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Butanone
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Butanone is the organic compound with the formula CH3C(O)CH2CH3. This colorless liquid has a sharp, sweet odor reminiscent of butterscotch and acetone. It is a ketone, better known as methyl ethyl ketone or MEK. It is produced on a large scale industrially. Butanone occurs in only trace amounts in nature.
none is produced by the dehydrogenation of 2-butanol using a catalyst based on copper, zinc, or bronze:
- CH3CH(OH)CH2CH3 ? CH3C(O)CH2CH3 + H2
In this way, approximately 700M kg are produced yearly.

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Encyclopedia
Butanone is the organic compound with the formula CH3C(O)CH2CH3. This colorless liquid has a sharp, sweet odor reminiscent of butterscotch and acetone. It is a ketone, better known as methyl ethyl ketone or MEK. It is produced on a large scale industrially. Butanone occurs in only trace amounts in nature.
Production
Butanone is produced by the dehydrogenation of 2-butanol using a catalyst based on copper, zinc, or bronze:
- CH3CH(OH)CH2CH3 ? CH3C(O)CH2CH3 + H2
In this way, approximately 700M kg are produced yearly. Other routes that have been examined but not implemented include Wacker oxidation of 2-butene and oxidation of isobutylbenzene (analogous to the industrial route to acetone.
MEK is biosynthesize by some trees and found in some fruits and vegetables in small amounts. It is also released to the air from car and truck exhausts.
Applications
MEK dissolves many substances and is used as a solvent in processes involving gums, resins, cellulose acetate and nitrocellulose coatings and in vinyl films. For this reason it finds use in the manufacture of plastics, textiles, in the production of paraffin wax, and in household products such as lacquer, varnishes, paint remover, a denaturing agent for denatured alcohol, glues, and as a cleaning agent. MEK is also used in dry erase markers as the solvent of the erasable dye.
MEK is the precursor to methyl ethyl ketone peroxide, a catalyst for some polymerization reactions.
Health effects
Butanone is an irritant, but serious health effects in animals have been seen only at very high levels. When inhaled, these effects included birth defects,
Methyl ethyl ketone is listed as a Table II precursor under the United Nations Convention Against Illicit Traffic in Narcotic Drugs and Psychotropic Substances.
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