Tridymite
Encyclopedia
Tridymite is a high-temperature polymorph
Polymorphism (materials science)
Polymorphism in materials science is the ability of a solid material to exist in more than one form or crystal structure. Polymorphism can potentially be found in any crystalline material including polymers, minerals, and metals, and is related to allotropy, which refers to chemical elements...

 of quartz
Quartz
Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz,...

 and usually occurs as minute tabular white or colorless pseudo-hexagonal triclinic crystals, or scales, in cavities in acidic volcanic rock
Volcanic rock
Volcanic rock is a rock formed from magma erupted from a volcano. In other words, it is an igneous rock of volcanic origin...

s. Its chemical formula
Chemical formula
A chemical formula or molecular formula is a way of expressing information about the atoms that constitute a particular chemical compound....

 is Si
Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. A tetravalent metalloid, it is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table...

O
Oxygen
Oxygen is the element with atomic number 8 and represented by the symbol O. Its name derives from the Greek roots ὀξύς and -γενής , because at the time of naming, it was mistakenly thought that all acids required oxygen in their composition...

2. Tridymite was first described in 1868 and the type location is in Hidalgo, Mexico
Mexico
The United Mexican States , commonly known as Mexico , is a federal constitutional republic in North America. It is bordered on the north by the United States; on the south and west by the Pacific Ocean; on the southeast by Guatemala, Belize, and the Caribbean Sea; and on the east by the Gulf of...

. The name is from the Greek Tridymos for triplet as tridymite commonly occurs as twinned
Crystal twinning
Crystal twinning occurs when two separate crystals share some of the same crystal lattice points in a symmetrical manner. The result is an intergrowth of two separate crystals in a variety of specific configurations. A twin boundary or composition surface separates the two crystals....

 crystal trillings. Tridymite can occur in several crystalline forms, which are metastable at ambient conditions, the most common being α and β. Alpha phase is orthorhombic, Pearson symbol
Pearson symbol
The Pearson symbol, or Pearson notation, is used in crystallography as a means of describing a crystal structure, and was originated by W.B. Pearson. The symbol is made up of two letters followed by a number. For example:* Diamond structure, cF8...

 oS24, group C2221, No.20 whereas β-tridymite is hexagonal
Hexagonal crystal system
In crystallography, the hexagonal crystal system is one of the 7 crystal systems, the hexagonal lattice system is one of the 7 lattice systems, and the hexagonal crystal family is one of the 6 crystal families...

, hP12, P63/mmc, No. 194. β-tridymite converts to β-cristobalite
Cristobalite
The mineral cristobalite is a high-temperature polymorph of silica, meaning that it has the same chemical formula, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group which also include coesite, tridymite and stishovite...

at 1470 °C.

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