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Rankine cycle



 
 
The Rankine cycle is a thermodynamic
Thermodynamics

In physics, thermodynamics is the study of the conversion of heat energy into different forms of energy ; different energy conversions into heat energy; and its relation to macroscopic variables such as temperature, pressure, and volume....
 cycle which converts heat into work. The heat is supplied externally to a closed loop, which usually uses water as the working fluid. This cycle generates about 80% of all electric power used throughout the world., including virtually all solar thermal, biomass
Biomass

Biomass, as a renewable energy source, refers to living and recently dead biological material that can be used as fuel or for industrial production....
, coal and nuclear power plants. It is named after William John Macquorn Rankine
William John Macquorn Rankine

William John Macquorn Rankine Fellow of the Royal Society was a Scottish engineering and physics. He was a founding contributor, with Rudolf Clausius and William Thomson, 1st Baron Kelvin , to the science of thermodynamics....
, a Scottish polymath
Polymath

A polymath is a person whose knowledge is not restricted to one subject area. In less formal terms, a polymath may simply refer to someone who is very knowledgeable....
.

nkine cycle describes a model of the operation of steam heat engines most commonly found in power generation plants.






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Encyclopedia


The Rankine cycle is a thermodynamic
Thermodynamics

In physics, thermodynamics is the study of the conversion of heat energy into different forms of energy ; different energy conversions into heat energy; and its relation to macroscopic variables such as temperature, pressure, and volume....
 cycle which converts heat into work. The heat is supplied externally to a closed loop, which usually uses water as the working fluid. This cycle generates about 80% of all electric power used throughout the world., including virtually all solar thermal, biomass
Biomass

Biomass, as a renewable energy source, refers to living and recently dead biological material that can be used as fuel or for industrial production....
, coal and nuclear power plants. It is named after William John Macquorn Rankine
William John Macquorn Rankine

William John Macquorn Rankine Fellow of the Royal Society was a Scottish engineering and physics. He was a founding contributor, with Rudolf Clausius and William Thomson, 1st Baron Kelvin , to the science of thermodynamics....
, a Scottish polymath
Polymath

A polymath is a person whose knowledge is not restricted to one subject area. In less formal terms, a polymath may simply refer to someone who is very knowledgeable....
.

Description


A Rankine cycle describes a model of the operation of steam heat engines most commonly found in power generation plants. Common heat sources for power plants using the Rankine cycle are coal
Coal

Coal is a readily combustion black or brownish-black sedimentary rock. The harder forms, such as anthracite, can be regarded as metamorphic rock because of later exposure to elevated temperature and pressure....
, natural gas
Natural gas

Natural gas is a gas consisting primarily of methane. It is found associated with fossil fuels, in coal beds, as methane clathrates, and is created by methanogenic organisms in marshes, bogs, and landfills....
, oil
Oil

An oil is a chemical substance that is in a viscosity liquid state at room temperature or slightly warmer, and is both hydrophobic and lipophilic ....
, and nuclear
Nuclear power

Nuclear power is any nuclear technology designed to extract usable energy from atomic nucleus via controlled nuclear reactions. The only method in use today is through nuclear fission, though other methods might one day include nuclear fusion and radioactive decay ....
.

The Rankine cycle is sometimes referred to as a practical Carnot cycle
Carnot cycle

The Carnot cycle is a particular thermodynamic cycle, modeled on the hypothetical Carnot heat engine, proposed by Nicolas L?onard Sadi Carnot in 1824 and expanded upon by ?mile Clapeyron in the 1830s and 40s....
 as, when an efficient turbine is used, the TS diagram
Carnot cycle

The Carnot cycle is a particular thermodynamic cycle, modeled on the hypothetical Carnot heat engine, proposed by Nicolas L?onard Sadi Carnot in 1824 and expanded upon by ?mile Clapeyron in the 1830s and 40s....
 will begin to resemble the Carnot cycle. The main difference is that a pump is used to pressurize liquid instead of gas. This requires about 100 times less energy than that compressing a gas in a compressor (as in the Carnot cycle
Carnot cycle

The Carnot cycle is a particular thermodynamic cycle, modeled on the hypothetical Carnot heat engine, proposed by Nicolas L?onard Sadi Carnot in 1824 and expanded upon by ?mile Clapeyron in the 1830s and 40s....
).

