a chemical compound in which ions are held together in a lattice structure by ionic bonds. Usually, the positively charged portion consists of metal cations and the negatively charged portion is an anion or polyatomic ion. Ions in ionic compounds are held together...

 or covalent network solid
Network solid
A network solid or covalent network solid is a chemical compound in which the atoms are bonded by covalent bonds in a continuous network. In a network solid there are no individual molecules and the entire crystal may be considered a macromolecule...

 compound used as an independent entity for stoichiometric calculations. It is the lowest whole number ratio of ions represented in an ionic compound. Examples include ionic NaCl and K2O and covalent networks such as SiO2 and C (as diamond
Diamond
In mineralogy, diamond is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions...

 or graphite
Graphite
The mineral graphite is one of the allotropes of carbon. It was named by Abraham Gottlob Werner in 1789 from the Ancient Greek γράφω , "to draw/write", for its use in pencils, where it is commonly called lead . Unlike diamond , graphite is an electrical conductor, a semimetal...

).

Ionic compounds do not exist as individual molecules; a formula unit thus indicates the lowest reduced ratio of ions in the compound.

A formula unit shows the kinds and numbers of atoms in the smallest representative unit of a substance.
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