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Sterling Silver

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Sterling silver



 
 
Sterling silver is an alloy
Alloy

An alloy is a partial or complete solid solution of one or more chemical element in a metallic matrix. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may be homogeneous in distribution depending on thermal history....
 of silver
Silver

Silver is a chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal....
 containing 92.5% pure silver and 7.5% other metals, usually copper
Copper

Copper is a chemical element with the symbol Cu and atomic number 29.It is a ductile metal with very high thermal and electrical conductivity....
. The sterling silver standard
Silver standards

Silver standards refer to the standards of Millesimal_fineness for the silver alloy used in the manufacture or crafting of silver objects. This list is organized from highest to lowest millesimal fineness, or purity of the silver....
 has a minimum millesimal fineness
Millesimal fineness

Millesimal fineness is a system of denoting the purity of platinum, gold and silver alloys by parts per thousand of pure metal by mass in the alloy....
 of 925.

Fine silver (99.9% pure) is generally too soft for producing large functional objects; therefore, the silver is usually alloyed with either copper or titanium to give it strength, while at the same time preserving the ductility
Ductility

Ductility is a mechanical property used to describe the extent to which materials can be deformed deformation without fracture.In material science, ductility specifically refers to a material's ability to deform under tensile stress; this is often characterized by the material's ability to be stretched into a wire....
 and beauty of the precious metal
Precious metal

A precious metal is a rare metallic chemical element of high economics value. Chemically, the precious metals are less reactivity than most elements, have high lustre , are softer or more ductility, and have higher melting points than other metals....
.






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Encyclopedia


Sterling silver is an alloy
Alloy

An alloy is a partial or complete solid solution of one or more chemical element in a metallic matrix. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may be homogeneous in distribution depending on thermal history....
 of silver
Silver

Silver is a chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal....
 containing 92.5% pure silver and 7.5% other metals, usually copper
Copper

Copper is a chemical element with the symbol Cu and atomic number 29.It is a ductile metal with very high thermal and electrical conductivity....
. The sterling silver standard
Silver standards

Silver standards refer to the standards of Millesimal_fineness for the silver alloy used in the manufacture or crafting of silver objects. This list is organized from highest to lowest millesimal fineness, or purity of the silver....
 has a minimum millesimal fineness
Millesimal fineness

Millesimal fineness is a system of denoting the purity of platinum, gold and silver alloys by parts per thousand of pure metal by mass in the alloy....
 of 925.

Fine silver (99.9% pure) is generally too soft for producing large functional objects; therefore, the silver is usually alloyed with either copper or titanium to give it strength, while at the same time preserving the ductility
Ductility

Ductility is a mechanical property used to describe the extent to which materials can be deformed deformation without fracture.In material science, ductility specifically refers to a material's ability to deform under tensile stress; this is often characterized by the material's ability to be stretched into a wire....
 and beauty of the precious metal
Precious metal

A precious metal is a rare metallic chemical element of high economics value. Chemically, the precious metals are less reactivity than most elements, have high lustre , are softer or more ductility, and have higher melting points than other metals....
. Other metals can replace the copper, usually with the intent to improve various properties of the basic sterling alloy
Alloy

An alloy is a partial or complete solid solution of one or more chemical element in a metallic matrix. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may be homogeneous in distribution depending on thermal history....
 such as reducing casting porosity
Porosity

Porosity is a measure of the void spaces in a material, and is measured as a fraction, between 0?1, or as a percentage between 0?100%. The term is used in multiple fields including ceramics, metallurgy, materials, manufacturing, earth sciences and construction....
, eliminating firescale
Firescale

Firescale, also known as firestain, is a red or purple stain that appears on mixtures of silver and copper, such as sterling silver. At high temperatures, oxygen mixes with the copper to form cuprous oxide and then cupric oxide....
, and increasing resistance to tarnish
Tarnish

Tarnish is a layer of corrosion that forms over copper, brass, silver, aluminum, and other semi-reactive metals as they undergo oxidation. It is analogous to rust, but with a slower rate of occurrence....
. These replacement metals include germanium
Germanium

Germanium is a chemical element with the symbol Ge and atomic number 32. It is a lustrous, hard, greyish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon....
, zinc
Zinc

Zinc is a metallic chemical element with the symbol Zn and atomic number 30. It is a first-row transition metal of the group 12 element of the periodic table....
 and platinum
Platinum

