Solubility pump
Overview
 
In ocean
Ocean
An ocean is a major body of saline water, and a principal component of the hydrosphere. Approximately 71% of the Earth's surface is covered by ocean, a continuous body of water that is customarily divided into several principal oceans and smaller seas.More than half of this area is over 3,000...

ic biogeochemistry
Biogeochemistry
Biogeochemistry is the scientific discipline that involves the study of the chemical, physical, geological, and biological processes and reactions that govern the composition of the natural environment...

, the solubility pump is a physico-chemical process that transports carbon
Carbon
Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds...

 (as dissolved inorganic carbon) from the ocean's surface to its interior.
The solubility pump is driven by the coincidence of two processes in the ocean :
  • The solubility
    Solubility
    Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent to form a homogeneous solution of the solute in the solvent. The solubility of a substance fundamentally depends on the used solvent as well as on...

     of carbon dioxide
    Carbon dioxide
    Carbon dioxide is a naturally occurring chemical compound composed of two oxygen atoms covalently bonded to a single carbon atom...

     is a strong inverse function of seawater temperature
    Sea surface temperature
    Sea surface temperature is the water temperature close to the oceans surface. The exact meaning of surface varies according to the measurement method used, but it is between and below the sea surface. Air masses in the Earth's atmosphere are highly modified by sea surface temperatures within a...

     (i.e. solubility is greater in cooler water)
  • The thermohaline circulation
    Thermohaline circulation
    The term thermohaline circulation refers to a part of the large-scale ocean circulation that is driven by global density gradients created by surface heat and freshwater fluxes....

     is driven by the formation of deep water at high latitudes where seawater is usually cooler and denser


Since deep water (that is, seawater in the ocean's interior) is formed under the same surface conditions that promote carbon dioxide solubility, it contains a higher concentration of dissolved inorganic carbon than one might otherwise expect.
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