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Ion exchange resin
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An ion-exchange resin is an insoluble matrix (or support structure) normally in the form of small (1-2 mm diameter) beads, usually white or yellowish, fabricated from an organic polymer substrate. The material has highly developed structure of pores on the surface of which are sites with easily trapped and released ions.
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An ion-exchange resin is an insoluble matrix (or support structure) normally in the form of small (1-2 mm diameter) beads, usually white or yellowish, fabricated from an organic polymer substrate. The material has highly developed structure of pores on the surface of which are sites with easily trapped and released ions. The trapping of ions takes place only with simultaneous releasing of other ions; thus the process is called ion-exchange. There are multiple different types of ion-exchange resin which are fabricated to selectively prefer one or several different types of ions.
Ion-exchange resins are widely used in different separation, purification, and decontamination processes. The most common examples are water softening and water purification. In many cases ion-exchange resins were introduced in such processes as a more flexible alternative to the use of natural or artificial zeolites.
Most typical ion-exchange resins are based on crosslinked polystyrene. The required active groups can be introduced after polymerization, or substituted monomers can be used. For example, the crosslinking is often achieved by adding 0.5-25% of divinyl benzene to styrene at the polymerization process. Non-crosslinked polymers are used only rarely because they are less stable. Crosslinking decreases ion- exchange capacity of the resin and prolongs the time needed to accomplish the ion exchange processes. Particle size also influences the resin parameters; smaller particles have larger outer surface, but cause larger head loss in the column processes.
Besides being made as bead-shaped materials, ion exchange resins are produced as membranes. The membranes are made of highly cross-linked ion exchange resins that allow passage of ions, but not of water, are used for electrodialysis.
There are four main types differing in their functional groups:
- strongly acidic (typically, sulfonic acid groups, eg. sodium polystyrene sulfonate or polyAMPS)
- strongly basic, (quaternary amino groups, for example, trimethylammonium groups, eg. polyAPTAC)
- weakly acidic (mostly, carboxylic acid groups)
- weakly basic (primary, secondary, and/or ternary amino groups, eg. polyethylene amine)
There are also specialised types:
Uses
Water softening
In this application, ion-exchange resins are used to replace the magnesium and calcium ions found in hard water with sodium ions. When the resin is fresh, it contains sodium ions at its active sites. When in contact with a solution containing magnesium and calcium ions (but a low concentration of sodium ions), the magnesium and calcium ions preferentially migrate out of solution to the active sites on the resin, being replaced in solution by sodium ions. This process reaches equilibrium with a much lower concentration of magnesium and calcium ions in solution than was started with.
The resin can be recharged by washing it with a solution containing a high concentration of sodium ions (e.g. it has large amounts of common salt (NaCl) dissolved in it). The calcium and magnesium ions migrate off the resin, being replaced by sodium ions from the solution until a new equilibrium is reached.
This is the method of operation used in dishwashers that require the use of 'dishwasher salt'. The salt is used to recharge an ion-exchange resin which itself is used to soften the water so that limescale deposits are not left on the cooking and eating utensils being washed.
Water purification
In this application, ion-exchange resins are used to remove poisonous (e.g. copper) and heavy metal (e.g. lead or cadmium) ions from solution, replacing them with more innocuous ions, such as sodium and potassium. Note that this is why it is not recommended to prepare artificial milk (infant formula) with softened water, since increased levels of sodium and potassium in the diet can be harmful to nursing infants.
Few ion-exchange resins remove chlorine or organic contaminants from water - this is usually done by using an activated charcoal filter mixed in with the resin. There are some ion-exchange resins that do remove organic ions, such as MIEX (magnetic ion-exchange) resins. Domestic water purification resin is not usually recharged - the resin is discarded when it can no longer be used.
Production of high purity water
Water of highest purity is required for electronics, scientific experiments, production of superconductors, and nuclear industry, among others. Such water is produced using ion-exchange processes or combinations of membrane and ion-exchange methods. Cations are replaced with hydrogen ions using cation-exchange resins; anions are replaced with hydroxyls using anion-exchange resins. The hydrogen ions and hydroxyls recombine producing water molecules. Thus, no ions remain in the produced water. The purification process is usually performed in several steps with "mixed bed ion-exchange columns" at the end of the technological chain.
Ion-exchange in metal separation
Ion-exchange processes are used to separate and purify metals, including separating uranium from plutonium and other actinides, including thorium; and lanthanum, neodymium, ytterbium, samarium, lutetium, from each other and the other lanthanides. There are two series of rare earth metals, the lanthanides and the actinides, both of which families all have very similar chemical and physical properties. Ion-exchange is the only practical way to separate them in large quantities.
A very important case is the PUREX process (plutionium-uranium extraction process) which is used to separate the plutonium and the uranium from the spent fuel products from a nuclear reactor, and to be able to dispose of the waste products. Then, the plutonium and uranium are available for making nuclear-energy materials, such as new reactor fuel and nuclear weapons.
The ion-exchange process is also used to separate other sets of very similar chemical elements, such as zirconium and hafnium, which incidentally is also very important for the nuclear industry. Zirconium is practically transparent to free neutrons, used in building reactors, but hafnium is a very strong absorber of neutrons, used in reactor control rods.
Catalysis
In chemistry ion-exchange resins are known to catalyze organic reactions. See for instance self-condensation.
Juice Purification
Ion-exchange resins are used in the manufacture of fruit juices such as orange juice where they are used to remove bitter tasting components and so improve the flavor. This allows poorer tasting fruit sources to be used for juice production.
Sugar Manufacturing
Ion-exchange resins are used in the manufacturing of sugar from various sources. They are used to help convert one type of sugar into another type of sugar, and to decolorize and purify sugar syrups.
Pharmaceuticals
Ion-exchange resins are used in the manufacturing of pharmaceuticals, not only for catalyzing certain reactions but also for isolating and purifying pharmaceutical active ingredients.
Three ion-exchange resins, sodium polystyrene sulfonate, colestipol, and cholestyramine, are used as active ingredients. Sodium polystyrene sulfonate is a strongly acidic ion-exchange resin and is used to treat hyperkalemia. Colestipol is a weakly basic ion-exchange resin and is used to treat hypercholesterolemia. Cholestyramine is a strongly basic ion-exchange resin and is also used to treat hypercholesterolemia. Colestipol and cholestyramine are known as bile acid sequestrants.
Ion-exchange resins are also used as excipients in pharmaceutical formulations such as tablets, capsules, and suspensions. In these uses the ion-exchange resin can have several different functions, including taste-masking, extended release, tablet disintegration, and improving the chemical stability of the active ingredients.
See also
Sources
- including Resin equivalency charts for various brands, technical data sheets and brochures from Res-Kem Corp.
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- F. Helfferich, Ion Exchange, McGraw Hill, New York, 1962 (Bible of the subject).
- Ion Exchangers (K. Dorfner, ed.), Walter de Gruyter, Berlin, 1991.
- C. E. Harland, Ion exchange: Theory and Practice, The Royal Society of Chemistry, Cambridge, 1994.
- Ion exchange (D. Muraviev, V. Gorshkov, A. Warshawsky), M. Dekker, New York, 2000.
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