Platinum is a chemical element with the chemical symbol Pt and an atomic number of 78. Its name is derived from the Spanish term platina del Pinto, which is literally translated into "little silver of the Pinto River." It is in Group 10 of the periodic table of elements....
, as well as a variety of other additives, including silicon
Silicon

Silicon is the most common metalloid. It is a chemical element, which has the symbol Si and atomic number 14. The atomic mass is 28.0855....
 and boron
Boron

Boron is a chemical element with atomic number 5 and the chemical symbol B. Boron is a trivalent metalloid element which occurs abundantly in the evaporite ores borax and ulexite....
. A number of alloys have appeared in recent years, formulated to lessen firescale or to inhibit tarnish, and this has sparked heavy competition among the various manufacturers, who are rushing to make claims of having the best formulation. However, no one alloy has emerged to replace copper as the industry standard, and alloy development is a very active area.

Origin of the alloy metal


Although there is much confusion over the origin of the word "sterling", there is general agreement that the sterling alloy originated in what is now continental Europe, and was being used for commerce as early as the 12th century in the area of what is now northern Germany
Germany

Germany , officially the Federal Republic of Germany , is a country in Central Europe. It is bordered to the north by the North Sea, Denmark, and the Baltic Sea; to the east by Poland and the Czech Republic; to the south by Austria and Switzerland; and to the west by France, Luxembourg, Belgium, and the Netherlands....
.

Origin of the word "sterling", used to refer to the silver alloy


The word "sterling", used in reference to the 0.925 grade of silver, emerged in England
England

native_name =|conventional_long_name = England|common_name = England|image_flag = Flag of England.svg|image_coat = England COA.svg|symbol_type = Royal Coat of Arms...
 by the 13th century. The terms "sterling" and "pound sterling
Pound sterling

----The pound sterling , subdivided into 100 pence , is the currency of the United Kingdom, its Crown dependency and the British Overseas Territories of South Georgia and the South Sandwich Islands and British Antarctic Territory....
" acquired their meaning in more than a century, and from convergent sources. There are three possible origins for the word "sterling". Two originate from 12th and 13th century coinage, and one is generally discounted. The word could have derived from the Old English word "stiere", meaning "strong, firm, immovable".

Scottish mine theory, anachronistic

At the start of the 18th century (around 1715) on the edge of the Ochil Hills
Ochil Hills

The Ochil Hills is a range of hills in Scotland north of the River Forth valley bordered by the towns of Stirling, Alloa, Kinross and Perth, Scotland....
, near Alva
Alva, Clackmannanshire

Alva is a small town in Clackmannanshire, Scotland. It is one of a number of towns situated immediately to the south of the Ochil Hills. These towns are collectively referred to as the Hillfoots Villages or simply The Hillfoots....
, in what was "Sterlingshire" now part of Clackmannanshire
Clackmannanshire

Clackmannanshire and sometimes called Clacks is one of the 32 Local government in Scotland Council areas of Scotland of Scotland, and a Lieutenancy areas of Scotland, bordering Perth and Kinross, Stirling and Fife....
, was the richest deposit of silver in the United Kingdom. Hence the name "Sterling Silver" Analysis has revealed the silver was rich in mercury, containing around 10-15% of this element. Alva silver therefore approaches amalgam in its chemical constitution rather than the "kongsbergite" variety of silver, which is also mercury-rich. Additional analysis may also reveal more rare species or possibly new ones from this occurence.

The Alva silver mine is now barren: a later extraction has since cleaned out the deposit and the location of "Silver Glen
Silver Glen

The Silver Glen lies approximately 1km to the east of the town of Alva, Clackmannanshire, Scotland, and takes its name from the silver that was mined there in the early 18th century....
" is now part of a trustland.

Starling theory, discounted


Although marks of birds have been used in some coins of Edward the Confessor, sterling is not likely to have been derived from starling
Starling

Starlings are found around the World, from Europe, Asia and Africa, to northern Australia and the islands of the tropical Pacific. Several European and Asian species have been introduced to these areas as well as North America, Hawaii and New Zealand, where they generally compete for habitat with native birds and are considered to be invasive spec...
, as the word for starling at the time was spelled stær.

Mint mark theory


The 1955 edition of the Oxford English Dictionary
Oxford English Dictionary

The Oxford English Dictionary , published by the Oxford University Press , is a comprehensive dictionary of the English language. Two fully-bound print editions of the OED have been published under its current name, in 1928 and 1989; as of December 2008 the dictionary's current editors have completed a quarter of the third edition....
 states that the early Middle English name sterling was presumably descriptive of small stars that were visible on early Norman pennies. (Old English: steorling.)

