Tenmoku
Encyclopedia
Tenmoku is a dark glaze with a surface that resembles oilspotting.
It is made of feldspar
, limestone, and iron oxide
. The more quickly a piece is cooled, the blacker the glaze will be. Tenmoku takes its name from the 天目 (Mandarin
: tiān mù; ; Heaven's Eye) mountain temple in China
where iron-glazed bowls were used for tea.
Tenmoku's are known for their variability. During their heating and cooling, several factors influence the formation of iron crystals within the glaze. A long firing process and a claybody which is also heavily colored with iron increase the opportunity for iron from the clay to be drawn into the glaze. While the glaze is molten, iron can migrate within the glaze to form surface crystals, as in the "oil spot" glaze, or remain in solution deeper within the glaze for a rich glossy color.
Today, most potters are familiar with tenmoku glaze in a reduction firing. But to get oil spot effects, stiff tenmokus need to be fired in oxidation. This relies on a very simple chemical principle that, once understood, can lead to many successful firings. Red iron oxide (Fe2O3) acts as a refractory in oxidation but it can easily be changed to a flux in the form of black iron oxide (FeO), in reduction. Most potters are familiar with this property but for oil spots, we are interested in iron’s ability to self-reduce. At approximately cone 7 (2250°F or 1232°C), ferric iron (Fe2O3) cannot maintain its trigonal crystalline structure and rearranges to a cubic structure, magnetite (Fe3O4), which further reduces to become ferrous (FeO). This is called thermal reduction, and what this means in layman’s terms is that, when it is sufficiently heated, the red iron oxide used in the glaze recipe will naturally let go of an oxygen atom. As the liberated oxygen bubbles rise to the surface of the glaze, they drag a bit of the magnetite with them and deposit it on the surface. A rough black spot is left on the glaze surface that is a different color than the surrounding glaze, due to the larger concentration of iron oxide in that small area and its subsequent re-oxidization during cooling.
1
A longer cooling time allows for maximum surface crystals. Potters can "fire down" a kiln to help achieve this effect. During a normal firing, the kiln is slowly brought to a maximum temperature by adding fuel, then fueling is stopped and the kiln is allowed to cool slowly by losing heat to the air around it. To fire down a kiln, the potter continues to add a limited amount of fuel after the maximum temperature is reached to slow the cooling process and keep the glazes molten for as long as possible.
Tenmoku glazes can range in color from dark plum (persimmon), to yellow, to brown, to black.
"The Complete Guide to High Fire Glazes", John Britt, Lark Books 2004, Oil Spot Glazes page 75 - 77.
It is made of feldspar
Feldspar
Feldspars are a group of rock-forming tectosilicate minerals which make up as much as 60% of the Earth's crust....
, limestone, and iron oxide
Iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides.Iron oxides and oxide-hydroxides are widespread in nature, play an important role in many geological and biological processes, and are widely utilized by humans, e.g.,...
. The more quickly a piece is cooled, the blacker the glaze will be. Tenmoku takes its name from the 天目 (Mandarin
Standard Mandarin
Standard Chinese or Modern Standard Chinese, also known as Mandarin or Putonghua, is the official language of the People's Republic of China and Republic of China , and is one of the four official languages of Singapore....
: tiān mù; ; Heaven's Eye) mountain temple in China
China
Chinese civilization may refer to:* China for more general discussion of the country.* Chinese culture* Greater China, the transnational community of ethnic Chinese.* History of China* Sinosphere, the area historically affected by Chinese culture...
where iron-glazed bowls were used for tea.
Tenmoku's are known for their variability. During their heating and cooling, several factors influence the formation of iron crystals within the glaze. A long firing process and a claybody which is also heavily colored with iron increase the opportunity for iron from the clay to be drawn into the glaze. While the glaze is molten, iron can migrate within the glaze to form surface crystals, as in the "oil spot" glaze, or remain in solution deeper within the glaze for a rich glossy color.
Today, most potters are familiar with tenmoku glaze in a reduction firing. But to get oil spot effects, stiff tenmokus need to be fired in oxidation. This relies on a very simple chemical principle that, once understood, can lead to many successful firings. Red iron oxide (Fe2O3) acts as a refractory in oxidation but it can easily be changed to a flux in the form of black iron oxide (FeO), in reduction. Most potters are familiar with this property but for oil spots, we are interested in iron’s ability to self-reduce. At approximately cone 7 (2250°F or 1232°C), ferric iron (Fe2O3) cannot maintain its trigonal crystalline structure and rearranges to a cubic structure, magnetite (Fe3O4), which further reduces to become ferrous (FeO). This is called thermal reduction, and what this means in layman’s terms is that, when it is sufficiently heated, the red iron oxide used in the glaze recipe will naturally let go of an oxygen atom. As the liberated oxygen bubbles rise to the surface of the glaze, they drag a bit of the magnetite with them and deposit it on the surface. A rough black spot is left on the glaze surface that is a different color than the surrounding glaze, due to the larger concentration of iron oxide in that small area and its subsequent re-oxidization during cooling.
1
A longer cooling time allows for maximum surface crystals. Potters can "fire down" a kiln to help achieve this effect. During a normal firing, the kiln is slowly brought to a maximum temperature by adding fuel, then fueling is stopped and the kiln is allowed to cool slowly by losing heat to the air around it. To fire down a kiln, the potter continues to add a limited amount of fuel after the maximum temperature is reached to slow the cooling process and keep the glazes molten for as long as possible.
Tenmoku glazes can range in color from dark plum (persimmon), to yellow, to brown, to black.
External links
1. Ceramics Monthly, "Oil Spot and Hare’s Fur Glazes: Demystifying Classic Ceramic Glazes", John Britt, April 13, 2011."The Complete Guide to High Fire Glazes", John Britt, Lark Books 2004, Oil Spot Glazes page 75 - 77.
- http://www.kyohaku.go.jp/eng/dictio/data/touji/tenmoku.htm : Tenmoku ware at the Kyoto National Museum
- http://www.2000cranes.com/Koji-Kamada.htm : Web page about modern tenmoku works by KAMADA Koji