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Dipole

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Definition





In physics, there are two kinds of dipoles . An electric dipole is a separation of positive and negative charge. The simplest example of this is a pair of electric charges of equal magnitude but opposite sign, separated by some, usually small, distance. By contrast, a magnetic dipole is a closed circulation of electric current. A simple example of this is a single loop of wire with some constant current flowing through it.

Dipoles can be characterized by their dipole moment Dipole

Definition

In physics, there are two kinds of dipoles = double and polos = pivot).... 

, a vector quantity. For the simple electric dipole given above, the electric dipole moment would point from the negative charge towards the positive charge, and have a magnitude equal to the strength of each charge times the separation between the charges. For the current loop, the magnetic dipole moment Magnetic moment

In physics [i], the magnetic moment or magnetic dipole moment is a measure of the strength of a magnetic source [i] ... 

 would point through the loop , with a magnitude equal to the current in the loop times the area of the loop.

In addition to current loops, the electron Electron

The electron is a fundamental [i] subatomic particle [i] that carries an electric charge [i]... 

, among other fundamental particles, is said to have a magnetic dipole moment. This is because it generates a magnetic field Magnetic field

In physics [i], a magnetic field is that part of the electromagnetic field [i] that exists when there is ... 

 which is identical to that generated by a very small current loop. However, to the best of our knowledge, the electron's magnetic moment is not due to a current loop, but is instead an intrinsic property of the electron. It is also possible that the electron has an electric dipole moment, although this has not yet been observed

A permanent magnet, such as a bar magnet, owes its magnetism to the intrinsic magnetic dipole moment of the electron. The two ends of a bar magnet are referred to as poles , and are labeled "north" and "south." The dipole moment of the bar magnet points from its magnetic south South Pole

When not otherwise qualified, the term South Pole normally refers to the Geographic South Pole – t... 

 to its magnetic north pole North Pole

The North Pole is the northernmost point on the Earth [i] and is on the opposite side of the Earth from ... 

 — confusingly, the "north" and "south" convention for magnetic dipoles is the opposite of that used to describe the Earth's geographic and magnetic poles, so that the Earth's geomagnetic north pole is the south pole of its dipole moment.

The only known mechanisms for the creation of magnetic dipoles are by current loops or quantum-mechanical spin since the existence of magnetic monopoles has never been experimentally demonstrated.

Torque on a dipole


Since the direction of an electric field is defined as the direction of the force on a positive charge, electric field lines point away from a positive charge and toward a negative charge.

When placed in an electric Electric field

In physics [i], the properties of space that surrounds an electric charge [i] can be described using an ele ... 

 or magnetic Magnetic field

In physics [i], a magnetic field is that part of the electromagnetic field [i] that exists when there is ... 

 field, equal but opposite forces arise on each side of the dipole creating a torque Torque

In physics [i], torque can informally be thought of as "rotational force". ... 

 t:

for an electric dipole moment Dipole

Definition

In physics, there are two kinds of dipoles = double and polos = pivot).... 

 p , or

for a magnetic dipole moment m .

The resulting torque will tend to align the dipole with the applied field, which in the case of an electric dipole, yields a potential energy of

.

The energy of a magnetic dipole is similarly

.

Physical dipoles, point dipoles, and approximate dipoles



A physical dipole consists of two equal and opposite point charges: literally, two poles. Its field at large distances depends almost entirely on the dipole moment as defined above. A point dipole is the limit obtained by letting the separation tend to 0 while keeping the dipole moment fixed. The field of a point dipole has a particularly simple form, and the order-1 term in the multipole expansion is precisely the point dipole field.

Although there are no known magnetic monopoles in nature, there are magnetic dipoles in the form of the quantum-mechanical spin associated with particles such as electron Electron

The electron is a fundamental [i] subatomic particle [i] that carries an electric charge [i]... 

s . A theoretical magnetic point dipole has a magnetic field of the exact same form as the electric field of an electric point dipole. A very small current-carrying loop is approximately a magnetic point dipole; the magnetic dipole moment of such a loop is the product of the current flowing in the loop and the area of the loop.

Any configuration of charges or currents has a 'dipole moment', which describes the dipole whose field is the best approximation, at large distances, to that of the given configuration. This is simply one term in the multipole expansion; when the charge is 0—as it always is for the magnetic case, since there are no magnetic monopoles—the dipole term is the dominant one at large distances: its field falls off in proportion to , as compared to for the next term and higher powers of for higher terms, or for the monopole term.

Molecular dipoles

Many molecule Molecule

In chemistry, a molecule is an aggregate of two or more atom [i]s in a definite arrangement held togethe ... 

s have such dipole moments due to non-uniform distributions of positive and negative charges on the various atoms. For example:

H-Cl


A molecule with a permanent dipole moment is called a polar molecule and is polarized. The physical chemist Peter J. W. Debye Peter Debye

Petrus Josephus Wilhelmus Debije was a Dutch [i] physical chemist [i].
... 

 was the first scientist to study molecular dipoles extensively, and dipole moments are consequently measured in units named debye in his honor.