"Easterling" theory


An alternative explanation put forth by Walter de Pinchebek circa 1300 is that sterling silver may have been known first as "Easterling Silver". The term "Easterling Silver" is believed to have been used to refer to the grade of silver that had originally been used as the local currency
Currency

A currency is a Medium of exchange, facilitating the trade of goods and/or Service s. It is coins and paper bills used as money. It is one form of money, where money is anything that serves as a medium of exchange, a store of value, and a standard of value....
 in an area of Germany
Germany

Germany , officially the Federal Republic of Germany , is a country in Central Europe. It is bordered to the north by the North Sea, Denmark, and the Baltic Sea; to the east by Poland and the Czech Republic; to the south by Austria and Switzerland; and to the west by France, Luxembourg, Belgium, and the Netherlands....
, known as "The Easterling".

This "Easterling" area consisted of five towns in northern Germany that banded together in the 12th century under the name Hanseatic League
Hanseatic League

The Hanseatic League was an Military alliance of Trade cities and their guilds that established and maintained trade monopoly along the coast of Northern Europe, from the Baltic Sea to the North Sea and inland, during the Late Middle Ages and Early modern period ....
. The Hanseatic League proceeded to engage in considerable commerce with England. In payment for English cattle
Cattle

Cattle, colloquially referred to as cows, are domestication ungulates, a member of the subfamily Bovinae of the family Bovidae. They are raised as livestock for meat , dairy products , leather and as draft animals ....
 and grain, the League used their local currency. This currency was in the form of 92.5% silver coins. England soon learned that these coins, which they referred to as "the coins of the Easterlings", were of a reliably high quality and hardness.

King Henry II
Henry II of England

Henry II, called Curtmantle ruled as King of England , Count of Anjou, Duke of Normandy, Duke of Aquitaine, Duke of Gascony, Count of Nantes, Lord of Ireland and, at various times, controlled parts of Wales, Scotland and western France....
 set about to adopt the alloy
Alloy

An alloy is a partial or complete solid solution of one or more chemical element in a metallic matrix. Complete solid solution alloys give single solid phase microstructure, while partial solutions give two or more phases that may be homogeneous in distribution depending on thermal history....
 as the standard for English currency. He recruited metal refiners from The Easterling and put them to work making silver coins for England. The silver these refiners produced came into usage as currency by 1158 in the form of what are now known as "Tealby Pennies
History of the English penny (1154-1485)

This is the history of the British one penny coin from the years 1154 to 1485....
", and was eventually adopted as a standard alloy throughout England. The original name "Easterling Silver" later became known as simply "sterling silver".

The original English silver penny was 22½ troy grains of fine silver (as pure as can readily be made). 22½ troy grains is equivalent to 30 so-called tower grains or one tower pennyweight. When Henry II reformed the coinage, he based the new coinage on the then international standard of the troy pound rather than the pre-conquest English standard of the tower pound. A troy pennyweight is 24 troy grains. To maintain the same amount of silver (and thus the same value) in a coin that weighed more required less silver. It required that the alloy be only 92½% pure.

Though coin weights and silver purity varied considerably (reaching a low point before the reign of Elizabeth I, who reinstated sterling silver coinage for the first time since the early 14th century), the pound sterling was used as currency in England from the 12th century until the middle of the 20th century. Specifically this was in the silver coins of the British Empire
British Empire

The British Empire comprised the dominions, Crown colony, protectorates, League of Nations mandate, and other Dependent territory ruled or administered by the United Kingdom , that had originated with the overseas colonies and trading posts established by England in the late 16th and early 17th centuries....
: Britain, British colonies, and some former British colonies. This sterling coin silver is not to be confused with coin silver.

Sterling silver, no longer used in circulating currency, is still used for flatware, jewellery
Jewellery

Jewellery is an item of personal adornment, such as a necklace, ring , brooch or bracelet, that is worn by a person. It may be made from gemstones or precious metals, but may be from any other material, and may be appreciated because of geometric or other patterns, or meaningful symbols....
 and plate
Plate

Plate may refer to:* Plate * Plate , a type of foundation* A flat piece of metal used in orthopedics to connect the two parts of a broken bone, such as a dynamic compression plate...
, and is a grade of silver respected for both relatively high purity and sufficient hardness to form durable objects in daily use.

