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Propellant



 
 
A propellant is a material that is used to move ("propel") an object. This will often involve a chemical reaction. It may be a gas
Gas

In physics, a gas is a state of matter, consisting of a collection of particles without a definite shape or volume that are in more or less random motion....
, liquid
Liquid

Liquid is one of the principal states of matter. A liquid is a fluid that has the particles loose and can freely form a distinct surface at the boundaries of its bulk material....
, plasma
Plasma (physics)

In physics and chemistry, plasma is a partially ionized gas, in which a certain proportion of electrons are free rather than being bound to an atom or molecule....
, or, before the chemical reaction, a solid.

Common chemical propellants consist of a fuel, like gasoline
Gasoline

File:GasCan.jpgGasoline or petrol is a petroleum-derived liquid mixture, primarily used as fuel in internal combustion engines.It consists mostly of aliphatic hydrocarbons, enhanced with iso-octane or the aromatic hydrocarbons toluene and benzene to increase its octane rating....
, jet fuel
Jet fuel

Jet fuel is a type of aviation fuel designed for use in aircraft powered by Aircraft engine#Gas turbine engine configurations. It is clear to straw colored....
 and rocket fuel, and an oxidizer.

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Aerosol spray

Aerosol spray is a type of dispensing system which creates an Particulate mist of liquid particles. This is used with a spray can or bottle that contains a liquid under pressure....
 cans, the propellant is simply a pressurized gas in equilibrium with its liquid (at its saturated vapour pressure).






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A propellant is a material that is used to move ("propel") an object. This will often involve a chemical reaction. It may be a gas
Gas

In physics, a gas is a state of matter, consisting of a collection of particles without a definite shape or volume that are in more or less random motion....
, liquid
Liquid

Liquid is one of the principal states of matter. A liquid is a fluid that has the particles loose and can freely form a distinct surface at the boundaries of its bulk material....
, plasma
Plasma (physics)

In physics and chemistry, plasma is a partially ionized gas, in which a certain proportion of electrons are free rather than being bound to an atom or molecule....
, or, before the chemical reaction, a solid.

Common chemical propellants consist of a fuel, like gasoline
Gasoline

File:GasCan.jpgGasoline or petrol is a petroleum-derived liquid mixture, primarily used as fuel in internal combustion engines.It consists mostly of aliphatic hydrocarbons, enhanced with iso-octane or the aromatic hydrocarbons toluene and benzene to increase its octane rating....
, jet fuel
Jet fuel

Jet fuel is a type of aviation fuel designed for use in aircraft powered by Aircraft engine#Gas turbine engine configurations. It is clear to straw colored....
 and rocket fuel, and an oxidizer.

Aerosol sprays

In aerosol spray
Aerosol spray

Aerosol spray is a type of dispensing system which creates an Particulate mist of liquid particles. This is used with a spray can or bottle that contains a liquid under pressure....
 cans, the propellant is simply a pressurized gas in equilibrium with its liquid (at its saturated vapour pressure). As some gas escapes to expel the payload, more liquid evaporates, maintaining an even pressure. (See aerosol spray propellant
Aerosol spray

Aerosol spray is a type of dispensing system which creates an Particulate mist of liquid particles. This is used with a spray can or bottle that contains a liquid under pressure....
 for more information.)

Solid propellant rockets and projectiles

In ballistics
Ballistics

Ballistics is the science of mechanics that deals with the flight, behavior, and effects of projectiles, especially bullets, gravity bombs, rockets, or the like; the science or art of designing and accelerating projectiles so as to achieve a desired performance....
 and pyrotechnics
Pyrotechnics

Pyrotechnics is the science of materials capable of undergoing self-contained and self-sustained exothermic chemical reactions for the production of heat, light, gas, smoke and/or sound....
, a propellant is a generic name for chemicals used for propelling projectiles from guns and other firearms.

Propellants are nearly always chemically different from high explosives as used in shells
Shell (projectile)

A shell is a payload-carrying projectile, which, as opposed to Round shot, contains an explosive or other filling, though modern usage includes large solid projectiles previously termed shot ....
 and mines to produce a blasting effect. However, some explosive substances can be used both as propellants and as bursters, as for example gunpowder
Gunpowder

Gunpowder, also called black powder, is an explosive mixture of sulfur, charcoal and potassium nitrate, KNO3 that burns rapidly, producing volumes of hot solids and gases which can be used as a propellant in firearms and as a pyrotechnic composition in fireworks....
, and some of the ingredients of a propellant may be similar, though differently proportioned and combined, to those of an explosive.

