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Polyvinyl acetate

 

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Polyvinyl acetate



 
 
Polyvinyl acetate (PVA or PVAc) is a rubber
Rubber

Natural rubber is an elastomer?an Elasticity_ hydrocarbon polymer?that was originally derived from a milky colloidal suspension, or latex , found in the sap of some plants....
y synthetic polymer
Synthetic polymer

Synthetic polymers are often referred to as "plastics", such as the well-known polyethylene and nylon. However, most of them can be classified in at least three main categories: thermoplastics, thermosets and elastomers....
. PVA is a common copolymer.

It is prepared by polymerization
Polymerization

In polymer chemistry, polymerization is a process of reacting monomer molecules together in a chemical reaction to form three-dimensional networks or polymer chains....
 of vinyl acetate monomer
Vinyl acetate

Vinyl acetate is an organic compound with the Chemical formula CH3COOCH=CH2. A colorless liquid with a pungent odor, it is the precursor to polyvinyl acetate , an important polymer in industry....
, also referred to as VAM. Partial or complete hydrolysis
Hydrolysis

Hydrolysis is a chemical reaction during which one or more water are split into hydrogen and hydroxide ions which may go on to participate in further reactions....
 of the polymer is used to prepare polyvinyl alcohol
Polyvinyl alcohol

Polyvinyl alcohol is a water-soluble synthetic polymer....
. Hydroylized alcohol
Alcohol

In chemistry, an alcohol is any organic compound in which a hydroxyl Functional group is bound to a carbon atom of an alkyl or substituted alkyl group....
 product is typically in the 87% to 99% range (converted PVA).

as discovered in Germany
Germany

Germany , officially the Federal Republic of Germany , is a country in Central Europe. It is bordered to the north by the North Sea, Denmark, and the Baltic Sea; to the east by Poland and the Czech Republic; to the south by Austria and Switzerland; and to the west by France, Luxembourg, Belgium, and the Netherlands....
 in 1912 by Dr. Fritz Klatte
Fritz Klatte

Fritz Klatte was a German chemist and the discoverer of polyvinyl acetate, with German patent for its preparation from acetylene gas.Polyvinyl chloride was discovered by French physicist Henri Victor Regnault, and German physicist Eugen Baumann....
 with the help of his assistant James Michael Fairholm.

n emulsion
Emulsion

An emulsion is a mixture of two immiscible liquids. One liquid is dispersion in the other . Many emulsions are oil/water emulsions, with dietary fats being one common type of oil encountered in everyday life....
 in water, PVA is sold as an adhesive
Adhesive

Adhesive or glue is a compound in a liquid or semi-liquid state that adhesion or bonds items together. Adhesives may come from either natural or Chemical synthesis sources....
 for porous
Porosity

Porosity is a measure of the void spaces in a material, and is measured as a fraction, between 0?1, or as a percentage between 0?100%. The term is used in multiple fields including ceramics, metallurgy, materials, manufacturing, earth sciences and construction....
 materials, particularly wood
Wood

Wood is an organic material; in the strict sense wood is produced as secondary xylem in the stems of woody plants, notably trees but also shrubs, etc....
, paper
Paper

Paper is thin material mainly used for writing upon, printing upon or packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....
, and cloth.






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Polyvinyl Acetate Formula
Polyvinyl acetate (PVA or PVAc) is a rubber
Rubber

Natural rubber is an elastomer?an Elasticity_ hydrocarbon polymer?that was originally derived from a milky colloidal suspension, or latex , found in the sap of some plants....
y synthetic polymer
Synthetic polymer

Synthetic polymers are often referred to as "plastics", such as the well-known polyethylene and nylon. However, most of them can be classified in at least three main categories: thermoplastics, thermosets and elastomers....
. PVA is a common copolymer.

It is prepared by polymerization
Polymerization

In polymer chemistry, polymerization is a process of reacting monomer molecules together in a chemical reaction to form three-dimensional networks or polymer chains....
 of vinyl acetate monomer
Vinyl acetate

Vinyl acetate is an organic compound with the Chemical formula CH3COOCH=CH2. A colorless liquid with a pungent odor, it is the precursor to polyvinyl acetate , an important polymer in industry....
, also referred to as VAM. Partial or complete hydrolysis
Hydrolysis

Hydrolysis is a chemical reaction during which one or more water are split into hydrogen and hydroxide ions which may go on to participate in further reactions....
 of the polymer is used to prepare polyvinyl alcohol
Polyvinyl alcohol

Polyvinyl alcohol is a water-soluble synthetic polymer....
. Hydroylized alcohol
Alcohol

In chemistry, an alcohol is any organic compound in which a hydroxyl Functional group is bound to a carbon atom of an alkyl or substituted alkyl group....
 product is typically in the 87% to 99% range (converted PVA).