A century of dining regalia: the silver craze of 1840 to 1940


Tiffanypitcher
From about 1840 to somewhere around 1940 in the United States
United States

The United States of America is a Federal government constitutional republic comprising U.S. state and a federal district. The country is situated mostly in central North America, where its Contiguous United States and Washington, D.C., the Capital districts and territories, lie between the Pacific Ocean and Atlantic Oceans, Borders of the U...
 and Europe
Europe

Europe is, conventionally, one of the world's seven continents. Comprising the westernmost peninsula of Eurasia, Europe is generally divided from Asia to its east by the water divide of the Ural Mountains, the Ural , the Caspian Sea, and by the Caucasus Mountains to the southeast....
, sterling silver flatware became de rigueur
De rigueur

De rigueur is a French language expression that literally means "of rigor" or "of strictness". In English language usage, it means "necessary according to etiquette, protocol or fashion."...
 when setting a proper table. In fact, there was a marked increase in the number of silver companies that emerged during that period.

The height of the silver craze was during the 50-year period from 1870 to 1920. Flatware lines during this period sometimes included up to 100 different types of pieces. In conjunction with this, the dinner went from three courses to sometimes ten or more. There was a soup course, a salad course, a fruit course, a cheese course, an antipasto course, a fish course, the main course and a pastry or dessert course.

Individual eating implements often included forks (dinner fork, place fork, salad fork, pastry fork, shrimp or cocktail fork), spoons (teaspoon, coffee spoon, demitasse spoon, bouillon spoon, gumbo soup spoon, iced tea spoon) and knives (dinner knife, place knife, butter spreader, fruit knife, cheese knife). This was especially true during the Victorian time period, when etiquette dictated that nothing should be touched with one's fingers.

Serving pieces were often elaborately decorated and pierced and embellished with ivory, and could include any or all of the following: carving knife and fork, salad knife and fork, cold meat fork, punch ladle, soup ladle, gravy ladle, casserole serving spoon, berry spoon, lasagna server, macaroni server, asparagus server, cucumber server, tomato server, olive spoon, cheese scoop, fish knife and fork, pastry server, petit four server, cake
Cake

Cake is a form of food that is usually sweet and often Baking. Cakes normally combine some kind of flour, a sweetener , a binding agent , fats , a liquid , flavoring and some form of leavening agent , though many cakes lack these ingredients and instead rely on air bubbles in the dough to expand and cause the cake to rise....
 knife, bon bon spoon, tiny salt spoon, sugar sifter or caster and crumb remover with brush.

Flatware sets were often accompanied by tea services, hot water pots, chocolate pots, trays and salvers, goblets, demitasse cups and saucers, liqueur cups, bouillon cups, egg cups, sterling plates, napkin rings, water and wine pitchers and coasters, candelabra and even elaborate centerpieces.

In fact, the craze with sterling even extended to business (sterling page clips, mechanical pencil
Mechanical pencil

A mechanical pencil, propelling pencil or technical pencil is a pencil containing an internal mechanism which pushes or propels the thin graphite lead through the tip....
s, letter openers, calling card boxes, cigarette case
Cigarette case

A cigarette case or cigarette box is a sturdy, most commonly metal Packaging to store small amounts of cigarettes safely from crushing. In modern times they are also made of plastic....
s), to the boudoir (sterling dresser trays, mirrors, hair and suit brushes, pill bottles, manicure sets, shoehorns, perfume bottles, powder bottles, hair clips) and even to children (cups, flatware, rattle
Rattle

Rattle may mean:* Rattle * RATTLE magazine, an American poetry journal* Bird-scaring rattle, a Slovene device used to drive birds off vineyards and a folk instrument...
s, christening sets).

A number of factors converged to make sterling fall out of favor around the time of World War II
World War II

World War II, or the Second World War , was a global military conflict which involved a Participants in World War II, including all of the great powers, organised into two opposing military alliances: the Allies of World War II and the Axis powers....
. The cost of labor rose (sterling pieces were all still mostly hand-made, with only the basics being done by machine). Only the wealthy could afford the large number of servants required for fancy dining with ten courses. And changes in aesthetics resulted in people desiring simpler dinnerware that was easier to clean.

Hallmarks


Over the years, most countries in the world have developed their own systems of hallmarking silver
Silver hallmarks

A sterling silver object that is to be sold commercially is, in most countries, stamped with one or more silver hallmarks indicating the purity of the silver, the mark of the manufacturer or silversmith, and other markings to indicate date of manufacture and additional information about the piece....
. The purpose of hallmark
Hallmark

A hallmark is a mark or series of marks struck on items made of precious metals — platinum, gold, silver and in some nations, palladium....
 application is manifold:

  • To indicate the purity of the silver alloy used in the manufacture or hand-crafting of the piece.