A very typical propellant burns rapidly but controllably and non explosively, to produce thrust
Thrust

Thrust is a reaction force described quantitatively by Isaac Newton's Newton's laws of motion. When a system expels or acceleration mass in one direction the accelerated mass will cause a proportional but opposite force on that system....
 by gas
Gas

In physics, a gas is a state of matter, consisting of a collection of particles without a definite shape or volume that are in more or less random motion....
 pressure
Pressure

Pressure is the force per unit area applied to an object in a direction surface normal to the surface. Gauge pressure is the pressure relative to the local atmospheric or ambient pressure....
 and thus accelerates a projectile
Projectile

A projectile is any object propelled through space by the exertion of a force, which ceases after launch. In a general sense, even a Football or baseball may be considered a projectile....
 or rocket
Rocket

A rocket or rocket vehicle is a missile, aircraft or other vehicle which obtains thrust by the Reaction of the rocket to the ejection of fast moving fluid exhaust from a rocket engine....
. In this sense, common or well known propellants include, for firearm
Firearm

A firearm is a tool that projects either single or multiple projectiles at high velocity through a controlled explosion. The firing is achieved by the gases produced through rapid, confined combustion of a propellant....
s, artillery
Artillery

Artillery is a military Combat Arms which employs any apparatus, machine, an assortment of tools or instruments, a system or systems used as weapons for the discharge of large projectiles in combat as a major contribution of fire power within the overall military capability of an armed force....
 and solid propellant rocket
Solid rocket

A solid rocket or a solid-fuel rocket is a rocket with a motor that uses Rocket fuel#Solid propellants . The earliest rockets were solid fueled, powered by gunpowder, used by the Science and technology in China and Inventions in the Muslim world in warfare as early as the 13th century....
s:
  • Gun propellants, such as:
    • Gunpowder
      Gunpowder

      Gunpowder, also called black powder, is an explosive mixture of sulfur, charcoal and potassium nitrate, KNO3 that burns rapidly, producing volumes of hot solids and gases which can be used as a propellant in firearms and as a pyrotechnic composition in fireworks....
       (black powder)
    • Nitrocellulose
      Nitrocellulose

      Nitrocellulose is a highly flammable compound formed by nitrating cellulose through exposure to nitric acid or another powerful nitrating agent....
      -based powders
    • Cordite
      Cordite

      Cordite is a family of smokeless powder developed and produced in the United Kingdom from 1889 to replace gunpowder as a military propellant....
    • Ballistite
      Ballistite

      Ballistite is a smokeless powder made from two high explosives, nitrocellulose and nitroglycerin , nitroglycerin . It was developed and patented by Alfred Nobel in the late 19th century....
    • Smokeless powder
      Smokeless powder

      Smokeless powder is the name given to a number of propellants used in firearms and artillery which produce negligible smoke when fired, unlike the older gunpowder which they replaced....
      s
  • Composite propellants made from a solid oxidizer such as ammonium perchlorate
    Ammonium perchlorate

    Ammonium perchlorate is a chemical compound with the formula NitrogenHydrogen4ChlorineOxygen4.It is the salt of ammonia and perchloric acid....
     or ammonium nitrate
    Ammonium nitrate

    The chemical compound ammonium nitrate, the nitrate of ammonia with the chemical formula NitrogenHydrogen4NitrogenOxygen3, is a white powder at room temperature and standard pressure....
    , a rubber such as HTPB or PBAN
    PBAN

    PBAN - Polybutadiene Acrylonitrile copolymer. Also noted as Polybutadiene — Acrylic acid — Acrylonitrile terpolymer.This was the binder formulation widely used on the 1960-70's big booster rocket ....
    , and usually a powdered metal
    Metal

    In chemistry, a metal is a chemical element whose atoms readily lose electrons to form positive ions , and form metallic bonds between other metal atoms and ionic bonds between nonmetal atoms....
     fuel
    Fuel

