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Radon
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Radon is a chemical element with symbol Rn and atomic number 86. Radon is a colorless, odorless, tasteless, naturally occurring, radioactive noble gas that is formed from the decay of radium. It is one of the heaviest substances that remains a gas under normal conditions and is considered to be a health hazard. The most stable isotope, 222Rn, has a half-life of 3.8 days and is used in radiotherapy. While having been less studied by chemists due to its high radioactivity, there are a few known compounds of this generally unreactive element.
Because Radon has eight valence electrons, it is highly unreactive.
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Radon is a chemical element with symbol Rn and atomic number 86. Radon is a colorless, odorless, tasteless, naturally occurring, radioactive noble gas that is formed from the decay of radium. It is one of the heaviest substances that remains a gas under normal conditions and is considered to be a health hazard. The most stable isotope, 222Rn, has a half-life of 3.8 days and is used in radiotherapy. While having been less studied by chemists due to its high radioactivity, there are a few known compounds of this generally unreactive element.
Because Radon has eight valence electrons, it is highly unreactive. Some scientists have been able to make Radon react with other elements to form compounds.
Radon is a significant contaminant that affects indoor air quality worldwide. Radon gas from natural sources can accumulate in buildings, especially in confined areas such as the basement.
Radon can be found in some spring waters and hot springs.
According to the United States Environmental Protection Agency, radon is reportedly the second most frequent cause of lung cancer, after cigarette smoking; and radon-induced lung cancer the 6th leading cause of cancer death overall. According to the same sources, radon reportedly causes 21,000 lung cancer deaths per year in the United States.
History and etymology
Discovered in 1900 by Friedrich Ernst Dorn, radon was the third radioactive element to be discovered, after radium and polonium. In 1900 Dorn reported some experiments in which he noticed that radium compounds emanate a radioactive gas which he named Radium Emanation (Ra Em). Before that, in 1899, Pierre and Marie Curie observed that the "gas" emitted by radium remained radioactive for a month. Later that year, Robert B. Owens and Ernest Rutherford noticed variations when trying to measure radiation from thorium oxide. Rutherford noticed that the compounds of thorium continuously emit a radioactive gas which retain the radioactive powers for several minutes and called this gas "emanation" (from Latin "emanare" - to elapse and "emanatio" - expiration), and later Thorium Emanation (Th Em). In 1901, he demonstrated that the emanations are radioactive, but credited the Curies for the discovery of the element. In 1903, similar emanations were observed from actinium by André-Louis Debierne and were called Actinium Emanation (Ac Em).
Several names were suggested for these three gases: exradio, exthorio, and exactinio in 1904; radon, thoron, and akton in 1918; radeon, thoreon, and actineon in 1919, and eventually radon, thoron, and actinon in 1920. The likeness of the spectra of these three gases with those of argon, krypton, and xenon, and their observed chemical inertia led Sir William Ramsay to suggest in 1904 that the "emanations" might contain a new element of the noble gas family.
In 1910, Sir William Ramsay and Robert Whytlaw-Gray isolated radon, determined its density, and determined that it was the heaviest known gas. They wrote that "L'expression l'émanation du radium est fort incommode," (the expression of radium emanation is very awkward) and suggested the new name niton (Nt) (from the Latin "nitens" meaning "shining") in order to emphasize the property of gases that cause the phosphorescence of some substances, and in 1912 it was accepted by the International Commission for Atomic Weights. In 1923, the International Committee for Chemical Elements and International Union of Pure and Applied Chemistry (IUPAC) chose among the names radon (Rn), thoron (Tn), and actinon (An). Later, when isotopes were numbered instead of named, the element took the name of the most stable isotope, radon, while Tn became 220Rn and An 219Rn. As late as the 1960s, the element was also referred to simply as emanation. The first synthesized compound of radon, radon fluoride, was obtained in 1962.
The first major studies with radon and health occurred in the context of uranium mining, first in the Joachimsthal region of Bohemia and then in the Southwestern United States during the early Cold War. Because radon is a product of the radioactive decay of uranium, underground uranium mines may have high concentrations of radon. Many uranium miners in the Four Corners region contracted lung cancer and other pathologies as a result of high levels of exposure to radon in the mid-1950s. The increased number of incidences of lung cancer was particularly pronounced among Native American and Mormon miners, because those groups normally have low rates of lung cancer. Safety standards requiring expensive ventilation were not widely implemented or policed during this period.
