Isotopes of germanium
Encyclopedia
Germanium
Germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. The isolated element is a semiconductor, with an appearance most similar to elemental silicon....

(Ge) has five naturally occurring isotope
Isotope
Isotopes are variants of atoms of a particular chemical element, which have differing numbers of neutrons. Atoms of a particular element by definition must contain the same number of protons but may have a distinct number of neutrons which differs from atom to atom, without changing the designation...

s, 70Ge, 72Ge, 73Ge, 74Ge, and 76Ge. Of these, 76Ge is very slightly radioactive, decaying by double beta decay
Double beta decay
Double beta decay is a radioactive decay process where a nucleus releases two beta rays as a single process.In double-beta decay, two neutrons in the nucleus are converted to protons, and two electrons and two electron antineutrinos are emitted...

 with a half-life
Half-life
Half-life, abbreviated t½, is the period of time it takes for the amount of a substance undergoing decay to decrease by half. The name was originally used to describe a characteristic of unstable atoms , but it may apply to any quantity which follows a set-rate decay.The original term, dating to...

 of 1.78 × 1021 years (130 million million times the age of the universe), giving it the distinction of being the nuclide with the longest directly measured half-life (tellurium-128 has a half-life > 1000 times longer, but it has been indirectly measured by decay products in ancient rocks).

Stable 74Ge is the most common isotope, having a natural abundance
Natural abundance
In chemistry, natural abundance refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass of these isotopes is the atomic weight listed for the element in the periodic table...

 of approximately 36%. 76Ge is the least common with a natural abundance of approximately 7%. When bombarded with alpha particles, the isotopes 72Ge and 76Ge will generate stable 75As and 77Se, releasing high energy electrons in the process.

At least 27 radioisotopes have also been synthesized ranging in atomic mass from 58 to 89. The most stable of these is 68Ge, decaying by electron capture
Electron capture
Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino...

 with a half-life of 270.95 d. It decays to the medically useful positron-emitting isotope 68Ga. (See gallium-68 generator
Gallium-68 generator
A gallium-68 generator is a device used to extract the positron-emitting isotope 68Ga of gallium from a source of decaying germanium-68. The parent isotope 68Ge has a half-life of 271 days and can be easily sent to hospitals within the generator, where it is storable for almost a year...

 for notes on the source of this isotope, and its medical use). The least stable known germanium stable is 60Ge with a half-life of 30 ms.

While most of germanium's radioisotopes decay by beta decay
Beta decay
In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a...

, 61Ge and 64Ge decay by β+
Positron emission
Positron emission or beta plus decay is a type of beta decay in which a proton is converted, via the weak force, to a neutron, releasing a positron and a neutrino....

 delayed proton emission
Proton emission
Proton emission is a type of radioactive decay in which a proton is ejected from a nucleus. Proton emission can occur from high-lying excited states in a nucleus following a beta decay, in which case the process is known as beta-delayed proton emission, or can occur from the ground state of very...

. 84Ge through 87Ge also have minor β-
Beta decay
In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a...

 delayed neutron emission
Neutron emission
Neutron emission is a type of radioactive decay of atoms containing excess neutrons, in which a neutron is simply ejected from the nucleus. Two examples of isotopes which emit neutrons are helium-5 and beryllium-13...

 decay paths.


Standard atomic mass: 72.64(1) u

Table

nuclide
symbol
Z(p
Proton
The proton is a subatomic particle with the symbol or and a positive electric charge of 1 elementary charge. One or more protons are present in the nucleus of each atom, along with neutrons. The number of protons in each atom is its atomic number....

)
N(n
Neutron
The neutron is a subatomic hadron particle which has the symbol or , no net electric charge and a mass slightly larger than that of a proton. With the exception of hydrogen, nuclei of atoms consist of protons and neutrons, which are therefore collectively referred to as nucleons. The number of...

)
 
isotopic mass (u)
 
half-lifeBold for isotopes with half-lives longer than the age of the universe (nearly stable) decay
mode(s)Abbreviations:
EC: Electron capture
Electron capture
Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino...


IT: Isomeric transition
Isomeric transition
An isomeric transition is a radioactive decay process that involves emission of a gamma ray from an atom where the nucleus is in an excited metastable state, referred to in its excited state, as a nuclear isomer....

daughter
isotope(s)Bold for stable isotopes
nuclear
spin
representative
isotopic
composition
(mole fraction)
range of natural
variation
(mole fraction)
excitation energy
58Ge 32 26 57.99101(34)# 2p
Proton decay
In particle physics, proton decay is a hypothetical form of radioactive decay in which the proton decays into lighter subatomic particles, such as a neutral pion and a positron...

56Zn 0+
59Ge 32 27 58.98175(30)# 2p 57Zn 7/2-#
60Ge 32 28 59.97019(25)# 30# ms β+
Beta decay
In nuclear physics, beta decay is a type of radioactive decay in which a beta particle is emitted from an atom. There are two types of beta decay: beta minus and beta plus. In the case of beta decay that produces an electron emission, it is referred to as beta minus , while in the case of a...