  • To identify the silversmith or company that made the piece.


  • To note the date and/or location of the manufacture.


Miscellaneous


In addition to the uses of sterling silver mentioned above, there are some little known uses of sterling:

  • Medical instruments: Evidence of silver and/or silver-alloy surgical and medical instruments has been found in civilisations as early as Ur, Hellenistic-era Egypt and Rome, and their use continued until largely replaced in Western countries in the mid to late 20th century by cheaper, disposable plastic items. Its natural malleability is an obvious physical advantage, but it also exhibits medically-specific utility, including the fact that it is naturally aseptic, and, in respect of modern medical practices, it is resistant to antiseptics, heat sterilisation and body fluids.


  • Musical instruments: Due to sterling silver having a special sound character, some brasswind instrument manufacturers use 92.5% sterling silver as the material for making their instruments, including the flute and saxophones. For example, some leading saxophone manufactuers such as Selmer
    The Selmer Company

    The Selmer Company was a manufacturer of musical instruments started in Paris, France in the early 1900s. Selmer was known for its high-quality woodwind instruments, especially saxophones and clarinets....
     and Yanagisawa
    Yanagisawa Wind Instruments

    Yanagisawa Wind Instruments is a Japanese woodwind company known for its range of student, intermediate and professional grade saxophones. Along with Yamaha they are one of the leading manufacturers of saxophones in Japan....
     have crafted some of their saxophones from sterling silver, which they believe will make the instruments more resonant and colorful in timbre.


Tarnish and corrosion


As the purity of the silver decreases, the problem of corrosion
Corrosion

Corrosion means the breaking down of essential properties in a material due to chemical reactions with its surroundings. In the most common use of the word, this means a loss of electrons of metals reacting with water and oxygen....
 or tarnishing increases.

Chemically, silver is not very reactive — it does not react with oxygen
Oxygen

Oxygen no O2 produced; 2) O2 produced, but absorbed in oceans & seabed rock; 3) O2 starts to gas out of the oceans, but is absorbed by land surfaces and formation of ozone layer; 4-5) O2 sinks filled and the gas accumulates]]...
 or water at ordinary temperatures, so does not easily form a silver oxide. However, the other metal in the alloy, usually copper, may react with oxygen in the air.

The black silver sulfide
Silver sulfide

Silver sulfide , Ag2S, is a black sulfide of silver. It is black and constitutes the tarnish that forms on silver when exposed to the hydrogen sulfide of the atmosphere....
 (Ag2S) is among the most insoluble
Solubility

Solubility is often seen as a property of a substance; for instance the solubility of a solid substance usually refers to the concentration of the substance in a liquid that has reached equilibrium with the substance in solid phase ....
 salts in aqueous solution
Solution

In chemistry, a solution is a homogeneous mixture composed of two or more substances. In such a mixture, a solute is dissolved in another substance, known as a solvent....
, a property that is exploited for separating silver ion
Ion

An ion is an atom or molecule which has lost or gained one or more electrons, giving it a positive or negative electrical charge. According to the Bohr_model this will be from or in the outer shield 'n'....
s from other positive ions.

Sodium chloride (NaCl) or common table salt is known to corrode silver-copper alloy, typically seen in silver salt shakers where corrosion appears around the holes in the top.

Several products have been developed for the purpose of polishing silver that serve to remove sulfur
Sulfur

Sulfur or sulphur is the chemical element that has the atomic number 16. It is denoted with the symbol S. It is an abundant Valence non-metal....
 from the metal without damaging or warping it. Because harsh polishing and buffing can permanently damage and devalue a piece of antique silver, valuable items are typically hand-polished to preserve the unique patina
Patina

Patina is a film on the surface of bronze or similar metals ; a sheen on wooden furniture produced by age, wear, and polishing; or any such acquired change of a surface through age and exposure....
s of older pieces. Techniques such as wheel polishing, which are typically performed by professional jewelers or silver repair companies, are reserved for extreme tarnish or corrosion. See also Tarnish, Removal
Tarnish

Tarnish is a layer of corrosion that forms over copper, brass, silver, aluminum, and other semi-reactive metals as they undergo oxidation. It is analogous to rust, but with a slower rate of occurrence....
.

External links

  • , an award-winning site.
  • , a blog devoted to teaching about sterling silver, including how to care for it.