The danger of radon exposure in dwellings was discovered in 1984 when Stanley Watras, an employee at the Limerick nuclear power plant in Pennsylvania, set off the radiation alarms on his way to work for two weeks while authorities searched for the source of the contamination. They found that the source was high levels of radon – about 100,000 Bq/m³ (2,700 pCi/L) – in his house's basement, and it was not related to the nuclear plant. The risks associated with living in his house were estimated to be equivalent to smoking 135 packs of cigarettes every day. Following this highly publicized event, national radon safety standards were set, and radon detection and ventilation became a standard homeowner concern.
Characteristics
At standard temperature and pressure, radon forms a monatomic gas with a density of 9.73 kg/m3, about 8 times the surface density of the Earth's atmosphere, 1.217 kg/m3, and is one of the heaviest gases at room temperature and the heaviest of the noble gases, excluding ununoctium. At standard temperature and pressure, radon is a colorless gas, but when it is cooled below its freezing point of , it has a brilliant phosphorescence which turns yellow as the temperature is lowered, and becomes orange-red as the air liquefies at temperatures below . Upon condensation, radon also glows because of the intense radiation it produces.
Natural radon concentrations in Earth's atmosphere are so low that radon-rich water in contact with the atmosphere will continually lose radon by volatilization. Hence, ground water has a higher concentration of 222Rn than surface water, because the radon is continuously produced by radioactive decay of 226Ra present in rocks. Likewise, the saturated zone of a soil frequently has a higher radon content than the unsaturated zone because of diffusional losses to the atmosphere.
Radon is a health hazard as exposure can cause lung cancer – it is, in fact, the second major cause of lung cancer after smoking. Radon as a terrestrial source of background radiation is of particular concern because, although on average it is very rare, this intensely radioactive element can be found in high concentrations in many areas of the world, where it represents a significant health hazard. Radon-222 has been classified by International Agency for Research on Cancer as being carcinogenic to humans.
Radon commercialization is regulated, but it is available in small quantities, at a price of almost $6,000 per mililitre. Because it is also radioactive and is a relatively unreactive chemical element, radon has few uses and is seldom used in academic research.
Isotopes
Radon has no stable isotopes. There are 34 radioactive isotopes that have been studied which range from an atomic mass of 195 to 228. The most stable isotope is 222Rn, which is a decay product of 226Ra. It has a half-life of 3.823 days and decomposes by alpha particle emission into 218Po. Among the decay daughters of this decay chain is also the highly unstable isotope 218Rn. The naturally occurring 226Ra is a product of the decay chain of 238U. This decay series (with half-lives) is:
- 238U (4.5 x 109 yr) ? 234Th (24.1 days) ? 234Pa (1.18 min) ? 234U (250,000 yr) ? 230Th (75,000 yr) ? 226Ra (1,600 yr) ? 222Rn (3.82 days) ? 218Po (3.1 min) ? 218At (1.5 s) ? 218Rn (35 ms) ? 214Pb (26.8 min) ? 214Bi (19.7 min) ? 214Po (164 µs) ? 210Pb (22.3 yr) ? 210Bi (5.01 days) ? 210Po (138 days) ? 206Pb (stable)
There are three other isotopes that have a half life of over an hour: 211Rn, 210Rn and 224Rn. The 220Rn isotope is a natural decay product of the most stable thorium isotope (232Th), named thoron. It has a half-life of 55.6 seconds and also emits alpha radiation. Similarly, 219Rn is derived from the most stable isotope of actinium (227Ac) — named “actinon” — and is an alpha emitter with a half-life of 3.96 seconds. No radon isotopes are part of the other major decay series, that of neptunium (237Np).
Chemistry
Radon is a member of the zero-valence elements that are called noble or inert gases. It is inert to most common chemical reactions, such as combustion, because the outer valence shell contains eight electrons. This produces a stable, minimum energy configuration in which the outer electrons are tightly bound. For example, an energy of more than 248 kcal/mol is required to extract one electron from its shells (also known as the first ionization energy). However, due to periodic trends, radon has a lower electronegativity than the element one period before it, xenon, and is therefore more reactive. Radon is sparingly soluble in water, but more soluble than that of lighter noble gases. Radon is appreciably more soluble in organic liquids than in water. Early studies concluded that the stability of radon hydrate should be of the same order as that of the hydrates of chlorine or sulfur dioxide (and significantly higher than the stability of the hydrate of hydrogen sulphide .