The efficiency of a Rankine cycle is usually limited by the working fluid. Without the pressure going super critical
Critical point (thermodynamics)

In physical chemistry, thermodynamics, chemistry and condensed matter physics, a critical point, also called a critical state, specifies the conditions at which a phase boundary ceases to exist....
 the temperature range the cycle can operate over is quite small, turbine entry temperatures are typically 565°C (the creep
Creep (deformation)

Creep is the tendency of a solid material to slowly move or deform permanently under the influence of stress es. It occurs as a result of long term exposure to levels of stress that are below the yield strength of the material....
 limit of stainless steel) and condenser temperatures are around 30°C. This gives a theoretical Carnot efficiency of around 63% compared with an actual efficiency of 42% for a modern coal-fired power station. This low turbine entry temperature (compared with a gas turbine
Gas turbine

A gas turbine, also called a combustion turbine, is a rotary engine that extracts energy from a flow of combustion gas. It has an upstream compressor coupled to a downstream turbine, and a combustion chamber in-between....
) is why the Rankine cycle is often used as a bottoming cycle in combined cycle gas turbine
Combined cycle

A combined cycle is characteristic of a power producing engine or plant that employs more than one thermodynamic cycle. Heat engines are only able to use a portion of the energy their fuel generates ....
 power stations.

The working fluid in a Rankine cycle follows a closed loop and is re-used constantly. The water vapor
Vapor

A vapor or vapour is a substance in the gas phase at a temperature lower than its critical temperature.This means that the vapor can be condensation to a liquid or to a solid by increasing its pressure, without reducing the temperature....
 often seen billowing from power stations is generated by the cooling systems (not from the closed loop Rankine power cycle) and represents the waste heat that could not be converted to useful work. Note that steam
Steam

In physical chemistry, and in engineering, steam refers to vaporized water. It is a pure, completely invisible gaseous phase . At standard temperature and pressure, pure steam occupies about 1,600 times the volume of an equal mass of liquid water....
 is invisible until it comes in contact with cool, saturated air, at which point it condenses and forms the white billowy clouds seen leaving cooling towers. While many substances could be used in the Rankine cycle, water is usually the fluid of choice due to its favorable properties, such as nontoxic and unreactive chemistry, abundance, and low cost, as well as its thermodynamic properties.

One of the principal advantages it holds over other cycles is that during the compression stage relatively little work is required to drive the pump, due to the working fluid being in its liquid phase at this point. By condensing the fluid to liquid, the work required by the pump will only consume approximately 1% to 3% of the turbine power and so give a much higher efficiency for a real cycle. The benefit of this is lost somewhat due to the lower heat addition temperature. Gas turbine
Gas turbine

A gas turbine, also called a combustion turbine, is a rotary engine that extracts energy from a flow of combustion gas. It has an upstream compressor coupled to a downstream turbine, and a combustion chamber in-between....
s, for instance, have turbine entry temperatures approaching 1500°C. Nonetheless, the efficiencies of steam cycles and gas turbines are fairly well matched.

Processes of the Rankine cycle


There are four processes in the Rankine cycle, each changing the state of the working fluid. These states are identified by number in the diagram to the right.

  • Process 1-2: The working fluid is pumped from low to high pressure, as the fluid is a liquid at this stage the pump requires little input energy.
  • Process 2-3: The high pressure liquid enters a boiler where it is heated at constant pressure by an external heat source to become a dry saturated vapor.
  • Process 3-4: The dry saturated vapor expands through a turbine
    Turbine

    A turbine is a rotary engine that extracts energy from a fluid flow. Claude Burdin coined the term from the Latin turbo, or vortex, during an 1828 engineering competition....
    , generating power. This decreases the temperature and pressure of the vapor, and some condensation may occur.
  • Process 4-1: The wet vapor then enters a condenser where it is condensed at a constant pressure and temperature to become a saturated liquid
    Boiling point

    The boiling point of a liquid is the temperature at which the vapor pressure of the liquid equals the environmental pressure surrounding the liquid....
    . The pressure and temperature of the condenser is fixed by the temperature of the cooling coils as the fluid is undergoing a phase-change
    Phase transition

    In thermodynamics, a phase transition is the transformation of a thermodynamic system from one phase to another.At phase-transition point, physical properties may undergo abrupt change- for instance, volume of the two phases may be vastly different....
    .


