Sienna
Encyclopedia
Sienna is a form of limonite
Limonite
Limonite is an ore consisting in a mixture of hydrated iron oxide-hydroxide of varying composition. The generic formula is frequently written as FeO·nH2O, although this is not entirely accurate as limonite often contains a varying amount of oxide compared to hydroxide.Together with hematite, it has...

 clay
Clay
Clay is a general term including many combinations of one or more clay minerals with traces of metal oxides and organic matter. Geologic clay deposits are mostly composed of phyllosilicate minerals containing variable amounts of water trapped in the mineral structure.- Formation :Clay minerals...

 most famous in the production of oil paint pigment
Pigment
A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, in which a material emits light.Many materials selectively absorb...

s. Its yellow-brown colour comes from ferric oxides contained within. As a natural pigment, it (along with its chemical cousins ochre
Ochre
Ochre is the term for both a golden-yellow or light yellow brown color and for a form of earth pigment which produces the color. The pigment can also be used to create a reddish tint known as "red ochre". The more rarely used terms "purple ochre" and "brown ochre" also exist for variant hues...

 and umber
Umber
Umber is a natural brown clay pigment which contains iron and manganese oxides. The color becomes more intense when calcined , and the resulting pigment is called burnt umber. Its name derives from the Latin word umbra and was originally extracted in Umbria, a mountainous region of central Italy,...

) was one of the first pigments to be used by humans, and is found in many cave paintings.

Variants

Sienna, in and of itself, is sometimes referred to as "raw sienna", in order to differentiate it from "burnt sienna", which is a more common pigment than the raw form. The difference is in the process applied to create burnt sienna, which is raw sienna heated to remove the water from the clay and give it a warm reddish-brown colour. The name of this pigment was classically referred to by the French
French language
French is a Romance language spoken as a first language in France, the Romandy region in Switzerland, Wallonia and Brussels in Belgium, Monaco, the regions of Quebec and Acadia in Canada, and by various communities elsewhere. Second-language speakers of French are distributed throughout many parts...

 term, "terre de Sienne brulée".

The name derives from the most notable Renaissance
Renaissance
The Renaissance was a cultural movement that spanned roughly the 14th to the 17th century, beginning in Italy in the Late Middle Ages and later spreading to the rest of Europe. The term is also used more loosely to refer to the historical era, but since the changes of the Renaissance were not...

 location for the earth, Siena
Siena
Siena is a city in Tuscany, Italy. It is the capital of the province of Siena.The historic centre of Siena has been declared by UNESCO a World Heritage Site. It is one of the nation's most visited tourist attractions, with over 163,000 international arrivals in 2008...

, Italy
Italy
Italy , officially the Italian Republic languages]] under the European Charter for Regional or Minority Languages. In each of these, Italy's official name is as follows:;;;;;;;;), is a unitary parliamentary republic in South-Central Europe. To the north it borders France, Switzerland, Austria and...

, and is short for terra di Siena, "earth of Siena". The mines used to produce this sienna petered out in the 1940s. Much of today's sienna production is still carried out in the Italian islands
Insular Italy
Insular Italy is one of the five official statistical regions of Italy used by the National Institute of Statistics , a first level NUTS region and a European Parliament constituency. Insular Italy encompasses two of the country's 20 regions:...

 of Sardinia
Sardinia
Sardinia is the second-largest island in the Mediterranean Sea . It is an autonomous region of Italy, and the nearest land masses are the French island of Corsica, the Italian Peninsula, Sicily, Tunisia and the Spanish Balearic Islands.The name Sardinia is from the pre-Roman noun *sard[],...

 and Sicily
Sicily
Sicily is a region of Italy, and is the largest island in the Mediterranean Sea. Along with the surrounding minor islands, it constitutes an autonomous region of Italy, the Regione Autonoma Siciliana Sicily has a rich and unique culture, especially with regard to the arts, music, literature,...

, while other major deposits are found in the Appalachian Mountains
Appalachian Mountains
The Appalachian Mountains #Whether the stressed vowel is or ,#Whether the "ch" is pronounced as a fricative or an affricate , and#Whether the final vowel is the monophthong or the diphthong .), often called the Appalachians, are a system of mountains in eastern North America. The Appalachians...

, where it often goes hand-in-hand with the region's iron
Iron
Iron is a chemical element with the symbol Fe and atomic number 26. It is a metal in the first transition series. It is the most common element forming the planet Earth as a whole, forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust...

 deposits.

Many of these deposits date back to the Precambrian
Precambrian
The Precambrian is the name which describes the large span of time in Earth's history before the current Phanerozoic Eon, and is a Supereon divided into several eons of the geologic time scale...

, and are pointed to as evidence of the Snowball Earth
Snowball Earth
The Snowball Earth hypothesis posits that the Earth's surface became entirely or nearly entirely frozen at least once, some time earlier than 650 Ma . Proponents of the hypothesis argue that it best explains sedimentary deposits generally regarded as of glacial origin at tropical...

 hypothesis.

Burnt sienna

Burnt sienna is an iron oxide
Iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. All together, there are sixteen known iron oxides and oxyhydroxides.Iron oxides and oxide-hydroxides are widespread in nature, play an important role in many geological and biological processes, and are widely utilized by humans, e.g.,...

 pigment
Pigment
A pigment is a material that changes the color of reflected or transmitted light as the result of wavelength-selective absorption. This physical process differs from fluorescence, phosphorescence, and other forms of luminescence, in which a material emits light.Many materials selectively absorb...

: a warm mid brown colour. Chemically, burnt sienna is formed by burning raw sienna
Sienna
Sienna is a form of limonite clay most famous in the production of oil paint pigments. Its yellow-brown colour comes from ferric oxides contained within...

(Terra di Siena Naturale).

Dark sienna

This infobox shows the color Dark Sienna
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