Because of its price and radioactivity, experimental chemical research is seldom performed with radon, and as a result there are very few reported compounds of radon, all either fluorides or oxides. Radon can be oxidized by a few powerful oxidizing agents such as , thus forming radon fluoride. It decomposes back to elements at a temperature of above 250°C. It has a low volatility and was thought to be . But because of the short half-life of radon and the radioactivity of its compounds, it has not been possible to study the compound in any detail. However, theoretical studies on this molecule have predicted that it should have a Rn-F bond distance of 2.08 A, and that the compound is thermodinamically more stable and less volatile than its lighter counterpart . The octahedral molecule was predicted to have an even lower enthalpy of formation than the difluoride. The [RnF]+ is believed to form by the reaction:
- Rn(g) + 2 ((s)) ? (s) + 2 (g)
Radon oxides are among the few other reported compounds of radon. The radon carbonyl RnCO has been predicted to be stable and to have a linear geometry. The molecules and RnXe were found to be significantly stabilized by spin-orbit couplings. Radon caged inside a fullerene has been proposed as a drug for tumors.
Occurrence
Natural
The average concentration of radon in the atmosphere is about 6 atoms of radon for each molecule in the air, or about 150 atoms in each mL of air. It can be found in some spring waters and hot springs. The towns of Boulder, Montana; Misasa; Bad Kreuznach, Germany; and the country of Japan have radium-rich springs which emit radon. The element emanates naturally from the ground all over the world, but particularly in regions with soils containing granite or shale. However, not all granitic regions are prone to high emissions of radon. The element emitted from the ground has been shown to accumulate in the air if there is a meteorological inversion and little wind. In some caves, increased radon concentration has been observed.
Radon is found in some petroleum. Because radon has a similar pressure and temperature curve as propane, and oil refineries separate petrochemicals based on their boiling points, the piping carrying freshly separated propane in oil refineries can become partially radioactive due to radon decay particles. Residues from the oil and gas industry often contain radium and its daughters. The sulfate scale from an oil well can be radium rich, while the water, oil, and gas from a well often contains radon. The radon decays to form solid radioisotopes which form coatings on the inside of pipework. An oil processing plant, the area of the plant where propane is processed, is often one of the more contaminated areas of the plant as radon has a similar boiling point as propane.
In 1971, Apollo 15 passed above the Aristarchus plateau on the Moon, and detected a significant rise in alpha particles thought to be caused by the decay of radon-222. The presence of radon-222 (222Rn) has been inferred later from data obtained from the Lunar Prospector alpha particle spectrometer.
Accumulation
Radon, along with the noble gases krypton and xenon, is also produced during the operation of nuclear power plants. A small fraction of it leaks out of the fuel, through the cladding, and into the cooling water, from which it is scavenged. It is then routed to a holding tank where it remains for a large number of half-lives. It is finally purged to the open air through a tall stack, which is carefully monitored for radiation level.
Radon collects over samples of radium-226 at a rate of about 0.001 cm3/day per gram of radium. The radon (222Rn) released into the air decays to 210Pb and other radioisotopes, the levels of 210Pb can be measured. The rate of deposition of this radioisotope is dependent on the weather. In the early part of the 20th century in the USA, gold which was contaminated with lead-210 entered the jewelry industry. This was from gold seeds which had held radon-222 that had been melted down after the radon had decayed. The daughters of the radon are still radioactive today.
Depending on how houses are built and ventilated, radon may accumulate in basements and dwellings. The highest average radon concentrations in the United States are found in Iowa and in the Appalachian Mountain areas in southeastern Pennsylvania. Some of the highest readings ever have been recorded in the Irish town of Mallow, County Cork, prompting local fears regarding lung cancer. Iowa has the highest average radon concentrations in the United States due to significant glaciation that ground the granitic rocks from the Canadian Shield and deposited it as soils making up the rich Iowa farmland. Many cities within the state, such as Iowa City, have passed requirements for radon-resistant construction in new homes. A study made in December 2004 noted that the counties surrounding Three Mile Island have the highest radon concentrations in the United States and that this may be the cause of the increased lung cancer noted in the region.