    Fuel is any material that is burned or altered in order to obtain energy and to heat or to move an object. Fuel releases its energy either through a chemical reaction means, such as combustion, or nuclear means, such as nuclear fission or nuclear fusion....
     such as aluminum.
  • Some amateur
    Amateur rocketry

    File:Model rocket launch 2 .jpgAmateur rocketry, sometimes known as amateur experimental rocketry or experimental rocketry is a hobby in which participants experiment with fuels and make their own rocket motors, launching a wide variety of types and sizes of rockets....
     propellants use potassium nitrate
    Potassium nitrate

    Potassium nitrate is a chemical compound with the chemical formula PotassiumNitrogenOxygen3. A naturally occurring mineral source of nitrogen, KNO3 constitutes a critical oxidation component of black powder/gunpowder....
    , combined with sugar
    Sugar

    Sugar is a class of edible crystalline substances, mainly sucrose, lactose, and fructose. Human taste buds interpret its flavor as sweet. Sugar as a basic food carbohydrate primarily comes from sugar cane and from sugar beet, but also appears in fruit, honey, sorghum, sugar maple , and in many other sources....
    , epoxy
    Epoxy

    In chemistry, epoxy or polyepoxide is a thermosetting epoxide polymer that cures when mixed with a catalyst agent or hardener. Most common epoxy resins are produced from a reaction between epichlorohydrin and bisphenol-A....
    , or other fuels / binder compounds.
  • Potassium perchlorate
    Potassium perchlorate

    Potassium perchlorate is the inorganic salt with the chemical formula potassiumchlorineoxygen. Like other a perchlorates, this salt is a strong oxidizing agent....
     has been used as an oxidizer, paired with asphalt
    Asphalt

    Asphalt is a sticky, black and highly viscosity liquid or semi-solid that is present in most crude petroleums and in some natural deposits sometimes termed asphaltum....
    , epoxy
    Epoxy

    In chemistry, epoxy or polyepoxide is a thermosetting epoxide polymer that cures when mixed with a catalyst agent or hardener. Most common epoxy resins are produced from a reaction between epichlorohydrin and bisphenol-A....
    , and other binders.


Propellants that explode in operation are of little practical use currently, although there have been experiments with Pulse Detonation Engine
Pulse detonation engine

A pulse-detonation engine, or "PDE", is a type of Air propulsion system that can operate from subsonic up to hypersonic speeds. In theory the PDE design can produce an engine with a burn Fuel efficiency higher than other designs, with considerably fewer moving parts....
s.

Aircraft and rockets

Technically, the word propellant is the general name for chemicals used to create thrust. The term propellant refers only to chemicals that are stored within the vehicle prior to use, and excludes atmospheric gas or other material that may be collected in operation.

Amongst the English-speaking lay public, used to having fuels propel vehicles on Earth, the word fuel is inappropriately used. In Germany, the word Treibstoff—literally "drive-stuff"—is used; in France, the word ergols is used; it has the same Greek roots as hypergolic, a term used in English for propellants which combine spontaneously and do not have to be set ablaze by auxiliary ignition system.

In rocket
Rocket

A rocket or rocket vehicle is a missile, aircraft or other vehicle which obtains thrust by the Reaction of the rocket to the ejection of fast moving fluid exhaust from a rocket engine....
s the most common combinations are bipropellants, which use two chemicals, a fuel and an oxidiser. There is the possibility of a tripropellant combination, which takes advantage of the ability of substances with smaller atoms to attain a greater exhaust velocity, and hence propulsive efficiency, at a given temperature.

Although not used in practice, the most developed tripropellant systems involves adding a third propellant tank containing liquid hydrogen to do this.

