Sampleite
Encyclopedia
Sampleite has a general formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 of NaCaCu5(PO4)4Cl•5(H2O). It was first described in 1942 for an occurrence in Chuquicamata, Chile and was named after Mat Sample, a mine superintendent for the Chile Exploration Company.

Sampleite is orthorhombic, which means crystallographically, it contains 3 unequal axes with angles that are 90°. It belongs to the space group
Space group
In mathematics and geometry, a space group is a symmetry group, usually for three dimensions, that divides space into discrete repeatable domains.In three dimensions, there are 219 unique types, or counted as 230 if chiral copies are considered distinct...

 2/m. In a thin section it has a high surface relief and will have sharp boundaries with the surrounding medium. Sampleite is anisotropic and has visible pleochroism
Pleochroism
Pleochroism is an optical phenomenon in which a substance appears to be different colors when observed at different angles with polarized light.- Background :Anisotropic crystals will have optical properties that vary with the direction of light...

 and birefringence
Birefringence
Birefringence, or double refraction, is the decomposition of a ray of light into two rays when it passes through certain anisotropic materials, such as crystals of calcite or boron nitride. The effect was first described by the Danish scientist Rasmus Bartholin in 1669, who saw it in calcite...

.

It is characteristically found in earthy crusts in a highly sericitized
Sericite
Sericite is a fine grained mica, similar to muscovite, illite, or paragonite. Sericite is a common alteration mineral of orthoclase or plagioclase feldspars in areas that have been subjected to hydrothermal alteration typically associated with copper, tin, or other hydrothermal ore deposits...

 rock and is present in highly oxidized conditions near the surface. When it occurs as micaceous rosettes and aggregates it can be associated with dendrites of manganese and iron oxides. Sampleite appears to be the most recent mineral deposited with the exception of gypsum.
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