With respect to molecules there are three types of dipoles:
  • Permanent dipoles: These occur when 2 atoms in a molecule have substantially different electronegativity — one atom attracts electrons more than another becoming more negative, while the other atom becomes more positive. See dipole-dipole attractions.
  • Instantaneous dipoles: These occur due to chance when electron Electron

    The electron is a fundamental [i] subatomic particle [i] that carries an electric charge [i]... 

    s happen to be more concentrated in one place than another in a molecule Molecule

    In chemistry, a molecule is an aggregate of two or more atom [i]s in a definite arrangement held togethe ... 

    , creating a temporary dipole. See Instantaneous dipole attraction.
  • Induced dipoles These occur when one molecule with a permanent dipole repels another molecule's electrons, "inducing" a dipole moment in that molecule. See induced-dipole attraction.


Typical gas phase values of some chemical compounds in Debye units :

  • carbon dioxide Carbon dioxide

    Carbon dioxide is a chemical compound [i] composed of one carbon [i] and two oxygen [i] atoms. ... 

    : 0
  • carbon monoxide Carbon monoxide

    Carbon monoxide, with the chemical formula CO, is a colourless, odourless, and tasteless gas [i]. ... 

    : 0.112
  • ozone Ozone

    Ozone is a triatomic molecule [i], consisting of three oxygen atom [i]s. ... 

    : 0.53
  • phosgene Phosgene

    Phosgene is the chemical compound [i] with the formula COCl2. ... 

    : 1.17
  • water vapor Water vapor

    Water vapor, also aqueous vapor, is the gas [i] phase of water [i]. ... 

    : 1.85
  • hydrogen cyanide Hydrogen cyanide

    Hydrogen cyanide is a chemical compound [i] with chemical formula [i] HCN. ... 

    : 2.98
  • cyanamide Cyanamide

    Cyanamide is an amide [i] of cyanogen [i], a white, crystalline compound. ... 

    : 4.27
  • potassium bromide Potassium bromide

    Potassium bromide is a salt [i], widely used as an anticonvulsant [i] and a sedative [i] in the late 19t ... 

    : 10.41


These values can be obtained from measurement of the dielectric constant. When the symmetry of a molecule cancels out a net dipole moment, the value is set at 0. The highest dipole moments are in the range of 10 to 11. From the dipole moment information can be deduced about the molecular geometry Molecular geometry

Molecular geometry or molecular structure is the three dimensional [i] arrangement of th ... 

 of the molecule. For example the data illustrate that carbon dioxide is a linear molecule but ozone is not.

Field from a magnetic dipole


Magnitude

The strength, B, of a dipole magnetic field is given by:

where:

B is the strength of the field, measured in teslas


r is the distance from the center, measured in metre Metre

The metre, or meter , is a measure of length [i]. ... 

s


? is the magnetic latitude where ? = magnetic colatitude, measured in radian Radian

The radian is a unit of plane angle [i]. ... 

s or degrees from the dipole axis


M is the dipole moment, measured in ampere square-metres, which equals joules per tesla.


µ0 is the permeability of free space, measured in henrys per metre.

Vector form

The field itself is a vector quantity:

where

B is the field
r is the vector from the position of the dipole to the position where the field is being measured
r is the absolute value of r: the distance from the dipole

is the unit vector parallel to r
m is the dipole moment
µ0 is the permeability of free space


This is exactly the field of a point dipole, exactly the dipole term in the multipole expansion of an arbitrary field, and approximately the field of any dipole-like configuration at large distances.

Magnetic vector potential

The vector potential A of a magnetic dipole is

with the same definitions as above.

Field from an electric dipole

The electrostatic potential of an electric dipole is

And the electric field Electric field

In physics [i], the properties of space that surrounds an electric charge [i] can be described using an ele ... 

 from a dipole can be found from the gradient Gradient

A generalization of these concepts is the gradient in vector calculus [i]; and this article is mostly ab ... 

 of this potential:

  
  



where

E is the electric field
r, r, are as above
p is the dipole moment
e0 is the permittivity of free space Permittivity

Permittivity is a physical quantity [i] that describes how an electric field [i] affects and is affected ... 

.


Notice that this is formally identical to the magnetic field of a point magnetic dipole; only a few names have changed.

Dipole radiation

In addition to dipoles in electrostatics, it is also common to consider an electric or magnetic dipole that is oscillating in time.

In particular, a harmonically oscillating electric dipole is described by a dipole moment of the form where ? is the angular frequency Angular frequency

*Radian [i]
  • Pulsation [i]

... 

. In vacuum, this produces fields:

Far away , the fields approach the limiting form of a radiating spherical wave:

which produces a total time-average radiated power P given by:

This power is not distributed isotropically, but is rather concentrated around the directions lying perpendicular to the dipole moment.
Usually such equations are described by spherical harmonics Spherical harmonics

In mathematics [i], the spherical harmonics are the angular portion of an orthogonal [i] set of solution ... 

, but they look very different.
A circular polarized dipole is described as a superposition of two linear dipoles.

See also

  • Electrostatics
  • Magnetostatics
  • Electric field Electric field

    In physics [i], the properties of space that surrounds an electric charge [i] can be described using an ele ... 

  • Magnetic field Magnetic field

    In physics [i], a magnetic field is that part of the electromagnetic field [i] that exists when there is ... 

  • Magnetic dipole moment Magnetic moment

    In physics [i], the magnetic moment or magnetic dipole moment is a measure of the strength of a magnetic source [i] ... 



References


External links