In an ideal Rankine cycle the pump and turbine would be isentropic, i.e., the pump and turbine would generate no entropy and hence maximize the net work output. Processes 1-2 and 3-4 would be represented by vertical lines on the Ts diagram and more closely resemble that of the Carnot cycle. The Rankine cycle shown here prevents the vapor ending up in the superheat region after the expansion in the turbine , which reduces the energy removed by the condensers.

Variables










Heat flow rate to or from the system (energy per unit time)
Mass flow rate
Mass flow rate

Mass flow rate is the mass of substance which passes through a given surface per unit time. Its physical unit is mass divided by time, so kilogram per second in SI units, and Slug per second or pound per second in US customary units....
 (mass per unit time)
Mechanical power
Power (physics)

In physics, power is the rate at which mechanical work is performed or energy is transmitted, or the amount of energy required or expended for a given unit of time....
 consumed by or provided to the system (energy per unit time)
Thermodynamic efficiency of the process (net power output per heat input, dimensionless)
Isentropic efficiency of the compression (feed pump) and expansion (turbine) processes, dimensionless
The "specific enthalpies
Enthalpy

In thermodynamics and chemistry, the enthalpy is a quotient or description of thermodynamic potential of a system, which can be used to calculate the heat transfer during a quasistatic process taking place in a closed system thermodynamic system under constant pressure....
" at indicated points on the T-S diagram
The final "specific enthalpy
Enthalpy

In thermodynamics and chemistry, the enthalpy is a quotient or description of thermodynamic potential of a system, which can be used to calculate the heat transfer during a quasistatic process taking place in a closed system thermodynamic system under constant pressure....
" of the fluid if the turbine were isentropic
The pressures before and after the compression process


Equations

Each of the first four equations is easily derived from the energy
Energy

In physics, energy is a scalar physical quantity that describes the amount of Work_ that can be performed by a force. Energy is an attribute of objects and systems that is subject to a conservation law....
 and mass balance
Mass balance

A mass balance is an application of conservation of mass to the analysis of physical systems. By accounting for material entering and leaving a system, mass flows can be identified which might have been unknown, or difficult to measure without this technique....
 for a control volume. The fifth equation defines the thermodynamic efficiency of the cycle as the ratio of net power output to heat input. As the work required by the pump is often around 1% of the turbine work output, equation 5 can be simplified.

  
 


Real Rankine cycle (non-ideal)

In a real Rankine cycle, the compression by the pump
Pump

A pump is a device used to move fluids, such as gases, liquids or Slurry. A pump displaces a volume by physical or mechanical action. One common misconception about pumps is the thought that they create pressure....
 and the expansion in the turbine
Turbine

A turbine is a rotary engine that extracts energy from a fluid flow. Claude Burdin coined the term from the Latin turbo, or vortex, during an 1828 engineering competition....
 are not isentropic. In other words, these processes are non-reversible and entropy
Entropy

In many branches of science, entropy is a measure of the disorder of a system. The concept of entropy is particularly notable as it is applied across physics, information theory and mathematics....
 is increased during the two processes. This somewhat increases the power
Power (physics)

In physics, power is the rate at which mechanical work is performed or energy is transmitted, or the amount of energy required or expended for a given unit of time....
 required by the pump and decreases the power generated by the turbine.

In particular the efficiency of the steam turbine will be limited by water droplet formation. As the water condenses, water droplets hit the turbine blades at high speed causing pitting and erosion, gradually decreasing the life of turbine blades and efficiency of the turbine. The easiest way to overcome this problem is by superheating the steam. On the Ts diagram above, state 3 is above a two phase region of steam and water so after expansion the steam will be very wet. By superheating, state 3 will move to the right of the diagram and hence produce a dryer steam after expansion.