Industrial production
Radon is obtained as a by-product of uraniferous ores processing after transferring into 1% solutions of hydrochloric or hydrobromic acids. The gas mixture extracted from the solutions contains , , He, Rn, , and hydrocarbons. The mixture is purified by passing it over copper at 1000°K to remove the and the , and then KOH and are used to remove the acids and moisture by sorption. Radon is condensed by liquid nitrogen and purified from residue gases by sublimation.
Applications
Medical
It has been said that exposure to radon gas mitigates auto-immune diseases such as arthritis.
Radioactive water baths have been applied since 1906 in Jáchymov, Czech Republic, but even before radon discovery they were used in Bad Gastein, Austria. Radium-rich springs are also used in traditional Japanese onsen in Misasa, Tottori prefecture. Drinking therapy is applied in Bad Brambach, Germany. Inhalation therapy is carried out in Gasteiner-Heilstollen, Austria, in Kowary, Poland and in Boulder, Montana, United States. In the United States and Europe there are several "radon spas," where people sit for minutes or hours in a high-radon atmosphere in the belief that low doses of radiation will invigorate or energize them.
In addition to personal testimonies of arthritis relief and other benefits, there is some scientific evidence for this belief, known as hormesis. However, the general scientific community finds it unsubstantiated. There is no known biological mechanism by which such an effect could occur. In addition, it conflicts with the internationally recognized standard that there is no safe threshold for radiation exposure and that exposure should be limited to that "as low as reasonably achievable" (ALARA).
The radon gas which is used as a cancer treatment in medicine is obtained from the decay of a radium chloride source. In the past, radium and radon have both been used for X-ray medical radiography, but they have fallen out of use as they are radiotoxic alpha radiation emitters which are expensive and have been replaced with iridium-192 and cobalt-60 since they are far better photon sources.
Scientific
Radon emanation from the soil varies with soil type and with surface uranium content, so outdoor radon concentrations can be used to track air masses to a limited degree. This fact has been put to use by some atmospheric scientists. Because of radon's rapid loss to air and comparatively rapid decay, radon is used in hydrologic research that studies the interaction between ground water and streams. Any significant concentration of radon in a stream is a good indicator that there are local inputs of ground water. Radon is also used in the dating of oil-containing soils because radon has a high affinity of oil-like substances.
Radon soil-concentration has been used in an experimental way to map buried close-subsurface geological faults because concentrations are generally higher over the faults. Similarly, it has found some limited use in geothermal prospecting. Some researchers have also looked at elevated soil-gas radon concentrations, or rapid changes in soil or groundwater radon concentrations, as a predictor for earthquakes. Results have been generally unconvincing but may ultimately prove to have some limited use in specific locations.
Radon is a known pollutant emitted from geothermal power stations, though it disperses rapidly, and no radiological hazard has been demonstrated in various investigations. The trend in geothermal plants is to reinject all emissions by pumping deep underground, and this seems likely to ultimately decrease such radon hazards further.
Testing and mitigation
ASTM E-2121 is a standard for reducing radon in homes as far as practicable below 4 picocuries per liter (pCi/L) in indoor air. Radon test kits are commercially available. The kit includes a collector that the user hangs in the lowest livable floor of the house for 2 to 7 days. The user then sends the collector to a laboratory for analysis. The National Environmental Health Association provides a list of radon measurement professionals. Long term kits, taking collections for up to one year, are also available. An open-land test kit can test radon emissions from the land before construction begins. The EPA and the National Environmental Health Association have identified 15 types of radon testing. A Lucas cell is one type of device.
Radon levels fluctuate naturally. An initial test might not be an accurate assessment of a home's average radon level. Transient weather can affect short term measurements. Therefore, a high result (over 4 pc/l) justifies repeating the test before undertaking more expensive abatement projects. Measurements between 4 and 10 pc/l warrant a long term radon test. Measurements over 10 pc/l warrant only another short term test so that abatement measures are not unduly delayed. Purchasers of real estate are advised to delay or decline a purchase if the seller has not successfully abated radon to 4 pc/l or less.