60Ga 0+
2p 58Zn
61Ge 32 29 60.96379(32)# 39(12) ms β+, p (80%) 60Zn (3/2-)#
β+ (20%) 61Ga
62Ge 32 30 61.95465(15)# 129(35) ms β+ 62Ga 0+
63Ge 32 31 62.94964(21)# 142(8) ms β+ 63Ga (3/2-)#
64Ge 32 32 63.94165(3) 63.7(25) s β+ 64Ga 0+
65Ge 32 33 64.93944(11) 30.9(5) s β+ (99.99%) 65Ga (3/2)-
β+, p (.01%) 64Zn
66Ge 32 34 65.93384(3) 2.26(5) h β+ 66Ga 0+
67Ge 32 35 66.932734(5) 18.9(3) min β+ 67Ga 1/2-
67m1Ge 18.20(5) keV 13.7(9) µs 5/2-
67m2Ge 751.70(6) keV 110.9(14) ns 9/2+
68GeUsed to generate
Gallium-68 generator
A gallium-68 generator is a device used to extract the positron-emitting isotope 68Ga of gallium from a source of decaying germanium-68. The parent isotope 68Ge has a half-life of 271 days and can be easily sent to hospitals within the generator, where it is storable for almost a year...

 68Ga
32 36 67.928094(7) 270.95(16) d EC
Electron capture
Electron capture is a process in which a proton-rich nuclide absorbs an inner atomic electron and simultaneously emits a neutrino...

68Ga 0+
69Ge 32 37 68.9279645(14) 39.05(10) h β+ 69Ga 5/2-
69m1Ge 86.765(14) keV 5.1(2) µs 1/2-
69m2Ge 397.944(18) keV 2.81(5) µs 9/2+
70Ge 32 38 69.9242474(11) Stable 0+ 0.2038(18)
71Ge 32 39 70.9249510(11) 11.43(3) d EC 71Ga 1/2-
71mGe 198.367(10) keV 20.40(17) ms IT
Isomeric transition
An isomeric transition is a radioactive decay process that involves emission of a gamma ray from an atom where the nucleus is in an excited metastable state, referred to in its excited state, as a nuclear isomer....

71Ge 9/2+
72Ge 32 40 71.9220758(18) Stable 0+ 0.2731(26)
72mGe 691.43(4) keV 444.2(8) ns 0+
73Ge 32 41 72.9234589(18) Stable 9/2+ 0.0776(8)
73m1Ge 13.2845(15) keV 2.92(3) µs 5/2+
73m2Ge 66.726(9) keV 499(11) ms 1/2-
74Ge 32 42 73.9211778(18) Stable 0+ 0.3672(15)
75Ge 32 43 74.9228589(18) 82.78(4) min β- 75As 1/2-
75m1Ge 139.69(3) keV 47.7(5) s IT (99.97%) 75Ge 7/2+
β- 75As
75m2Ge 192.18(7) keV 216(5) ns 5/2+
76GePrimordial
Primordial nuclide
In geochemistry and geonuclear physics, primordial nuclides or primordial isotopes are nuclides found on the earth that have existed in their current form since before Earth was formed. Only 288 such nuclides are known...

 radionuclide
Radionuclide
A radionuclide is an atom with an unstable nucleus, which is a nucleus characterized by excess energy available to be imparted either to a newly created radiation particle within the nucleus or to an atomic electron. The radionuclide, in this process, undergoes radioactive decay, and emits gamma...

32 44 75.9214026(18) 1.78(8)×1021 aLongest directly measured half-life
Half-life
Half-life, abbreviated t½, is the period of time it takes for the amount of a substance undergoing decay to decrease by half. The name was originally used to describe a characteristic of unstable atoms , but it may apply to any quantity which follows a set-rate decay.The original term, dating to...

 of all known radioisotopes
β-β- 76Se 0+ 0.0783(7)
77Ge 32 45 76.9235486(18) 11.30(1) h β- 77As 7/2+
77mGe 159.70(10) keV 52.9(6) s β- (79%) 77As 1/2-
IT (21%) 77Ge
78Ge 32 46 77.922853(4) 88(1) min β- 78As 0+
79Ge 32 47 78.9254(1) 18.98(3) s β- 79As (1/2)-
79mGe 185.95(4) keV 39.0(10) s β- (96%) 79As (7/2+)#
IT (4%) 79Ge
80Ge 32 48 79.92537(3) 29.5(4) s β- 80As 0+
81Ge 32 49 80.92882(13) 7.6(6) s β- 81As 9/2+#
81mGe 679.13(4) keV 7.6(6) s β- (99%) 81As (1/2+)
IT (1%) 81Ge
82Ge 32 50 81.92955(26) 4.55(5) s β- 82As 0+
83Ge 32 51 82.93462(21)# 1.85(6) s β- 83As (5/2+)#
84Ge 32 52 83.93747(32)# 0.947(11) s β- (89.2%) 84As 0+
β-, n (10.8%) 83As
85Ge 32 53 84.94303(43)# 535(47) ms β- (86%) 85As 5/2+#
β-, n (14%) 84As
86Ge 32 54 85.94649(54)# >150 ns β-, n 85As 0+
β- 86As
87Ge 32 55 86.95251(54)# 0.14# s 5/2+#
88Ge 32 56 87.95691(75)# >=300 ns 0+
89Ge 32 57 88.96383(97)# >150 ns 3/2+#

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