Austinite
Encyclopedia
Austinite is a member of the adelite
-descloizite group, adelite subgroup, the Zn end member of the Cu-Zn series with conichalcite
. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was thought to be a different species, but it is now considered to be identical to austinite. Austinite is named in honour of Austin Flint Rogers (1877–1957), American mineralogist from Stanford University, California, USA.
Any crystal
which has a mirror plane as one of its symmetry elements has the property that its mirror image
(with any plane as the mirror plane) can always be superimposed on the original crystal by translation or rotation or both.
If there are no mirror planes as symmetry elements then the mirror image of a crystal cannot be brought into superposition with the original crystal by rotation or translation. This is enantiomorphism, and the mirror images are said to be enantiomorphs of each other. The possibility of enantiomorphic crystals is determined by the crystal symmetry, i.e., by the point group
of the crystal species. There are 32 possible point groups, and 22 of these are capable of forming enantiomorphs. The enantiomorphs are designated right or left handed, according to whether they rotate the plane of polarised light to the right or to the left. Sometimes it is clear from the outward form of the crystal whether it is right or left handed, and sometimes optical methods are needed to determine this.
The commonest enantiomorphic mineral is quartz
, with point group 32; all quartz crystals will be either right or left handed, but it may not be possible to distinguish this from the external form unless some critical crystal faces are present.
Austinite has point group 222, with no mirror planes, so austinite is also an enantiomorphic mineral, occurring as both right handed and left handed crystals, with right handed ones more common.
deposits, where it is found developed on the colloform (pertaining to the rounded, globular texture of mineral formed by colloidal precipitation) surface of limonite
or lining small cavities. It is closely associated with adamite
, and appears to be a later mineral. Austinite is associated with adamite, quartz
, talmessite and limonite. Its type locality
is Gold Hill Mine (Western Utah Mine), Gold Hill, Gold Hill District (Clifton District), Deep Creek Mts, Tooele County, Utah, USA.
Adelite
The rare mineral adelite, is a calcium, magnesium, arsenate with chemical formula CaMgAsO4OH. It forms a solid solution series with the vanadium bearing mineral gottlobite...
-descloizite group, adelite subgroup, the Zn end member of the Cu-Zn series with conichalcite
Conichalcite
Conichalcite, CaCu, is a relatively common arsenate mineral related to duftite . It is green, often botryoidal, and occurs in the oxidation zone of some metal deposits. It occurs with limonite, malachite, beudantite, adamite, cuproadamite, olivenite and smithsonite.- Formation :Conichalcite forms...
. It is the zinc analogue of cobaltaustinite and nickelaustinite. At one time “brickerite” was thought to be a different species, but it is now considered to be identical to austinite. Austinite is named in honour of Austin Flint Rogers (1877–1957), American mineralogist from Stanford University, California, USA.
Structure
The structure is composed of chains of edge-sharing polyhedra ZnO6, and very distorted Ca(O,OH)8 polyhedra linked through AsO4 into a three-dimensional network.Any crystal
Crystal
A crystal or crystalline solid is a solid material whose constituent atoms, molecules, or ions are arranged in an orderly repeating pattern extending in all three spatial dimensions. The scientific study of crystals and crystal formation is known as crystallography...
which has a mirror plane as one of its symmetry elements has the property that its mirror image
Mirror image
A mirror image is a reflected duplication of an object that appears identical but reversed. As an optical effect it results from reflection off of substances such as a mirror or water. It is also a concept in geometry and can be used as a conceptualization process for 3-D structures...
(with any plane as the mirror plane) can always be superimposed on the original crystal by translation or rotation or both.
If there are no mirror planes as symmetry elements then the mirror image of a crystal cannot be brought into superposition with the original crystal by rotation or translation. This is enantiomorphism, and the mirror images are said to be enantiomorphs of each other. The possibility of enantiomorphic crystals is determined by the crystal symmetry, i.e., by the point group
Point group
In geometry, a point group is a group of geometric symmetries that keep at least one point fixed. Point groups can exist in a Euclidean space with any dimension, and every point group in dimension d is a subgroup of the orthogonal group O...
of the crystal species. There are 32 possible point groups, and 22 of these are capable of forming enantiomorphs. The enantiomorphs are designated right or left handed, according to whether they rotate the plane of polarised light to the right or to the left. Sometimes it is clear from the outward form of the crystal whether it is right or left handed, and sometimes optical methods are needed to determine this.
The commonest enantiomorphic mineral is quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...
, with point group 32; all quartz crystals will be either right or left handed, but it may not be possible to distinguish this from the external form unless some critical crystal faces are present.
Austinite has point group 222, with no mirror planes, so austinite is also an enantiomorphic mineral, occurring as both right handed and left handed crystals, with right handed ones more common.
Occurrence
Austinite is a rare mineral in the oxidation zone of arsenic bearing base metalBase metal
In chemistry, the term base metal is used informally to refer to a metal that oxidizes or corrodes relatively easily, and reacts variably with diluted hydrochloric acid to form hydrogen. Examples include iron, nickel, lead and zinc...
deposits, where it is found developed on the colloform (pertaining to the rounded, globular texture of mineral formed by colloidal precipitation) surface of limonite
Limonite
Limonite is an ore consisting in a mixture of hydrated iron oxide-hydroxide of varying composition. The generic formula is frequently written as FeO·nH2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.Together with hematite, it has...
or lining small cavities. It is closely associated with adamite
Adamite
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with...
, and appears to be a later mineral. Austinite is associated with adamite, quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...
, talmessite and limonite. Its type locality
Type locality (geology)
Type locality , also called type area or type locale, is the where a particular rock type, stratigraphic unit, fossil or mineral species is first identified....
is Gold Hill Mine (Western Utah Mine), Gold Hill, Gold Hill District (Clifton District), Deep Creek Mts, Tooele County, Utah, USA.