The National Environmental Health Association administers a voluntary National Radon Proficiency Program for radon professionals consisting of individuals and companies wanting to take training courses and examinations to demonstrate their competency. A list of mitigation service providers is available. Indoor radon can be mitigated by sealing basement foundations, water drainage, or by sub-slab de-pressurization. In severe cases, mitigation can use air pipes and fans to exhaust sub-slab gases to the outside. Indoor ventilation systems are more effective, but exterior ventilation can be cost-effective in some cases.
The European Union recommends that action should be taken starting from concentrations of 400 Bq/m³ (11 pCi/L) for old houses and 200 Bq/m³ (5 pCi/L) for new ones. After publication of the North American and European Pooling Studies, Health Canada proposed a new guideline that lowers their action level from 800 to 200 Bq/m³ (22 to 5 pCi/L). The United States Environmental Protection Agency (EPA) strongly recommends action for any house with a concentration higher than 148 Bq/m³ (4 pCi/L), and encourages action starting at 74 Bq/m³ (2 pCi/L). EPA radon risk level tables including comparisons to other risks encountered in life are available in their citizen's guide. The EPA estimates that nationally, 8% to 12% of all houses are above their maximum "safe levels" (four picocuries per liter – the equivalent to roughly 200 chest x-rays). The United States Surgeon General and the EPA both recommend that all homes be tested for radon.
Positive-pressure ventilation systems can be combined with a heat exchanger to recover energy in the process of exchanging air with the outside, and simply exhausting basement air to the outside is not necessarily a viable solution as this can actually draw radon gas into a dwelling. Homes built on a crawl space may benefit from a radon collector installed under a "radon barrier" (a sheet of plastic that covers the crawl space).
Health risks and epidemiology
Radon is the invisible, radioactive mono-atomic gas that results from radioactive decay of some forms of uranium that may be found in rock formations beneath buildings or in certain building materials themselves. There are relatively simple tests for radon gas, but these tests are not commonly done, even in areas of known systematic hazards. Radon is a very heavy gas and thus will tend to accumulate at the floor level. Building materials can be a significant source of radon, but very little testing is done for stone, rock, or tile products brought into building sites. The half-life for radon is 3.8 days, indicating that once the source is removed, the hazard will be greatly reduced within a few weeks. Although radon may present significant risks, thousands of people annually go to radon-contaminated mines for deliberate exposure to help with the symptoms of arthritis without any serious health effects.
Radon is a colorless and odorless gas, and therefore not readily detectable by a human. The radiation decay products are thought to ionize genetic material, perhaps causing mutations that sometimes turn cancerous. Radon exposure is thought to be the second major cause of lung cancer after smoking. Radon gas levels vary by locality and the composition of the underlying soil and rocks. For example, in areas such as Cornwall in the UK, which has granite as substrata, radon gas is a major problem, and buildings have to be force-ventilated with fans to lower radon gas concentrations. The United States Environmental Protection Agency (EPA) estimates that one in 15 homes in the United States has radon levels above the recommended guideline of 4 picocuries per liter (pCi/L) (148 Bq/m³). Iowa has the highest average radon concentration in the United States; studies performed there have demonstrated a 50% increased lung cancer risk with prolonged radon exposure above the EPA's action level of 4 pCi/L.
Radon is a terrestrial source of radiation of particular concern because — although on average it is very rare — this intensely radioactive element can be found in high concentrations in many areas of the world, where it represents a significant health hazard. Radon is a decay product of uranium, which is relatively common in the Earth's crust, but generally concentrated in ore-bearing rocks scattered around the world. Radon seeps out of these ores into the atmosphere or into ground water, and in these localities it can accumulate within dwellings and expose humans to high concentrations. The widespread construction of well insulated and sealed homes in the northern industrialized world has led to radon becoming the primary source of background radiation in some localities in northern North America and Europe. Some of these areas, including Cornwall and Aberdeenshire in the United Kingdom have high enough natural radiation levels that nuclear licensed sites cannot be built there — the sites would already exceed legal radiation limits before they opened, and the natural topsoil and rock would all have to be disposed of as low-level nuclear waste.
