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Plutonium-238
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Plutonium-238, is a radioactive isotope of plutonium with a half-life of 87.7 years and is a very powerful alpha emitter. Because of its high level of alpha activity, it is used for radioisotope thermoelectric generators and radioisotope heater units.
Plutonium-238 was the first isotope of plutonium to be discovered.

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Encyclopedia
Plutonium-238, is a radioactive isotope of plutonium with a half-life of 87.7 years and is a very powerful alpha emitter. Because of its high level of alpha activity, it is used for radioisotope thermoelectric generators and radioisotope heater units.
Plutonium-238 was the first isotope of plutonium to be discovered. It was synthesized by Glenn Seaborg and associates in 1941 by bombarding uranium-238 with deuterons. Neptunium-238 is made as an intermediate product, which then decays to form plutonium-238. Plutonium-238 decays to uranium-234 and then further along the radium series to lead-206.
Today, plutonium-238 is usually prepared by the irradiation of neptunium-237, a minor actinide produced in nuclear reactors, that can be recovered from spent nuclear fuel during reprocessing, or by the irradiation of americium in a reactor. In both cases, the targets are subjected to a chemical treatment, including dissolution in nitric acid to extract the plutonium-238. A 100 kg sample of light water reactor fuel that has been irradiated for three years contains only about 700 grams of neptunium-237, and the neptunium must be extracted selectively.
The United States currently has limited facilities to produce plutonium-238. Since 1993, the U.S. has purchased all of the plutonium-238 it has used in space probes from Russia. 16.5 kilograms total have been purchased.
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