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Silicon tetrafluoride

 

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Silicon tetrafluoride


 
 

Silicon tetrafluoride is the chemical compoundChemical compound

A chemical compound is a chemical substance consisting of two or more different chemically bonded chemical elements, with a ...
 with the formula SiFacts About Silicon

Silicon is the chemical element in the periodic table that has the symbol Si and atomic number 14....
FFluorine

Fluorine , is the chemical element in the periodic table that has the symbol F and atomic number 9....
4. This tetrahedral molecule is striking because it has a remarkably narrow liquid range (its boiling point is only 4 °C above its melting point). It was first synthesized by John DavyJohn Davy (chemist)

John Davy was a British doctor and amateur chemist, and brother of the noted chemist Sir Humphry Davy....
 in 1812.

Preparation

SiF4 is a by-product of the production of phosphatePhosphate Overview

In inorganic chemistry, a phosphate is a salt of phosphoric acid....
 fertilizerFertilizer

Fertilizers or fertilisers are compounds given to plants with the intention of promoting growth; they are usually app...
s, resulting from the attack of HFHF

HF, Hf or hf can refer to:...
 (derived from fluoroapatite protonolysis) on silicateSilicate

In chemistry, a silicate is a compound containing an anion in which one or more central silicon atoms are surrounded by elec...
s. In the laboratory, the compound is prepared by heating BaSiF6 >300 °C, whereupon the solid releases volatile SiF4, leaving a residue of BaF2. The required BaSiF6 is prepared by treating aqueous fluorosilicic acidDihydrogen hexafluorosilicate

Dihydrogen hexafluorosilicate is commonly used for Water fluoridation in the United States. ...
 with barium chlorideBarium chloride

Barium chloride is the chemical compound with the formula BaCl2....
. The corresponding GeF4 is prepared analogously, except that the thermal "cracking" requires 700 °C.

Uses

This volatileVolatility (chemistry)

Volatility in chemistry is speed that a chemical compound evaporates....
 compound finds limited use in microelectronics and organic synthesisOrganic synthesis

Organic synthesis is the construction of organic molecules via chemical processes....
.

Occurrence

Vulcanic plumes contain significant amounts of silicon tetrafluoride, the daily production can reach several tonns per day. The silicon tetrafluoride is partly hydrolysed and forms hexafluorosilicic acid.