Radiation exposure from radon is indirect. Radon has a short half-life (4 days) and decays into other solid particulate radium-series radioactive nuclides. These radioactive particles are inhaled and remain lodged in the lungs, causing continued exposure. People in affected localities can receive up to 10 mSv per year background radiation. Radon is thus the second leading cause of lung cancer after smoking, and accounts for 15,000 to 22,000 cancer deaths per year in the US alone. The general population is exposed to small amounts of polonium as a radon daughter in indoor air; the isotopes 214Po and 218Po are thought to cause the majority of the estimated 15,000–22,000 lung cancer deaths in the US every year that have been attributed to indoor radon.
The general effects of radon to the human body are caused by its radioactivity and consequent risk of radiation-induced cancer. As an inert gas, radon has a low solubility in body fluids, which leads to a uniform distribution of the gas throughout the body. Radon gas and its solid decay products are carcinogens. The greatest health risks come from exposure to the inhaled solid radon gas decay products that are produced during its radioactive decay. Two of these decay products, polonium-218 and 214, present a significant radiologic hazard. Once the radioactive decay products are inhaled into the lung, they undergo further radioactive decay, releasing small bursts of energy in the form of alpha particles that can either cause DNA breaks or create free radicals.
It is not known whether radon can cause health effects in other organs besides the lungs. The effects of radon, if found in food or drinking water, are unknown.
The largest single source of radiation exposure to the general public is naturally-occurring radon gas, which comprises approximately 55% of the annual background dose. The largest natural contributor to public radiation dose is radon, a naturally occurring, radioactive gas found in soil and rock. If the gas is inhaled, some of the radon particles may attach to the inner lining of the lung. These particles continue to decay, emitting alpha particles which can damage cells in the lung tissue. The death of Marie Curie at age 66 from leukemia was likely caused by prolonged exposure to high doses of ionizing radiation. Its discoverer, Curie worked extensively with radium, which decays into radon, along with other radioactive materials that emit beta and gamma rays.
In the United Kingdom, residential radon is, after cigarette smoking, the second most frequent cause of lung cancer deaths: 83.9% of deaths are attributed to smoking only, 1.0% to radon only, and 5.5% to a combination of radon and smoking. The United States Environmental Protection Agency (EPA) says that radon is the number one cause of lung cancer among non-smokers. Based on studies carried out by the National Academy of Sciences in the United States, radon is the second most common cause of lung cancer after cigarette smoking, accounting for 15,000 to 22,000 cancer deaths per year in the U.S. The Surgeon General of the United States has reported that over 20,000 Americans die each year of radon-related lung cancer. The EPA recommends homes be fixed if an occupant's long-term exposure will average 4 picocuries per liter (pCi/L) (148 Bq m-3) or higher. Beginning with the late 1980s, this led to activists forming campaigns to raise awareness of radiation resulting from radon.
The most elaborate case-control epidemiologic radon study performed by R. William Field and colleagues demonstrated a 50% increased lung cancer risk with prolonged radon exposure at the EPA's action level of 4 pCi/L. Iowa has the highest average radon concentrations in the nation and a very stable population which added to the strength of the study. Pooled epidemiologic radon studies have also shown an increased lung cancer risk from radon below the EPA's action level of 4 pCi/L.
Radiation from radon has been attributed to increase of lung cancer among smokers too. This is because the daughters of radon often become attached to smoke and dust particles, and are then able to lodge in the lungs. It is unknown whether radon causes other types of cancer, but recent studies suggest a need for further studies to assess the relationship between radon and leukemia. Radon is a common problem encountered during uranium mining, as it is a radioactive gas, inhalation of which caused sharp increases in lung cancers among uranium miners employed in the 1940s and 1950s.
The results of a methodical ten-year-long, case-controlled study of residential radon exposure in Worcester County, Massachusetts, found an apparent 60% reduction in lung cancer risk amongst people exposed to low levels (0–150 Bq/m3) of radon gas; levels typically encountered in 90% of American homes — an apparent support for the idea of radiation hormesis. The study paid close attention to the cohort's levels of smoking, occupational exposure to carcinogens and education attainment. However, unlike the majority of the residential radon studies, the study was not population-based. Errors in retrospective exposure assessment could not be ruled out in the finding at low levels.
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