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Sodium bromide
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Sodium bromide, also known as sedoneural is a salt with the formula NaBr, widely used as an anticonvulsant and a sedative in the late 19th and early 20th centuries. Its action is due to the bromide ion (potassium bromide is equally effective). It is a high-melting white, crystalline solid that resembles sodium chloride. It is a widely used source of the bromide ion.
is widely used in organic synthesis as a nucleophile to convert organochlorine compounds to organobromine derivatives, which are more usefully (selectively) reactive.
- NaBr + RCl ? RBr + NaCl
Sodium bromide can be used as a source of the chemical element bromine.

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Encyclopedia
Sodium bromide, also known as sedoneural is a salt with the formula NaBr, widely used as an anticonvulsant and a sedative in the late 19th and early 20th centuries. Its action is due to the bromide ion (potassium bromide is equally effective). It is a high-melting white, crystalline solid that resembles sodium chloride. It is a widely used source of the bromide ion.
Principal chemical reactions
NaBr is widely used in organic synthesis as a nucleophile to convert organochlorine compounds to organobromine derivatives, which are more usefully (selectively) reactive.
- NaBr + RCl ? RBr + NaCl
Sodium bromide can be used as a source of the chemical element bromine. This can be accomplished by bubbling chlorine gas through an aqueous solution of NaBr.
As a source of HBr, NaBr is treated with a strong, non-volatile acid:
- NaBr + H3PO4 ? HBr + NaH2PO4
HBr can also be oxidized to Br2 using MnO2 or concentrated H2SO4.
Other applications
Safety
NaBr is harmful if swallowed or inhaled in large amounts, affecting the central nervous system, brain, and eyes (see potassium bromide). The chemical compound causes irritation to the skin, eyes and respiratory system.
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