Discovery

It was discovered in Germany
Germany

Germany , officially the Federal Republic of Germany , is a country in Central Europe. It is bordered to the north by the North Sea, Denmark, and the Baltic Sea; to the east by Poland and the Czech Republic; to the south by Austria and Switzerland; and to the west by France, Luxembourg, Belgium, and the Netherlands....
 in 1912 by Dr. Fritz Klatte
Fritz Klatte

Fritz Klatte was a German chemist and the discoverer of polyvinyl acetate, with German patent for its preparation from acetylene gas.Polyvinyl chloride was discovered by French physicist Henri Victor Regnault, and German physicist Eugen Baumann....
 with the help of his assistant James Michael Fairholm.

Applications and uses

As an emulsion
Emulsion

An emulsion is a mixture of two immiscible liquids. One liquid is dispersion in the other . Many emulsions are oil/water emulsions, with dietary fats being one common type of oil encountered in everyday life....
 in water, PVA is sold as an adhesive
Adhesive

Adhesive or glue is a compound in a liquid or semi-liquid state that adhesion or bonds items together. Adhesives may come from either natural or Chemical synthesis sources....
 for porous
Porosity

Porosity is a measure of the void spaces in a material, and is measured as a fraction, between 0?1, or as a percentage between 0?100%. The term is used in multiple fields including ceramics, metallurgy, materials, manufacturing, earth sciences and construction....
 materials, particularly wood
Wood

Wood is an organic material; in the strict sense wood is produced as secondary xylem in the stems of woody plants, notably trees but also shrubs, etc....
, paper
Paper

Paper is thin material mainly used for writing upon, printing upon or packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....
, and cloth. It is the most commonly used wood glue
Wood glue

Wood glue is an adhesive used to tightly bond pieces of wood together. Many substances have been used as glues.The most common wood glues are polyvinyl acetate , also known as "white glue" or "hobby and craft", and aliphatic resin emulsion, commonly referred to as "carpenter's glue" or "Yellow glue", which has similar relative ultimate stre...
, both as "white glue" and the yellow "carpenter's glue."

PVA is widely used in bookbinding
Bookbinding

Bookbinding is the process of physically assembling a book from a number of folded or unfolded sheets of paper or other material. It also usually involves attaching covers to the resulting text-block....
 and book arts due to its flexibility, and because it is non-acidic, (unlike many other polymers) it is used extensively in paper
Paper

Paper is thin material mainly used for writing upon, printing upon or packaging. It is produced by pressing together moist fibers, typically cellulose pulp derived from wood, rags or grasses, and drying them into flexible sheets....
, paint
Paint

Paint is any liquid, liquifiable, or mastic composition which after application to a Substrate in a thin layer is converted to an opaque solid film....
 and industrial coatings when it is referred to as vinyl acrylic.

It can also be used to protect cheese
Cheese

Cheese is a food consisting of proteins and fat from milk, usually the milk of cattle, Water Buffalo, goats, or sheep's milk. It is produced by Coagulation of the milk protein casein....
 from fungi and humidity
Humidity

Humidity is the amount of water vapor in the air. In daily language the term "humidity" is normally taken to mean relative humidity. Relative humidity is defined as the ratio of the partial pressure of water vapor in a Air parcel of air to the saturated vapor pressure of water vapor at a prescribed temperature....
. It is slowly attacked by alkali
Alkali

In chemistry, an alkali is a Base , Ionic compound salt of an alkali metal or alkaline earth metal Chemical element. Alkalis are best known for being Base s that dissolve in water....
, forming acetic acid
Acetic acid

Acetic acid, CH3COOH, also known as ethanoic acid, is an organic acid which gives vinegar its sour taste and pungent smell. Pure, water-free acetic acid is a colourless liquid that absorbs water from the environment , and freezes at 16.7 Celsius to a colourless crystalline solid....
 as a hydrolysis
Hydrolysis

Hydrolysis is a chemical reaction during which one or more water are split into hydrogen and hydroxide ions which may go on to participate in further reactions....
 product. Boron
Boron

Boron is a chemical element with atomic number 5 and the chemical symbol B. Boron is a trivalent metalloid element which occurs abundantly in the evaporite ores borax and ulexite....
 compounds like boric acid
Boric acid

Boric acid, also called boracic acid or orthoboric acid or Acidum Boricum, is a weak acid often used as an antiseptic, insecticide, flame retardant, in nuclear power plants to control the fission rate of uranium, and as a precursor of other chemical compounds....
 or borax
Borax

Borax, also known as sodium borate, sodium tetraborate, or disodium tetraborate, is an important boron compound, a mineral, and a salt of boric acid....
 will form tackifying precipitates by causing the polymer to cross-link
Cross-link

Cross-links are bonds that link one polymer chain to another. They can be covalent bonds or ionic bonds. "Polymer chains" can refer to synthetic polymers or natural polymers ....
.

PVA is also commonly recommended for use in making leather
Leather

Leather is a material created through the tanning of rawhides and skins of animals, primarily cattlehide. The tanning process converts the putrescible skin into a durable, long-lasting and versatile natural material for various uses....
 handcrafted works and papier-mâché
Papier-mâché

Papier-m?ch? , sometimes called paper-m?ch?, is a construction material that consists of pieces of paper, sometimes reinforced with textiles, stuck together using a wet paste ....
.