Common propellant combinations used for liquid propellant rockets include:
  • RFNA and kerosene
    Kerosene

    Kerosene, sometimes spelled kerosine in scientific and industrial usage, also known as paraffin, is a combustible hydrocarbon liquid....
     or RP-1
    RP-1

    RP-1 is a highly refined form of kerosene outwardly similar to jet fuel, used as a rocket fuel. Although having a lower specific impulse than liquid hydrogen and thus less thrust per unit mass, RP-1 is cheaper, can be stored at room temperature, is far less of an explosive hazard and is far more dense....
  • RFNA and UDMH
    UDMH

    Unsymmetrical dimethylhydrazine is a toxic volatile hygroscopic clear liquid, with a sharp, fishy, ammoniacal smell typical for organic amines....
  • Dinitrogen tetroxide
    Dinitrogen tetroxide

    Dinitrogen tetroxide is the chemical compound N2O4. It forms an Chemical equilibrium with nitrogen dioxide; some call this mixture dinitrogen tetroxide, some call it nitrogen dioxide....
     and UDMH
    UDMH

    Unsymmetrical dimethylhydrazine is a toxic volatile hygroscopic clear liquid, with a sharp, fishy, ammoniacal smell typical for organic amines....
    , MMH
    MMH

    MMH may refer to:* Monomethylhydrazine, a chemical with the formula CH3N2H3.* The IATA location identifier for Mammoth Yosemite Airport....
     and/or Hydrazine
    Hydrazine

    Hydrazine is a chemical compound with the chemical formula N2H4. It is a colourless liquid with an ammonia-like odor and is derived from the same industrial chemistry processes that manufacture ammonia....
  • Liquid oxygen
    Liquid oxygen

    Liquid oxygen is a form of the element oxygen. It has a pale blue color and is strongly paramagnetism. Liquid oxygen has a density of 1.141 g/cm? and is moderately cryogenics ...
     and kerosene
    Kerosene

    Kerosene, sometimes spelled kerosine in scientific and industrial usage, also known as paraffin, is a combustible hydrocarbon liquid....
     or RP-1
    RP-1

    RP-1 is a highly refined form of kerosene outwardly similar to jet fuel, used as a rocket fuel. Although having a lower specific impulse than liquid hydrogen and thus less thrust per unit mass, RP-1 is cheaper, can be stored at room temperature, is far less of an explosive hazard and is far more dense....
  • Liquid oxygen
    Liquid oxygen

    Liquid oxygen is a form of the element oxygen. It has a pale blue color and is strongly paramagnetism. Liquid oxygen has a density of 1.141 g/cm? and is moderately cryogenics ...
     and liquid hydrogen
    Hydrogen

    Hydrogen is the chemical element with atomic number 1. It is represented by the chemical symbol H. At standard temperature and pressure, hydrogen is a colorless, odorless, nonmetallic, tasteless, highly combustion and explosive Diatomic molecule gas with the molecular formula H2....
  • Hydrogen Peroxide
    Hydrogen peroxide

    Hydrogen peroxide is a very pale blue liquid which appears colorless in a dilute solution, slightly more viscous than water. It is a weak acid....
     and alcohol
    Alcohol

    In chemistry, an alcohol is any organic compound in which a hydroxyl Functional group is bound to a carbon atom of an alkyl or substituted alkyl group....
     or RP-1
    RP-1

    RP-1 is a highly refined form of kerosene outwardly similar to jet fuel, used as a rocket fuel. Although having a lower specific impulse than liquid hydrogen and thus less thrust per unit mass, RP-1 is cheaper, can be stored at room temperature, is far less of an explosive hazard and is far more dense....
  • Chlorine pentafluoride
    Chlorine pentafluoride

    Chlorine pentafluoride has formula ClF5. It was first synthesized in 1963.Its square pyramidal structure with C4v symmetry was confirmed by its high resolution19F NMR spectrum....
     & Hydrazine
    Hydrazine

    Hydrazine is a chemical compound with the chemical formula N2H4. It is a colourless liquid with an ammonia-like odor and is derived from the same industrial chemistry processes that manufacture ammonia....


Sources and references

(incomplete)

See also

  • Fuel
    Fuel

    Fuel is any material that is burned or altered in order to obtain energy and to heat or to move an object. Fuel releases its energy either through a chemical reaction means, such as combustion, or nuclear means, such as nuclear fission or nuclear fusion....
  • Spacecraft propulsion
    Spacecraft propulsion

    Spacecraft propulsion is any method used to accelerate spacecraft and artificial satellites. There are many different methods. Each method has drawbacks and advantages, and spacecraft propulsion is an active area of research....
  • Specific impulse
    Specific impulse

    Specific impulse is a way to describe the efficiency of rocket engine and jet engine engines. It represents the impulse per unit of propellant....