Corkite
Encyclopedia
Corkite is a phosphate mineral in the beudantite
Beudantite
Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe36SO4AsO4....

 subgroup of the alunite
Alunite
Alunite is a sulfate mineral that was first observed in the 15th century in Monti della Tolfa, north of Rome, where it was mined for the manufacture of alum. First called aluminilite by J.C. Delamétherie in 1797, this name was contracted by François Beudant in 1824 to alunite.Distinct crystals of...

 group. Corkite is the phosphate analogue of beudantite and with it, a complete solid solution
Solid solution
A solid solution is a solid-state solution of one or more solutes in a solvent. Such a mixture is considered a solution rather than a compound when the crystal structure of the solvent remains unchanged by addition of the solutes, and when the mixture remains in a single homogeneous phase...

 range exists. Corkite will also form a solid solution with kintoreite.

Corkite is named after County Cork
County Cork
County Cork is a county in Ireland. It is located in the South-West Region and is also part of the province of Munster. It is named after the city of Cork . Cork County Council is the local authority for the county...

, Ireland
Ireland
Ireland is an island to the northwest of continental Europe. It is the third-largest island in Europe and the twentieth-largest island on Earth...

; the location where the first notable amount was discovered in 1869. Like many of the other minerals in the beudantite group, corkite is a relatively uncommon, secondary mineral that occurs in oxidation zones near hydrothermal base metal
Base metal
In chemistry, the term base metal is used informally to refer to a metal that oxidizes or corrodes relatively easily, and reacts variably with diluted hydrochloric acid to form hydrogen. Examples include iron, nickel, lead and zinc...

 deposits. It occurs associated with pyromorphite
Pyromorphite
Pyromorphite is a mineral species composed of lead chlorophosphate: Pb53Cl, sometimes occurring in sufficient abundance to be mined as an ore of lead. Crystals are common, and have the form of a hexagonal prism terminated by the basal planes, sometimes combined with narrow faces of a hexagonal...

, malachite
Malachite
Malachite is a copper carbonate mineral, with the formula Cu2CO32. This green-colored mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses. Individual crystals are rare but do occur as slender to acicular prisms...

, plumbojarosite, limonite
Limonite
Limonite is an ore consisting in a mixture of hydrated iron oxide-hydroxide of varying composition. The generic formula is frequently written as FeO·nH2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.Together with hematite, it has...

  and quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

.
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