Variations of the basic Rankine cycle

The overall thermodynamic efficiency (of almost any cycle) can be increased by raising the average heat
Heat

In physics and thermodynamics, heat is any transfer of energy from one body or thermodynamic system to another due to a difference in temperature....
 input temperature
Temperature

In physics, temperature is a physical property of a Physical system that underlies the common notions of hot and cold; something that feels hotter generally has the greater temperature....
  of that cycle. Increasing the temperature of the steam into the superheat region is a simple way of doing this. There are also variations of the basic Rankine cycle which are designed to raise the thermal efficiency of the cycle in this way; two of these are described below.

Rankine cycle with reheat


In this variation, two turbine
Turbine

A turbine is a rotary engine that extracts energy from a fluid flow. Claude Burdin coined the term from the Latin turbo, or vortex, during an 1828 engineering competition....
s work in series. The first accepts vapor
Vaporization

Vaporization of an element or compound is a phase transition from the liquid phase to gas phase. There are two types of vaporization: evaporation and boiling....
 from the boiler
Boiler

A boiler is a closed Pressure vessel in which water or other fluid is heated. The heated or vaporized fluid exits the boiler for use in various processes or heating applications....
 at high pressure. After the vapor has passed through the first turbine, it re-enters the boiler and is reheated before passing through a second, lower pressure turbine. Among other advantages, this prevents the vapor from condensing
Condensation

Condensation is the change of the physical state of aggregation of matter from gaseous phase into liquid phase. When the transition happens from the gaseous phase into the solid phase directly, bypassing the liquid phase the change is called Deposition , which is the opposite of sublimation....
 during its expansion which can seriously damage the turbine blades, and improves the efficiency of the cycle.

Regenerative Rankine cycle


The regenerative Rankine cycle is so named because after emerging from the condenser (possibly as a subcooled liquid
Subcooled liquid

Subcooled liquid is a liquid at a temperature lower than the saturation temperature at a given pressure. Compressed liquid is a synonymous term, but it stresses that the pressure is greater than the saturation pressure for the given temperature....
) the working fluid is heated by steam
Steam

In physical chemistry, and in engineering, steam refers to vaporized water. It is a pure, completely invisible gaseous phase . At standard temperature and pressure, pure steam occupies about 1,600 times the volume of an equal mass of liquid water....
 tapped from the hot portion of the cycle. On the diagram shown, the fluid at 2 is mixed with the fluid at 4 (both at the same pressure) to end up with the saturated liquid at 7. The Regenerative Rankine cycle (with minor variants) is commonly used in real power stations.

Another variation is where 'bleed steam' from between turbine stages is sent to feedwater heater
Feedwater heater

A feedwater heater is a power plant component used to pre-heat water delivered to a steam generating boiler. Preheating the feedwater reduces the irreversibilities involved in steam generation and therefore improves the thermodynamic efficiency of the system....
s to preheat the water on its way from the condenser to the boiler.

Organic Rankine Cycle


The organic Rankine cycle (ORC) uses an organic fluid such as pentane
Pentane

Pentane is any or one of the organic compounds with the chemical formula C5H12. This alkane is a component of some fuels and is employed as a specialty solvent in the laboratory....
 or butane
Butane

Butane, also called n-butane, is the unbranched alkane with four carbon atoms, CH3CH2CH2CH3....
 in place of water and steam. This allows use of lower-temperature heat sources, such as solar ponds, which typically operate at around 70–90 °C. The efficiency of the cycle is much lower as a result of the lower temperature range, but this can be worthwhile because of the lower cost involved in gathering heat at this lower temperature. Alternatively, fluids can be used that have boiling points above water, and this may have thermodynamic benefits.

The Rankine cycle does not restrict the working fluid in its definition, so the inclusion of an "organic" cycle is simply a marketing concept that should not be regarded as a separate thermodynamic cycle.

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