Van der Waals molecule
Encyclopedia
A van der Waals molecule is a stable cluster consisting of two or more molecules held together by van der Waals forces or by hydrogen bonds. The name originated in the beginning of the 1970s when stable molecular clusters were regularly observed in molecular beam
microwave spectroscopy.
In (supersonic) molecular beams temperatures are very low (usually less than 5 K). At these low temperatures van der Waals (vdW) molecules are stable and can be investigated by microwave and far-infrared spectroscopy. Also in cold equilibrium gases vdW molecules are formed, albeit in small, temperature dependent, concentrations. Rotational and vibrational transitions in vdW molecules have indeed been observed in gases, mainly by UV and IR spectroscopy.
Van der Waals molecules are usually very non-rigid and different versions are separated by low energy barriers, so that tunneling splittings, observable in far-infrared spectra, are relatively large. Thus, in the far-infrared one may observe intermolecular vibrations, rotations, and tunneling motions of vdW molecules (VRT spectroscopy). The VRT spectroscopic study of vdW molecules is one of the most direct routes to the understanding of intermolecular forces.
Examples of well-studied vdW molecules are Ar2, H2-Ar, benzene-Ar, (H2O)2, and (HF)2
Molecular beam
A molecular beam is produced by allowing a gas at higher pressure to expand through a small orifice into a chamber at lower pressure to form a beam of particles moving at approximately equal velocities, with very few collisions between the particles...
microwave spectroscopy.
In (supersonic) molecular beams temperatures are very low (usually less than 5 K). At these low temperatures van der Waals (vdW) molecules are stable and can be investigated by microwave and far-infrared spectroscopy. Also in cold equilibrium gases vdW molecules are formed, albeit in small, temperature dependent, concentrations. Rotational and vibrational transitions in vdW molecules have indeed been observed in gases, mainly by UV and IR spectroscopy.
Van der Waals molecules are usually very non-rigid and different versions are separated by low energy barriers, so that tunneling splittings, observable in far-infrared spectra, are relatively large. Thus, in the far-infrared one may observe intermolecular vibrations, rotations, and tunneling motions of vdW molecules (VRT spectroscopy). The VRT spectroscopic study of vdW molecules is one of the most direct routes to the understanding of intermolecular forces.
Examples of well-studied vdW molecules are Ar2, H2-Ar, benzene-Ar, (H2O)2, and (HF)2